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公开(公告)号：KR1020050030649A
公开(公告)日：2005-03-31
申请号：KR1020030066580
申请日：2003-09-25
Applicant: 제일모직주식회사
Abstract: Provided are a flame retardant thermoplastic resin composition which is reduced in the addition of char generating materials and is excellent in flame retardancy, heat resistance, and a molded product prepared from the composition. The thermoplastic resin composition comprises 100 parts by weight of a rubber modified styrene-based resin which comprises 10-68 parts by weight of a rubber component, and 5-40 wt% of a styrene-acrylonitrile graft copolymer resin containing 18-50 wt% of acrylonitrile and 60-95 wt% of a styrene-acrylonitrile copolymer resin containing 18-50 wt% of acrylonitrile except a rubber component; 1-30 parts by weight of an epoxy resin; 1-20 parts by weight of a phenol resin; 5-30 parts by weight of an aromatic phosphate compound; and 0.005-5.000 parts by weight of a crosslinking accelerator.
Abstract translation: 提供一种阻燃热塑性树脂组合物，其在添加炭发生材料时减少，并且具有优异的阻燃性，耐热性和由该组合物制备的模塑产品。 热塑性树脂组合物包含100重量份的橡胶改性苯乙烯基树脂，其包含10-68重量份的橡胶组分和5-40重量％的含有18-50重量％的苯乙烯 - 丙烯腈接枝共聚物树脂， 的丙烯腈和60-95重量％的含有18-50重量％丙烯腈的苯乙烯 - 丙烯腈共聚物树脂，除了橡胶组分; 1-30重量份环氧树脂; 1-20份（重量）酚醛树脂; 5-30重量份的芳族磷酸酯化合物; 和交联促进剂0.005-5.000重量份。
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公开(公告)号：KR1020040058485A
公开(公告)日：2004-07-05
申请号：KR1020020084711
申请日：2002-12-27
Applicant: 제일모직주식회사
IPC: C08L51/06
CPC classification number: C08L51/04 , C08J2300/22 , C08K5/52 , C08L25/12 , C08L2201/02
Abstract: PURPOSE: Provided is a thermoplastic resin composition that has excellent flame retardancy and is environmentally friendly by using an oxaphosphorane compound as a flame retardant, instead of halogen compounds. CONSTITUTION: The flame retardant thermoplastic resin composition comprises: (A) 100pts.wt of a rubber-modified styrene resin comprised of (a1) 20-100wt% of a grafted copolymer resin which is prepared by adding 30-95wt% of an aromatic vinyl monomer, 0-20wt% of a monomer which is copolymerizable with the aromatic vinyl monomer and 0-15wt% of a monomer which imposes processability and heat resistance to 5-65wt% of a rubber polymer, and carrying out graft polymerization, and (a2) 0-80wt% of a copolymer resin which is prepared by, to 60-90wt% of an aromatic vinyl monomer, adding 10-40wt% of a monomer which is copolymerizable with the aromatic vinyl monomer and 0-30wt% of a monomer which imposes processability and heat resistance and carrying out copolymerization; and (B) 15-40pts.wt of an oxaphosphorane compound having a general formula 1, wherein R1 is hydrogen, C1-4 alkyl or C6-10 aryl group; each R2 and R3 is hydrogen or C1-4 alkyl group; and n is 1-30.
