公开(公告)号：AT343364B

公开(公告)日：1978-05-26

申请号：AT536975

申请日：1975-07-11

Applicant: STANDARD OIL CO OHIO

Inventor： KENNEDY ALICE WINNETTA ,  SHANK RAYMOND S ,  WARDLOW EDDIE JR

IPC: C08L33/00 ,  C08F6/00 ,  C08F279/02 ,  C08K5/57 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/02 ,  C08L33/18 ,  C08L51/00 ,  C08L51/02 ,  C08L101/00

Abstract: A polymer composition containing a high proportionate amount of olefinic nitrile is stabilized against thermal discoloration by inclusion therein from about 0.05 to 2 parts by weight per hundred parts of resin of an organotin maleate compound selected from the group consisting of the hydrocarbon tin maleates and the hydrocarbon tin-bis-maleate half esters.

公开(公告)号：ES2129758T3

公开(公告)日：1999-06-16

申请号：ES95303103

申请日：1995-05-05

Applicant: STANDARD OIL CO OHIO

Inventor： BALL LAWRENCE E ,  SMIERCIAK RICHARD C ,  WARDLOW EDDIE JR

IPC: C08F220/44

公开(公告)号：IT1166904B

公开(公告)日：1987-05-06

申请号：IT2552779

申请日：1979-09-06

Applicant: STANDARD OIL CO

Inventor： BRANDFORD EARLE GIDDINGS ,  WARDLOW EDDIE JR ,  MEHOSKY BRIAN LEE

IPC: C08F20060101 ,  C08F

Abstract: Residual monomer is steam extracted from an aq. suspension of a resin at 100-135 degrees C and 0.35-2.1 kg/cm2 pressure, the resin having been prepd. by free radical polymerisation of an aq. suspension of a mixt. of (A) \-50 wt. % of a nitrile monomer of formula CH2=C(R)CN, where R is H, 1-4C alkyl or halogen and (B) \-1 of (1) styrene, (2) esters of formula CH2=C(R1)COOR2 where R1 is H, 1-4C alkyl or halogen, and R2 is 1-6C alkyl, (3) alpha-olefins of formula CH2=C(R')(R"), where R' and R" are 1-7C alkyl, (4) vinyl ethers comprising (m)ethyl, propyl and butyl vinyl ethers, (5) vinyl acetate and (6) indene. Pref. (A) is acrylonitrile and (B) is styrene or methyl acrylate.

公开(公告)号：NO141611B

公开(公告)日：1980-01-02

申请号：NO752483

申请日：1975-07-10

Applicant: STANDARD OIL CO OHIO

Inventor： KENNEDY ALICE WINNETTA ,  SHANK RAYMOND S ,  WARDLOW EDDIE JR

IPC: C08F6/00 ,  C08F279/02 ,  C08K5/57 ,  C08L7/00 ,  C08L33/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/02 ,  C08L33/18 ,  C08L51/00 ,  C08L51/02 ,  C08L101/00 ,  C08L33/20 ,  C08L51/04 ,  C08L55/02

Abstract: A polymer composition containing a high proportionate amount of olefinic nitrile is stabilized against thermal discoloration by inclusion therein from about 0.05 to 2 parts by weight per hundred parts of resin of an organotin maleate compound selected from the group consisting of the hydrocarbon tin maleates and the hydrocarbon tin-bis-maleate half esters.

公开(公告)号：ATA536975A

公开(公告)日：1977-09-15

申请号：AT536975

申请日：1975-07-11

Applicant: STANDARD OIL CO OHIO

Inventor： KENNEDY ALICE WINNETTA ,  SHANK RAYMOND S ,  WARDLOW EDDIE JR

IPC: C08L33/00 ,  C08F6/00 ,  C08F279/02 ,  C08K5/57 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/02 ,  C08L33/18 ,  C08L51/00 ,  C08L51/02 ,  C08L101/00

Abstract: A polymer composition containing a high proportionate amount of olefinic nitrile is stabilized against thermal discoloration by inclusion therein from about 0.05 to 2 parts by weight per hundred parts of resin of an organotin maleate compound selected from the group consisting of the hydrocarbon tin maleates and the hydrocarbon tin-bis-maleate half esters.

