公开(公告)号：MX9703728A

公开(公告)日：1997-09-30

申请号：MX9703728

申请日：1995-11-14

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST ,  WETTLING THOMAS

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: La presente invencion se refiere a los cianuros de halometilbenzoilo I: PH-CO-CN (Ph [sic] = fenilo el cual esta substituido por clorometilo o bromometilo y puede, si se requiere, también llevar 1-4 de otros radicales) que se preparan a partir de cloruros de halometilbenzoilo II PH-Co-C1 (ii), mediante la reaccion II con un compuesto donador de cianuros en presencia de un ácido de Lewis, si se requiere, en un solvente orgánico o diluyente inerte, y luego el aislamiento del producto. Los cianuros de halometilbenzoilo son intermediarios importantes para la síntesis de agentes protectores de las cosechas.

公开(公告)号：PL320343A1

公开(公告)日：1997-09-29

申请号：PL32034395

申请日：1995-11-14

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST ,  WETTLING THOMAS

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

公开(公告)号：HU213728B

公开(公告)日：1997-09-29

申请号：HU9301255

申请日：1993-04-29

Applicant: BASF AG

Inventor： AMMERMANN EBERHARD ,  BENOIT REMY ,  LORENZ GISELA ,  ROEHL FRANZ ,  SAUTER HUBERT ,  WINGERT HORST

IPC: A01N37/36 ,  A01N37/38 ,  A01N37/50 ,  A01N43/08 ,  A01N43/16 ,  A01N43/40 ,  A01N43/42 ,  A01N43/58 ,  A01N57/22 ,  C07C69/734 ,  C07C69/738 ,  C07C251/48 ,  C07C255/15 ,  C07C255/23 ,  C07C255/31 ,  C07C255/35 ,  C07C255/37 ,  C07C255/54 ,  C07C255/62 ,  C07D203/10 ,  C07D205/04 ,  C07D207/325 ,  C07D213/30 ,  C07D213/57 ,  C07D213/61 ,  C07D213/69 ,  C07D215/22 ,  C07D239/26 ,  C07D307/60 ,  C07D309/12 ,  C07D309/36 ,  C07D309/38 ,  C07D309/40 ,  C07D311/46 ,  C07D311/54 ,  C07D311/62 ,  C07D335/02 ,  C07F9/40 ,  A01N37/42 ,  C07C59/58 ,  C07D303/46

Abstract: Benzyl enol ether derivatives of the formula I in which A denotes CH2, CHCl, CH-alkyl, CH-O-alkyl, CH-S-alkyl, N-O-alkyl and B denotes OH, alkoxy, alkylthio and alkylamino, U, V and W are identical or different and denote hydrogen, halogen, alkyl and alkoxy, R , R and R are identical or different and denote hydrogen, cyano, halogen, amino, ester, amide, acyl, S(O)nR , PO(OR )2, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkyl-alkyl, alkoxy-alkyl, alkylthio-alkyl, arylthio-alkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, alkoxy, haloalkoxy, alkylthio, benzylthio, alkylcarbonyl, optionally substituted phenylcarbonyl, optionally substituted benzylcarbonyl, alkoxycarbonyl, optionally substituted phenoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted arylalkyl, optionally substituted arylalkenyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted hetaryl, optionally substituted hetaryloxy, optionally substituted hetarylthio, optionally substituted heteroarylalkyl, optionally substituted hetarylalkenyl, optionally substituted hetaryloxyalkyl, optionally substituted heterocyclyl and optionally substituted heterocyclyloxy, and the radical R denotes hydrogen and C1-C4-alkyl, and R and R together and also R and R together can in each case form a carbocyclic or heterocyclic ring which, in turn, can be benzo-fused and substituted, and fungicides containing these compounds.

公开(公告)号：HU213456B

公开(公告)日：1997-06-30

申请号：HU9202451

申请日：1992-07-24

Applicant: BASF AG

Inventor： AMMERMANN EBERHARD ,  BAYER HERBERT ,  DEYN WOLFGANG ,  GRAMMENOS WASSILIOS ,  KOENIG HARTMANN ,  LORENZ GISELA ,  OBERDORF KLAUS ,  RANG HARALD ,  ROEHL FRANZ ,  SAUTER HUBERT ,  WINGERT HORST

