감소된 함량의 출발 물질을 갖는 염료 조성물 및 이를이용한 케라틴 섬유의 염색 방법
    203.
    发明公开
    감소된 함량의 출발 물질을 갖는 염료 조성물 및 이를이용한 케라틴 섬유의 염색 방법 失效
    具有降低起始材料含量的DYE组合物,以及使用它们的KERATIN纤维染色方法

    公开(公告)号:KR1020060105665A

    公开(公告)日:2006-10-11

    申请号:KR1020060029645

    申请日:2006-03-31

    Applicant: 로레알

    Abstract: 본 발명은, 수함량 (water content) 이 40 중량% 이상인 염료 조성물, 및 또한 상기 조성물을 이용하여 케라틴 섬유, 특히 인간의 케라틴 섬유를 염색하는 방법에 관한 것이다.
    상기 염료 조성물은 또한 하나 이상의 산화 염료 전구체 및/또는 하나 이상의 직접 염료; 하나 이상의 비이온성 또는 음이온성 계면활성제 또는 이의 혼합물; 하나 이상의 히드록시에틸셀룰로오스; 하나 이상의 지방성 물질 (지방성 물질의 총량에 대한 비이온성 및 음이온성 계면활성제의 총량의 중량비는 1.75 이상임); 및 하나 이상의 양이온성 결합성 중합체를 포함한다.
    본 발명은 또한, 한편으로는 염료 조성물, 및 다른 한편으로는 산화 조성물을 포함하는 다구획 장치에 관한 것이다.

    특정 양이온성 디아조 화합물, 이를 직접 염료로 함유하는조성물, 케라틴 섬유의 염색 방법 및 이를 위한 장치
    209.
    发明公开
    특정 양이온성 디아조 화합물, 이를 직접 염료로 함유하는조성물, 케라틴 섬유의 염색 방법 및 이를 위한 장치 失效
    某些阳离子重氮化合物,含有它们作为直接染料,角蛋白纤维染色的,及装置的组合物

