N-PHENYLTETRAHYDROINDAZOLES, THEIR PREPARATION, AND THEIR USE AS CROP PROTECTION AGENTS

    公开(公告)号:CA2197902A1

    公开(公告)日:1996-03-07

    申请号:CA2197902

    申请日:1995-08-18

    Applicant: BASF AG

    Abstract: N-Phenyltetrahydroindazoles of formula (I), where R1 is H or C1-4-alkyl; R2 is halogen, C1-4-alkyl or C1-4-haloalkyl; R3 is H or halogen; R4 is NO2, halogen, C1-4-alkyl or C1-4-haloalkyl; R5 is -XR6; X is -O-, -S-, -SO- or -SO2-; R6 is Alk-R7; Alk is a substituted or unsubstituted methylene, ethylene, propylene, butylene or pentamethylene chain, where one chain member can carry a spirolinked 2- to 5-membered C chain or where 2 ring members can be bridged via a C1-5-alkylene chain; R7 is CN, SCN, halogen or -YR11, where Y is -O-, -S-, -SO- or -SO2-; R10 is H, OH, C1-C4-alkyl, C1-C4-haloalkyl, C3-C5-cycloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C5-cycloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, -NH-R12, -N(C1-C4-alkyl)-R12, -N(C3-C4-alkenyl)-R12, -N(C3-C4-alkynyl)-R12, pyrrolidin-1-yl, piperid-1-yl, morpholin-4-yl, azepan-1-yl, (i) unsubstituted or substituted phenyl, benzyl, phenoxy or benzyloxy; R11 is C1-6-alkyl, C1-6-haloalkyl or C1-6-cycloalkyl; R12 is H, OH, C1-4-alkyl, C3-4-alkenyl, C3-4-alkynyl, C3-6-cycloalkyl, C1-4-alkoxy, C3-4-alkenyloxy, C3-4-alkenyloxy, C3-4-alkynyloxy, or substituted or unsubstituted phenyl or benzyl; and the agriculturally utilizable salts of formula (I), with the provisoes that the simultaneous meaning of R6 as dihalomethyl, R2 and R4 as chlorine and R3 as halogen is excluded; the simultaneous meaning of X as oxygen and R7 as OR11 or C1-C6-alkylthio is excluded; Alk must not carry a spiro-linked threemembered ring if R7 is halogen and R11 is not C1-6-alkyl if R1 is H, R2 is C14-haloalkyl, R3 is F, R4 is halogen and R7 is -OR11. Use: as herbicides; for desiccating/defoliating plants.

    Substituted 1-amino-3-phenyluracils
    202.
    发明专利

    公开(公告)号:ZA946699B

    公开(公告)日:1996-03-01

    申请号:ZA946699

    申请日:1994-09-01

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/02821 Sec. 371 Date Feb. 15, 1996 Sec. 102(e) Date Feb. 15, 1996 PCT Filed Aug. 25, 1994 PCT Pub. No. WO95/06641 PCT Pub. Date Mar. 9, 1995Substituted 1-amino-3-phenyluracils I I where the variables have the following meanings: R1=H, F, Cl; Y=O, S; Z=-CH=N-OH, -CH=N-O-(alkyl), -CH=N-O-(alkylene)-O-(alkyl), -CH=N-O-CH2-COOH, -CH=N-O-CH(alkyl)-COOH, -CH=N-O-CH2-CO-O-(alkyl), -CH=N-O-CH(alkyl)-CO-O-(alkyl), -CH=N-O-CH2-CO-O=O- (alkylene)-O-(alkyl), -CH=N-O-CH(alkyl)-CO-O- (alkylene)-O-(alkyl), -CH=CH-CO-O-(alkyl), -CH=CH- CO-O-(alkylene)-O-(alkyl), -CH=C(Cl)-CO-O-(alkyl), -CH=C(Br)-CO-O-(alkyl), -CH=C(Cl)-CO-O-(alkylene)-O-(alkyl), -CH=C(Br)-CO-O-(alkylene)-O-(alkyl), -CH=C(CH3)-CO-O-(alkyl), -CH=C(CH3)-CO-O-(alkylene)-O-(alkyl), -CH[X1-(alkyl)] [X2-(alkyl)] or a radical X1-X6=O, S; R2-R11=H, alkyl, vinyl, alkoxycarbonyl are described. Use: herbicides; desiccation/defoliation of plants.

    208.
    发明专利
    未知

    公开(公告)号:FI954993A0

    公开(公告)日:1995-10-19

    申请号:FI954993

    申请日:1995-10-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/01156 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 14, 1994 PCT Pub. No. WO94/25443 PCT Pub. Date Nov. 10, 19943-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I I where R1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH; R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted; an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; unsubstituted or substituted phenyl or naphthyl; R4 and R5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl, each of which is unsubstituted or substituted; R6 is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; Y is sulfur or oxygen or a single bond; and Z is sulfur or oxygen.