IPC: A01N37/36 ,  A01N37/38 ,  A01N37/44 ,  A01N37/48 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/56 ,  A01N43/74 ,  A01N43/78 ,  A01N43/80 ,  A01N43/82 ,  C07C69/618 ,  A61K31/21 ,  A61K31/40 ,  A61K31/505 ,  C07C67/343 ,  C07C69/65 ,  C07C69/734 ,  C07C69/736 ,  C07C69/738 ,  C07C69/75 ,  C07C69/76 ,  C07C69/84 ,  C07C69/86 ,  C07C69/92 ,  C07C69/94 ,  C07C205/34 ,  C07C205/38 ,  C07C205/56 ,  C07C229/40 ,  C07C229/44 ,  C07C233/11 ,  C07C235/32 ,  C07C235/34 ,  C07C251/38 ,  C07C251/48 ,  C07C251/52 ,  C07C251/60 ,  C07C251/66 ,  C07C255/57 ,  C07C255/64 ,  C07C275/64 ,  C07C309/66 ,  C07C309/73 ,  C07C311/09 ,  C07C311/21 ,  C07C311/29 ,  C07C313/04 ,  C07C313/06 ,  C07C317/44 ,  C07C317/46 ,  C07C323/56 ,  C07C323/62 ,  C07C327/22 ,  C07C327/48 ,  C07D207/32 ,  C07D207/335 ,  C07D207/337 ,  C07D213/53 ,  C07D213/64 ,  C07D213/643 ,  C07D213/66 ,  C07D213/68 ,  C07D213/70 ,  C07D215/22 ,  C07D215/227 ,  C07D215/233 ,  C07D215/36 ,  C07D231/12 ,  C07D233/84 ,  C07D235/28 ,  C07D239/52 ,  C07D249/12 ,  C07D257/04 ,  C07D261/08 ,  C07D263/32 ,  C07D263/34 ,  C07D263/58 ,  C07D271/06 ,  C07D271/10 ,  C07D271/113 ,  C07D277/28 ,  C07D277/30 ,  C07D277/36 ,  C07D277/68 ,  C07D277/74 ,  C07D285/12 ,  C07D285/125 ,  C07D307/46 ,  C07D307/52 ,  C07D307/54 ,  C07D309/06 ,  C07D333/24 ,  C07D409/04 ,  C07D413/04 ,  C07D513/04 ,  C07D521/00 ,  C07F7/08

Abstract: Derivatives of beta -substituted cinnamic acid of the general formula 1 in which R denotes optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl, and in which R can also denote chlorine or bromine, -X- represents the groups -O-, -S-, m denotes 0 or 1, -Y represents the groups -OR , -O-N=CR R , -NR R , -N(OR )R or -Sr , where the abovementioned substituents R to R denote optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl, and for the radicals R , R and R to R can also denote hydrogen, Z denotes halogen, nitro, cyano, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aralkyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted heteroarylalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted heteroarylthioalkyl, optionally substituted alkenyl, optionally substituted aralkenyl, optionally substituted aryloxyalkenyl, optionally substituted arylthioalkenyl, optionally substituted heteroarylalkenyl, optionally substituted heteroaryloxyalkenyl, optionally substituted heteroarylthioalkenyl, optionally substituted alkynyl, optionally substituted arylalkynyl, optionally substituted heteroarylalkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted arylazo, optionally substituted acylamino, -OR , -SR ,-SOR , -SO2R , -COOR , -CONR R , -COR , -CR =NR , -N=CR R , -CR =N-OR , -CR R -O-N=CR R , -CH2-OCOR or -NR R , where the groups R to R , and R and R denote hydrogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted heteroaryloxyalkyl or optionally substituted heteroarylthioalkyl and R denotes hydrogen or C1-C4-alkyl and in which U, V, W denote hydrogen or have one of the meanings mentioned for Z or in which two of the groups Z, U, V or W in adjacent positions of the phenyl ring optionally together form an optionally substituted five- or six-membered, aromatic or aliphatic ring fused to the phenyl ring, which can optionally contain one to three heteroatoms (N, S, O).

公开(公告)号：NO972375D0

公开(公告)日：1997-05-23

申请号：NO972375

申请日：1997-05-23

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST ,  WETTLING THOMAS

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

公开(公告)号：FI964901A0

公开(公告)日：1996-12-05

申请号：FI964901

申请日：1996-12-05

Applicant: BASF AG

Inventor： BAYER HERBERT ,  ISAK HEINZ ,  WINGERT HORST ,  SAUTER HUBERT ,  KEIL MICHAEL ,  NETT MARKUS ,  BENOIT REMY ,  MUELLER RUTH

IPC: C07C67/22 ,  C07C69/716 ,  C07C69/738 ,  C07C235/78 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48 ,  C07C251/60 ,  C07C255/41 ,  C07C255/62 ,  C07D249/12 ,  C07D521/00 ,  C07C

Abstract: A process and intermediates for preparing alpha -methoxyiminocarboxylic acid methylamides (I) by Pinner reaction of a cyanoketone (II) with an alcohol and subsequent reaction of the resulting ester (IV) with hydroxylamine to give the oxime (V), methylation of (V) to give the oxime ether (VI) and subsequent reaction of (VI) with methylamine: +TR X = nitro, trifluoromethyl, halogen, alkyl or alkoxy; n = 0, 1, 2, 3 or 4; Y = a C-organic radical.