Abstract translation: 目的：提供阻燃性优异且通过使用氧化磷烷化合物作为阻燃剂而环保的热塑性树脂组合物，而不是卤素化合物。 阻燃热塑性树脂组合物包括：（A）100重量份由（a1）20-100重量％的接枝共聚物树脂组成的橡胶改性苯乙烯树脂，其通过将30-95重量％的芳族乙烯基 单体，0-20重量％的可与芳族乙烯基单体共聚的单体和0-15重量％的单体，其加成性和耐热性为橡胶聚合物的5-65重量％，并进行接枝聚合，和（a2 ）0-80重量％的共聚物树脂，其通过向60-90重量％的芳族乙烯基单体制备，加入10-40重量％的可与芳族乙烯基单体共聚的单体和0-30重量％的单体， 施加加工性和耐热性并进行共聚; 和（B）15-40pts.wt的具有通式1的氧杂磷杂环戊烷化合物，其中R 1是氢，C 1-4烷基或C 6-10芳基; 每个R 2和R 3是氢或C 1-4烷基; n为1-30。
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公开(公告)号：KR100396404B1
公开(公告)日：2003-09-02
申请号：KR1020000082552
申请日：2000-12-27
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic flame retardant resin composition and a product prepared by using the composition are provided, to improve the flame retardancy by employing copper compounds without adding char compounds. CONSTITUTION: The composition comprises 100 parts by weight of a rubber-modified styrene-acrylonitrile copolymer resin which comprises (a1) 20-90 wt% of a styrene-acrylonitrile grafted copolymer resin whose rubber content is 10-68 wt% and whose acrylonitrile content except the rubber component is 18-65 wt%, and (a2) 10-80 wt% of a styrene-acrylonitrile grafted copolymer resin whose acrylonitrile content is 18-65 wt%; 2-30 parts by weight of an aromatic phosphate ester compound; and 0.01-20 parts by weight of at least one copper compound selected from the group consisting of oxides, sulfides, chlorides, fluorides, phosphates, sulfates, nitrates and salts of organic acids including monovalent or divalent copper. Optionally the composition comprises further 0-60 parts by weight of a polyphenylene ether resin.
Abstract translation: 目的：提供一种热塑性阻燃树脂组合物和使用该组合物制备的产品，以通过使用铜化合物而不添加焦化合物来提高阻燃性。 构成：该组合物包含100重量份的橡胶改性苯乙烯 - 丙烯腈共聚物树脂，其包含（a1）20-90重量％的苯乙烯 - 丙烯腈接枝共聚物树脂，其橡胶含量为10-68重量％，其丙烯腈含量 （a2）10-80重量％的丙烯腈含量为18-65重量％的苯乙烯 - 丙烯腈接枝共聚物树脂; 2-30重量份的芳族磷酸酯化合物; 和0.01-20重量份的至少一种选自氧化物，硫化物，氯化物，氟化物，磷酸盐，硫酸盐，硝酸盐和包括一价或二价铜的有机酸的盐的铜化合物。 任选地，组合物还包含0-60重量份的聚苯醚树脂。
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公开(公告)号：KR100394905B1
公开(公告)日：2003-08-19
申请号：KR1020010036185
申请日：2001-06-25
Applicant: 제일모직주식회사
IPC: C08K13/02
Abstract: PURPOSE: A fire retardant thermoplastic resin composition is provided, to improve the heat resistance and the mechanical properties by employing an organic phosphoric acid ester treated with an organoclay together with a phosphorus-based compound as a flame retardant. CONSTITUTION: The fire retardant thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; 5-30 parts by weight of an organic phosphoric acid ester treated with an organoclay, which consists of 0.1-20 % of an organoclay and 80-99.9 % of an organic phosphoric acid ester; optionally 50 parts by weight or less of a phosphorus-based compound; optionally 5 parts by weight or less of a dropping preventer; and optionally 50 parts by weight or less of a plasticizer, a heat stabilizer, an antioxidizing agent, a photostabilizer, a compatibilizer, a pigment and/or a dye and an inorganic additive. Preferably the organoclay is prepared by reacting the plate clay having a cation exchange property of 50-200 mg eq. per 100 g with the organic cation represented by the formula 1, wherein R1, R2, R3 and R4 are independent each another and are an alkyl group of C1-C30, an alkyl-substituted or unsubstituted aryl group of C6-C30, an alkyl group of C1-C30 having 1-5 hydroxy groups, or an aryl group of C6-C30 having 1-5 hydroxy groups; X- is an anion.
