Preparation of tetrahydrofuran homo- or copolymer or mono- or di-ester

    公开(公告)号:DE19735330A1

    公开(公告)日:1999-02-18

    申请号:DE19735330

    申请日:1997-08-14

    Applicant: BASF AG

    Abstract: The preparation of polytetrahydrofuran, tetrahydrofuran (THF) copolymers, their mono- and di-esters, with lower color index, involves polymerization in the presence of telomer and/or comonomer and also hydrogen, using a heterogeneous catalyst. The preparation of polytetrahydrofuran, tetrahydrofuran (THF) copolymers, their mono- and di-esters, with lower color index, comprises polymerizing THF in the presence of at least one telomer and/or comonomer using a heterogeneous catalyst and also hydrogen. SPECIFIC SUBSTANCES - The hydrogen pressure is 0.1-5 bar.

    252.
    发明专利
    未知

    公开(公告)号:NO986155L

    公开(公告)日:1998-12-28

    申请号:NO986155

    申请日:1998-12-28

    Applicant: BASF AG

    Abstract: The invention relates to a catalyst comprising alpha -aluminium oxide as the support material and copper as the active constituent, the BET surface (as defined in DIN 66131) of the aluminium oxide being not lower than 30 m /g. It also relates to a process for preparing said catalyst according to the invention, and the use thereof in dehydrogenation of cyclohexanol to form cyclohexanone, and also to the use of alpha -aluminium oxide, the BET surface (as defined in DIN 66131) of said aluminium oxide being not lower than 30 m /g, to prepare a catalyst.

    253.
    发明专利
    未知

    公开(公告)号:ES2119477T3

    公开(公告)日:1998-10-01

    申请号:ES95933381

    申请日:1995-09-21

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03651 Sec. 371 Date Mar. 10, 1997 Sec. 102(e) Date Mar. 10, 1997 PCT Filed Sep. 21, 1995 PCT Pub. No. WO96/09335 PCT Pub. Date Mar. 28, 1996A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C1-C10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C1-C10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500 DEG to 1000 DEG C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.

    254.
    发明专利
    未知

    公开(公告)号:AT169648T

    公开(公告)日:1998-08-15

    申请号:AT95933381

    申请日:1995-09-21

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03651 Sec. 371 Date Mar. 10, 1997 Sec. 102(e) Date Mar. 10, 1997 PCT Filed Sep. 21, 1995 PCT Pub. No. WO96/09335 PCT Pub. Date Mar. 28, 1996A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C1-C10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C1-C10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500 DEG to 1000 DEG C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.

    258.
    发明专利
    未知

    公开(公告)号:NO327435B1

    公开(公告)日:2009-06-29

    申请号:NO20044561

    申请日:2004-10-22

    Applicant: BASF AG

    Abstract: The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.

    PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORK MATERIALS

    公开(公告)号:CA2640294A1

    公开(公告)日:2008-08-16

    申请号:CA2640294

    申请日:2007-02-05

    Applicant: BASF AG

    Abstract: The present invention relates to a method for producing a porous metal-organic framework material comprising the step reacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.

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