公开(公告)号：MY131716A

公开(公告)日：2007-08-30

申请号：MYPI9402978

申请日：1994-11-09

Applicant: STANDARD OIL CO

Inventor： SMIERCIAK RICHARD C ,  WARDLOW EDDIE JR ,  BALL LAWRENCE E

IPC: C08F220/44

Abstract: A PROCESS FOR MAKING A THERMALLY STABLE MELT PROCESSABLE ACRYLONITRILE/METHACRYLONITRILE/OLEFINICALLY UNSATURATED MULTIPOLYMER, COMPRISING POLYMERIZING A MIXTURE OF ACRYLONITRILE MONOMER, METHACRYLONITRILE MONOMER, AND OLEFINICALLY UNSATURATED MONOMER IN WHICH THE RATE OF ADDITION OF THE MULTIMONOMER MIXTURE IS SET BY RATE OF POLYMERIZATION SO THAT THE CONCENTRATION OF UNREACTED ACRYLONITRILE MONOMER, UNREACTED METHACRYLONITRILE MONOMER OLEFINICALLY UNSATURATED MONOMER IS LOW AND THE POLYMERIZATION PROCESS IS IN A MONOMER STARVED CONDITION.

公开(公告)号：SG77564A1

公开(公告)日：2001-01-16

申请号：SG1996007801

申请日：1996-02-27

Applicant: STANDARD OIL CO

Inventor： SMIERCIAK RICHARD C ,  WARDLOW EDDIE JR ,  BALL LAWRENCE E

IPC: C08F2/22 ,  C08F220/44

Abstract: A homogeneous, high nitrile melt processable acrylonitrile olefinically unsaturated multipolymer and a process for making the multipolymer, comprising polymerizing a mixture of acrylonitrile monomer and one or more olefinically unsaturated monomers, in which the rate of addition of the multimonomer mixture is set by the rate of polymerization so that the concentration of unreacted acrylonitrile monomers and unreacted olefinically unsaturated monomer(s) is low and the polymerization process is in a monomer starved condition.

公开(公告)号：ZA9601520B

公开(公告)日：1997-01-29

申请号：ZA9601520

申请日：1996-02-26

Applicant: STANDARD OIL CO OHIO

Inventor： SMIERCIAK RICHARD C ,  WARDLOW EDDIE JR ,  BALL LAWRENCE E

IPC: C08F20060101 ,  C08F

公开(公告)号：CA2134823A1

公开(公告)日：1995-05-11

申请号：CA2134823

申请日：1994-11-01

Applicant: STANDARD OIL CO OHIO

Inventor： SMIERCIAK RICHARD C ,  WARDLOW EDDIE JR ,  BALL LAWRENCE E

IPC: C08F220/44

Abstract: Title: A PROCESS FOR MAKING A POLYMER OF ACRYLONI TRILE, METHACRYLONITRILE AND OLEFINICALLY UNSATURATED MONOMERS A process for making a thermally stable melt processable acrylonitrile/methacrylonitrile/olefinically unsaturated multipolymer, comprising polymerizing a mixture of acrylonitrile monomer, methacrylonitrile monomer, and olefinically unsaturated monomer in which the rate of addition of the multimonomer mixture isset by the rate of polymerization so that the concentration of unreacted acrylonitrile monomer, unreacted methacrylonitrile monomer and unreacted olefinically unsaturated monomer is low and the polymerization process is in a monomer starved condition.

公开(公告)号：CH620696A5

公开(公告)日：1980-12-15

申请号：CH432476

申请日：1976-04-06

Applicant: STANDARD OIL CO

Inventor： WARDLOW EDDIE JR ,  SHANK RAYMOND S

IPC: C08L51/00 ,  C08F279/02 ,  C08F285/00 ,  C08K5/11 ,  C08L7/00 ,  C08L21/00 ,  C08L51/02 ,  C08L51/04 ,  C08L33/18 ,  C08L55/02

Abstract: The present invention relates to a method for stabilizing thermoplastic nitrile resins against thermal discoloration by the inclusion in the resins of acid esters of certain polycarboxylic acid compounds in amounts of from 0.1 to 1.5 parts by weight per 100 parts of resin.