    209.
    发明专利
    未知

    公开(公告)号:DE4343922A1

    公开(公告)日:1995-06-29

    申请号:DE4343922

    申请日:1993-12-22

    Applicant: BASF AG

    Abstract: Pyridine-2,3-dicarboximides of formula (I) and their salts are new, except for 6-amino-5-cyano-4-phenyl-pyridine-2,3-dicarboximide. R1 = H, 1-4C alkoxy, 1-6C alkyl (substd. by 0-3 of 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio, 1-4C haloalkylthio, 1-4C dialkylamino, 3-8C cycloalkyl and halogen), 3-8C cycloalkyl (substd. by 0-3 of 1-6C alkyl, 1-6C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy, halogen or NO2) or 3-6C alkenyl or alkynyl (both substd. by 0-3 halogen); provided that R1 is not dialkylaminoethyl when one of R2-R4 is NH2 or OH; at least one of R2-R4 is NO2, OR5, NR6R7 or NCS, any others = H, halogen NO2, CN 1-6C alkyl (substd. by 0-5 halogen atoms and/or 1-3 of 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio, 1-4C haloalkylthio, 3-6C cycloalkyl or CN), Ar, 3-8C cycloalkyl (substd. by 0-3 of 1-4C alkyl or halogen), 2-6C alkenyl or 2-6C alkynyl (both substd. by 0-3 of halogen or 1-3C alkoxy and/or 0-1 of Ar), 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkoxy, 1-4C haloalkylthio, 1-4C alkylsulphinyl, 1-4C alkylsulphonyl, 1-4C haloalkylsulphonyl, 2-5C alkenyloxy, 2-5C alkynyloxy, OAr, SAr; 5- or 6-membered heterocyclyl (contg. 1-2 heteroatoms (O, S and/or N) and substd. by 0-3 of 1-3C alkyl, halogen, 1-3C alkoxy or 2-4C alkoxycarbonyl), phenyl (substd. by 0-3 of 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, 1-6C haloalkylthio, halogen, NO2 or CN), OR5, NR6R7 or NCS; R5 = H, 2-4C alkanoyl, 2-4C haloalkanoyl, 2-4C alkoxycarbonyl, (1-4C)alkoxy(2-4C)alkoxycarbonyl, mono- or di(1-4C alkyl)carbamoyl, 1-4C alkylsulphonyl, 1-4C haloalkylsulphonyl, SO2NH2, mono- or di(1-4C alkyl)sulphamoyl or SO2Ar; R6 = H, 1-4C alkyl, benzyl or 1-4C alkoxy; R7 = 1-4C alkyl or as defined for R5; Ar = benzyl (ring-substd. by 0-3 of 1-4C alkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio, 1-4C haloalkylthio, halogen, CN or NO). Also claimed are new pyridine-2,3-dicarboxylic anhydride (IIa) and pyridine-2,3-dicarboxylate ester intermediates (III) (see 'Starting Materials').

    SUBSTITUTED 1-AMINO-3-PHENYLURACILS
    210.
    发明专利

    公开(公告)号:CA2169467A1

    公开(公告)日:1995-03-09

    申请号:CA2169467

    申请日:1994-08-25

    Applicant: BASF AG

    Abstract: Substituted 1-amino-3-phenyluracils (I), where the variables have the following meanings: R1 = H, F, Cl; Y = O, S; W = -CH=N-OH, -CH=N-O-(alkyl), -CH=N-O-(alkylene)-O-(alkyl), -CH=N-O-CH2-COOH, -CH=N-O-CH(alkyl)-COOH, -CN-O-CH2-CO-O-(alkyl), -CH=N-O-CH(alkyl)-CO-O-(alkyl), -CH=N-O-CH2-CO-O-(alkylene)-O-(alkyl), -CH=N-O-CH(alkyl)-CO-O-(alkylene)-O-(alkyl), -CH=CH-CO-O-(alkyl), -CH=CH-CO-O-(alkylene)-O- (alkyl), -CH=C(Cl)-CO-O-(alkyl), -CH=C(Br)-CO-O-(alkyl), CH=C(Cl)-CO-O(alkylene)-O-(alkyl), -CH=C(Br)-CO-O-(alkylene)-O- (alkyl), -CH=C(CH3)-CO-O-(alkyl), -CH=C(CH3)-CO-O-(alkylene)-O-(alkyl), -CH¢XI-(alkyl)!!¢X2-(alkyl)! or a radical (a), (b), X1-X6 = O, S; R2-R11 = H, alkyl, vinyl, alkoxycarbonyl are described, Use: herbicides; desiccation/defoliation of plants.

Patent Agency Ranking