公开(公告)号：HU212697B

公开(公告)日：1996-10-28

申请号：HU9300296

申请日：1993-02-04

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WINGERT HORST ,  WOLF BERND

IPC: C07C67/313 ,  C07B61/00 ,  C07C59/68 ,  C07C59/84 ,  C07C67/31 ,  C07C69/708 ,  C07C69/716 ,  C07C249/04 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48 ,  C07C251/40

Abstract: The present invention relates to a process for the preparation of E-oxime ethers of phenylglyoxylic esters of the general formula I in which X and Y denote halogen, alkyl, alkoxy, CF3, C(=NOR)R (R = alkyl and alkenyl), by reacting oximes of the formula II with a methylating agent in an organic diluent, and process for the preparation of E-oximes of phenylglyoxylic esters of the formula II by isomerising the E/Z oximes.

公开(公告)号：NZ263804A

公开(公告)日：1996-07-26

申请号：NZ26380494

申请日：1994-03-19

Applicant: BASF AG

Inventor： DOETZER REINHARD ,  SAUTER HUBERT ,  HARREUS ALBRECHT ,  WINGERT HORST ,  AMMERMANN EBERHARD ,  LORENZ GISELA

IPC: C07D237/14 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N35/10 ,  A01N37/50 ,  C07C251/48 ,  C07C251/52 ,  C07C251/54 ,  C07C251/56 ,  C07C251/58 ,  C07C251/60 ,  C07C251/86 ,  C07C255/62 ,  C07C255/66 ,  C07D207/333 ,  C07D209/12 ,  C07D213/30 ,  C07D213/61 ,  C07D215/12 ,  C07D217/22 ,  C07D217/24 ,  C07D231/12 ,  C07D239/34 ,  C07D241/18 ,  C07D241/44 ,  C07D261/08 ,  C07D261/10 ,  C07D263/32 ,  C07D275/02 ,  C07D307/42 ,  C07D307/56 ,  C07D307/80 ,  C07D333/08 ,  C07D333/54 ,  C07D521/00 ,  A01N43/42

Abstract: Described are compounds of the formula (I) in which Y is oxygen or an NR6 group; Z and Z are hydrogen, halogen, alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, haloalkyl, haloalkoxy, haloalkenyloxy, cyano or nitro; R is hydrogen, alkyl, haloalkyl or aryl; R is hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aryl, heteroaryl, arylalkyl, heteroarylalkyl, arylalkenyl, heteroarylalkenyl, aryloxyalkyl, heteroarylalkyl, arylalkenyl, heteroarylalkenyl, aryloxyalkyl, heteroaryloxyalkyl, acyl, arylcarbonyl, heteroarylcarbonyl or alkoxycarbonyl and R , R , R and R are hydrogen or alkyl, whereby R and R can together form a ring. Also described are fungicides containing these compounds.

公开(公告)号：AU4174996A

公开(公告)日：1996-06-19

申请号：AU4174996

申请日：1995-11-21

Applicant: BASF AG

Inventor： WINGERT HORST ,  KEIL MICHAEL

IPC: C07C249/04 ,  C07C249/12 ,  C07C251/48

Abstract: PCT No. PCT/EP95/04580 Sec. 371 Date May 20, 1997 Sec. 102(e) Date May 20, 1997 PCT Filed Nov. 21, 1995 PCT Pub. No. WO96/16932 PCT Pub. Date Jun. 6, 1996A process for preparing oxime ethers of the general formula I I where R1 is a C-organic radical, R2 is hydrogen, alkoxy, cyano, nitro, SOR4, SO2R4, CO2-alkyl, P(O)(OR4)2 or a C-organic radical, and R3 and R4 are unsubstituted or substituted C1-C6-alkyl, entails converting an oxime of the general formula II II where the substituents R1 and R2 have the abovementioned meanings, in the presence or absence of an organic diluent, with a base into the corresponding salt, and reacting the latter with a dialkyl carbonate of the general formula III III where R3 has the abovementioned meanings.

公开(公告)号：CA2207002A1

公开(公告)日：1996-05-30

申请号：CA2207002

申请日：1995-11-14

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  WINGERT HORST ,  WOLF BERND ,  ISAK HEINZ ,  KEIL MICHAEL

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40 ,  C07C255/61

Abstract: A process is disclosed for preparing halogenated methyl benzoyl cyanides having the formula (I): PH-CO-CN, in which Ph stands for a phenyl rest substituted by chloromethyl or bromomethyl that may optionally carry 1-4 other rests, from halogenated methyl benzoyl chlorides having the formula (II): PHCO-Cl. The compound having the formula (II) is reacted with a cyanidereleasing compound in the presence of a Lewis acid, optionally in an inert organic solvent or diluent, and the product obtained by this process is then isolated. The halogenated methyl benzoyl cyanides having the formula (I) are important intermediate products for the synthesis of plant protective agents.