    公开(公告)号:KR1020060066606A

    公开(公告)日:2006-06-16

    申请号:KR1020050054701

    申请日:2005-06-23

    Applicant: 로레알

    Abstract: Cationic compound (I) or their additive salts with an acid are new. Cationic compounds (I) of formula Col1-LK-Col2 or their additive salts with an acid are new (where the electro neutrality of compound is ensured by one or more anions (An ->). Col1 : a compounds of formulae (I) and (II); Col2 : compounds of formulae (III) and (IV); W 1, W 6-NR 1- or -O; Wa 1, Wa 6-NRa 1Ra 2 or -ORa 3; either R 1, Ra 1, Ra 2, Ra 3H or 1-20 (preferably 1-16)C hydrocarbonated chain forming one or more carbonated cycles (optionally substituted by 3-7 chains and optionally interrupted by one or more heteroatoms or groups carrying at least a heteroatom (preferably O or N)); or Ra 1Ra 2 or NRa 1Ra 2optionally substituted 5-7C heterocyclic chain (optionally comprising another heteroatom, identical or different from nitrogen); or Ra 1+Ra 2+Ra 3, NRa 1, NRa 2, NRa 3forms the entire or part of LK group or 5-7C heterocyclic chain; or R 1, NR 15-7C heterocyclic chain (optionally comprising another heteroatom (optionally substituted by N or O); W 2, W 5, Wa 2, Wa 5phenyl compound of formula (a), pyrrole compound of formula (b) or naphthalene compound of formula (c); X 1N or CR 7 group; X 2N or CR 8 group; Z 1N or CR 10 group; Z 2N or CR 11 group; either R 4, R 5, R 6, Ra 6, R 7, R 8, R 10, R 111-16C hydrocarbonated chain forming one or more carbon cycles comprising 3-6 chains (optionally substituted and interrupted by one or more heteroatoms or groups carrying at least a heteroatom (preferably O or N), OH, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy, alkoxycarbonyl (RO-CO-) (where R is 1-4C alkyl radical), alkylcarbonyloxy (RCO-O-) radical (where R is 1-4C alkyl radical), amino, amino group substituted by one or more 1-4C alkyl radicals (optionally carrying OH), two alkyl radicals optionally with nitrogen atom forming 5-6C heterocyclic chain optionally carrying another heteroatom identical or different from nitrogen, alkylcarbonylamino (RCO-NR-) group (where R is 1-4C alkyl radical), carbamoyl ((R) 2N-CO) group (where R is H or 1-4C alkyl radical), ureido (N(R) 2-CO-NRa-) group (where R, Ra are H or 1-4C alkyl radical), sulfonamide ((R) 2N-SO 2-) group (where R is 1-4C alkyl radical), alkylsulfonylamino (RSO 2-NRa-) group (where R, Ra is H or 1-4C alkyl), guanidinium ((Ra) 2N-C(=NH 2 +>)-NR-) group (where R, Ra is H or 1-4C alkyl radical), NO 2, CN or halo (Cl or Fl); or R 4, R 5, R 6, Ra 6, R 7, R 8, R 10, R 11H or 5-7C heterocyclic chain, a bond of Wa 2 and Wa 1 with LK group or Wa 5 and Wa 6 with LK group; a : bond of W 2, W 5, Wa 2, Wa 5 with nitrogen group (-N=N-); b : bond of W 2 with W 1, W 5 with W 6, Wa 2 with Wa 1 with LK group or Wa 5 with Wa 6 with LK group; R 9H or 1-6C hydrocarbonated chain forming one or more carbons cycles comprising 3-7 chains (optionally substituted); n, na : lower or equal to 6; W 3, W 4a heteroaromatic cationic radical of formulae (1-11); Ra 41-16C hydrocarbonated chain, forming one or more carbon cycles comprising 3-6 chains (optionally substituted and interrupted by one or more heteroatoms or groups carrying at least a heteroatom (preferably O or N), OH, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy, alkoxycarbonyl (RO-CO-) (where R is 1-4C alkyl radical), alkylcarbonyloxy (RCO-O-) radical (where R is 1-4C alkyl radical), amino group, amino group substituted by one or more 1-4C alkyl radicals (identical or different) (optionally carrying OH), two alkyl radicals optionally with nitrogen atom forming a 5-6C heterocyclic chain optionally carrying another heteroatom identical or different from nitrogen, alkylcarbonylamino (RCO-NR-) group (where R is 1-4C alkyl radical), carbamoyl ((R) 2N-CO) group (where R is optionally identical H or 1-4C alkyl radical), ureido (N(R) 2-CO-NRa-) group (where R, Ra are H or 1-4C alkyl radical), sulfonamide ((R) 2N-SO 2-) group (where R is 1-4C alkyl radical), alkylsulfonylamino (RSO 2-NRa-) group (where R, Ra = H or 1-4C alkyl radical), guanidinium ((Ra) 2N-C(=NH 2 +>)-NR-) group ((where R, Ra = H or 1-4C alkyl radical), NO 2, CN, halo (preferably Cl or Fl), two radicals Ra4 carried by two adjacent carbon atoms of the main cycle optionally forming a secondary cycle with 5-6 (preferably 6) chains (optionally aromatic and substituted by at least H), OH, 1-4C alkyl radical, 1-4C alkoxy radical, 2-4C (poly)hydroxyalkoxy radical, amino radical, amino radical substituted by 1-4C alkyl radicals (optionally carrying at least OH group); Ra 5an atom (carbon) directly linked to quarternized nitrogen atom representing 1-16C hydrocarbonated chain, forming one or more carbon cycles comprising 3-6 chains (optionally substituted and interrupted by one or more heteroatoms or groups carrying at least a heteroatom (preferably O, N or S); R 71-4C alkyl, phenyl or benzyl (all optionally substituted); c : a bond linking the cationic radical with the nitrogen group on the main (preferred) or secondary cycle; p : 0-4; p1 : 0-2; p2 : 0-3; and LK : 2-40 (preferably 2-20)C hydrocarbon chain carrying cationic charge (optionally substituted or interrupted by a heteroatom or group comprising a heteroatom (O or N). Provided that: if the main cycle does not carry the number of maximum substituent, then the unsubstituted position(s) carry a hydrogen atom; LK is terminated by a heteroatom or group carrying a heteroatom (O or N) if LK is linked to Wa 2, Wa 5 and LK is terminated by a group carrying at least a heteroatom (-CO- or -SO 2) if LK is linked to W 6 and W 1. Independent claims are also included for: (1) tinctorial composition comprising (I) as a direct dye or its additive salts with an acid in a medium for dyeing of keratinous fibers; (2) coloring process of keratinous fiber comprising contacting the composition with the dry or wet keratinous fibers to obtain the desired effect; and (3) a device comprising several compartments in which the first compartment contains the composition and the second compartment contains an oxidizing composition. [Image] [Image] [Image] [Image] [Image] [Image].

    Abstract translation: 本发明涉及式(1)涉及阳离子第一染料-LK-2的双偶氮染料化合物:

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