Abstract translation: 目的：提供一种阻燃热塑性树脂组合物，通过使用用有机粘土和磷系化合物一起处理的有机磷酸酯作为阻燃剂来提高耐热性和机械性能。 构成：阻燃热塑性树脂组合物包含100重量份热塑性树脂; 5-30重量份用有机粘土处理的有机磷酸酯，该有机粘土由0.1-20％的有机粘土和80-99.9％的有机磷酸酯组成; 任选50重量份或更少的磷基化合物; 任选5重量份或更少的防滴剂; 和任选的50重量份或更少的增塑剂，热稳定剂，抗氧化剂，光稳定剂，增容剂，颜料和/或染料和无机添加剂。 优选地，有机粘土通过使阳离子交换性质为50-200mg eq。 每100g与式1代表的有机阳离子，其中R1，R2，R3和R4彼此独立，为C1-C30的烷基，C6-C30的烷基取代或未取代的芳基，烷基 具有1-5个羟基的C1-C30基团或具有1-5个羟基的C6-C30芳基; X-是一种阴离子。
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公开(公告)号：KR1020140077577A
公开(公告)日：2014-06-24
申请号：KR1020120146542
申请日：2012-12-14
Applicant: 제일모직주식회사
Abstract: According to the present invention, a thermoplastic resin composition comprises: (A) a rubber-modified vinyl-based graft copolymer; (B) a vinyl cyanide-aromatic vinyl-based copolymer; and (C) an α-methylene-γ-butyrolactone (MBL)-vinyl-based copolymer. The thermoplastic resin composition has excellent chemical resistance, thereby preventing chemical corrosion by a foaming agent.
Abstract translation: 根据本发明，热塑性树脂组合物包含：（A）橡胶改性的乙烯基类接枝共聚物; （B）乙烯基氰 - 芳族乙烯基类共聚物; 和（C）α-亚甲基-γ-丁内酯（MBL） - 乙烯基类共聚物。 热塑性树脂组合物具有优异的耐化学性，从而防止发泡剂的化学腐蚀。
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Patent Agency Ranking
公开(公告)号：KR1020130065455A
公开(公告)日：2013-06-19
申请号：KR1020110132313
申请日：2011-12-09
Applicant: 제일모직주식회사
CPC classification number: C08L25/04 , C08K3/22 , C08K5/5313 , C08K2003/2227 , C08L71/12
Abstract: PURPOSE: An environmental friendly thermoplastic resin composition is provided to have excellent mechanical properties and thermal stability, and improved flowability, thereby having excellent safety against fire. CONSTITUTION: An environmental friendly thermoplastic resin composition comprises an aromatic vinyl-based resin, polyphenylene ether-based resin, boehmite, and alkyl phosphinate metal salt. Te average particle diameter(D_50) of the alkyl phosphinate metal salt is 0.01-10 micron. The weight ratio of the boehmite and alkyl phosphinate metal salt is 9:1-4:6. The average particle diameter of the boehmite(D_50) is 0.01-10 micron. The aromatic vinyl-based resin is a rubber-modified styrene-based resin. The rubber-modified styrene-based resin has 1-30 wt% of rubber with an average rubber diameter of 0.1-3 micron.
Abstract translation: 目的：提供环保的热塑性树脂组合物以具有优异的机械性能和热稳定性，并提高流动性，从而具有优异的耐火安全性。 构成：环保型热塑性树脂组合物包含芳族乙烯基类树脂，聚苯醚系树脂，勃姆石，烷基次膦酸金属盐。 烷基次膦酸盐金属盐的Te平均粒径（D_50）为0.01-10微米。 勃姆石和烷基次膦酸盐金属盐的重量比为9：1-4：6。 勃姆石的平均粒径（D_50）为0.01-10微米。 芳族乙烯基类树脂是橡胶改性苯乙烯类树脂。 橡胶改性苯乙烯类树脂具有1-30重量％的橡胶，平均橡胶直径为0.1-3微米。
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公开(公告)号：KR100817399B1
公开(公告)日：2008-03-27
申请号：KR1020060044262
申请日：2006-05-17
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08F279/02 , C08F279/04 , C08K5/5357 , C08L55/02 , C08L2666/02
Abstract: 본 발명은 고무변성 스티렌계 수지, 고리형 알킬 포스포네이트 에스테르 화합물 및 선택적으로 방향족 인산 에스테르 화합물을 포함하는 난연성 열가소성 수지 조성물에 관한 것으로, 본 발명에 의하면 기존의 난연제인 할로겐계 화합물과 안티몬계 화합물의 유해성과 이의 대체 난연제인 트리페닐 포스페이트 또는 디인산 에스테르의 고휘발성 및 내열도 저하를 개선하여 환경 친화적인 난연성과 우수한 물성을 갖는 열가소성 수지를 제공할 수 있다.
열가소성 수지, 난연성, 내열도, 흡습성, 방향족 비닐계 단량체, 고리형 알킬 포스포네이트 에스테르 화합물, 방향족 인산 에스테르 화합물-
公开(公告)号：KR100685240B1
公开(公告)日：2007-02-22
申请号：KR1020067002322
申请日：2004-07-13
Applicant: 제일모직주식회사
IPC: C08K5/5333 , C08L55/02 , C08L71/12
CPC classification number: C08L51/04 , C08F279/02 , C08K5/523 , C08K5/5357 , C08L9/00 , C08L9/02 , C08L25/06 , C08L25/10 , C08L71/12 , C08L71/123 , C08L2205/03 , C08L2666/02 , C08L2666/14 , C08L2666/04
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 고무강화 플리스티렌 수지 20∼90 중량부, (B) 폴리페닐렌 에테르 수지 10∼80 중량부, (C) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여, 고리형 포스포닉산 화합물 0.1∼30 중량부, 및 (D) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여, 방향족 인산 에스테르계 화합물 0∼25 중량부로 이루어지는 것을 특징으로 한다.
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公开(公告)号：KR100654530B1
公开(公告)日：2006-12-05
申请号：KR1020050136024
申请日：2005-12-30
Applicant: 제일모직주식회사
Abstract: Provided is a flame retardant thermoplastic resin composition which is excellent in flame retardancy and heat resistance and is environmentally friendly by using a nonhalogenated compound. The thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; 0.1-40 parts by weight of a titanium-containing organic nitrogen compound; and 0.1-40 parts by weight of a phosphorus-based compound. Preferably the titanium-containing organic nitrogen compound is represented by the formula 1, wherein R1 and R2 are independently H, a C1-C12 alkyl group or a C6-C20 aryl group; and X is H, OH, a C1-C12 alkyl group or a C6-C20 aryl group.
Abstract translation: 本发明提供一种阻燃热塑性树脂组合物，其具有优异的阻燃性和耐热性，并且通过使用非卤化化合物而对环境友好。 该热塑性树脂组合物包含100重量份的热塑性树脂; 0.1-40重量份的含钛有机氮化合物; 和0.1-40重量份的磷基化合物。 优选地，含钛有机氮化合物由式1表示，其中R 1和R 2独立地为H，C 1 -C 12烷基或C 6 -C 20芳基; X是H，OH，C1-C12烷基或C6-C20芳基。
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30.发明授权
公开(公告)号：KR100592062B1
公开(公告)日：2006-06-21
申请号：KR1020040081724
申请日：2004-10-13
Applicant: 제일모직주식회사
IPC: C08L55/02 , C08K5/02 , C08K5/3492
Abstract: 본 발명의 우수한 내충격성 및 색상발현성을 갖는 난연성 아크릴로니트릴-부타디엔-스티렌계 공중합체 수지 조성물은 (A) 아크릴로니트릴-부타디엔-스티렌계 공중합체(ABS) 수지 100 중량부; (B) 브롬화 에폭시 올리고머 10 내지 20중량부; (C) 2,4,6-트리(2,4,6-트리브로모페녹시)-1,3,5-트리아진 5 내지 15 중량부; (D) 삼산화안티몬 1 내지 3 중량부; 및 (E) 염소계 화합물 1 내지 10 중량부로 이루어진다.
ABS 수지, 브롬화 에폭시 올리고머, 2,4,6-트리(2,4,6-트리브로모페녹시)-1,3,5-트리아진, 산화안티몬, 색상발현성Abstract translation: 丙烯腈，具有优异的耐冲击性，并且本发明 - 丁二烯 - 苯乙烯共聚物树脂组合物（A）丙烯腈 - 丁二烯 - 苯乙烯共聚物（ABS）树脂，100重量份的色表达丙烯酸阻燃剂; （B）10至20重量份的溴化环氧低聚物; （C）5至15重量份的2,4,6-三（2,4,6-三溴苯氧基）-1,3,5-三嗪; （D）1-3重量份三氧化锑; 和（E）1至10重量份的氯化化合物。
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