-
公开(公告)号：KR1020090072651A
公开(公告)日：2009-07-02
申请号：KR1020070140822
申请日：2007-12-28
Applicant: 제일모직주식회사
Abstract: A thermoplastic resin composition is provided to ensure excellent weatherability while maintaining heat resistance and impact strength of intrinsic resin. A thermoplastic resin composition with excellent weatherability comprises an acrylic graft-copolymer 20~60 parts by weight, diene graft-copolymer 0~20 parts by weight, and a copolymer 40~80 parts by weight of vinyl cyanide compound with average molecular weight of 80,000~400,000 and aromatic vinyl compound. The acrylic graft-copolymer is obtained by emulsion graft-polymerizing a monomer mixture 40~80 parts by weight consisting of a vinyl cyanide compound 30~35 weight% and an aromatic vinyl compound 70~65 weight% to an acrylic synthetic rubber 20~60 parts by weight.
Abstract translation: 提供热塑性树脂组合物以确保优异的耐候性，同时保持本征树脂的耐热性和冲击强度。 具有优异耐候性的热塑性树脂组合物包括20〜60重量份的丙烯酸接枝共聚物，0〜20重量份的二烯接枝共聚物和平均分子量为80,000的共聚物40〜80重量份的乙烯基氰化合物 〜40万和芳香族乙烯基化合物。 丙烯酸接枝共聚物通过乳液接枝聚合40〜80重量份的单体混合物而得到，所述单体混合物由30〜35重量％的乙烯基氰化合物和70〜65重量％的芳香族乙烯基化合物组成的丙烯酸合成橡胶20〜60 重量份。
-
公开(公告)号：KR1020070060681A
公开(公告)日：2007-06-13
申请号：KR1020050120597
申请日：2005-12-09
Applicant: 제일모직주식회사
IPC: C08F279/04 , C08F279/02
CPC classification number: C08F279/04 , C08F2/24 , C08F2/38 , C08L55/02
Abstract: Provided are an environment-friendly thermoplastic resin composition, which has low volatility and absorptiveness, generates a low amount of gas by pyrolysis, and is superior in an injection stay discoloring property, impact strength, and flowability, and a preparation thereof. The thermoplastic resin composition is prepared by the steps of: (i) adding ion-exchanged water and a reactive emulsifier to a butadiene rubber polymer in a reactor, thereto adding a monomer mixture of an aromatic vinyl monomer and a vinyl cyanide monomer, and a molecular weight controller, heating the admixture while stirring, thereto adding a cross-linking agent, a graft agent, an oil-soluble pyrolytic initiator when the temperature reaches 55-65°C, and starting polymerization to prepare a first graft ABS; and (ii) adding a water-soluble initiator in the presence of the first graft ABS to stir the admixture, adding the monomer mixture and the molecular weight controller for 2-5 hours, and performing a second graft reaction to prepare a graft acrylonitrile-butadiene-styrene copolymer.
Abstract translation: 提供一种环境友好的热塑性树脂组合物，其具有低的挥发性和吸收性，通过热解产生少量的气体，并且具有优异的注射停留变色性，冲击强度和流动性及其制备。 热塑性树脂组合物是通过以下步骤制备的：（i）在反应器中向丁二烯橡胶聚合物中加入离子交换水和反应性乳化剂，然后加入芳族乙烯基单体和乙烯基氰单体的单体混合物， 分子量控制器，在搅拌下加热混合物，当温度达到55-65℃时加入交联剂，接枝剂，油溶性热解引发剂，并开始聚合以制备第一接枝ABS; 和（ii）在第一接枝ABS的存在下加入水溶性引发剂以搅拌混合物，将单体混合物和分子量控制剂加入2-5小时，并进行第二次接枝反应以制备接枝丙烯腈 - 丁二烯 - 苯乙烯共聚物。
-
23.发明授权내충격성과 유동성이 우수하고 자연색상이 향상된 높은고무함량을 갖는 신규의 그라프트 공중합체의 제조방법 失效내충격성과유동성이우수하고자연색상이향상된높은고무을을갖는신규의그라프트공중합체의제조방법
公开(公告)号：KR100453875B1
公开(公告)日：2004-10-20
申请号：KR1020000082794
申请日：2000-12-27
Applicant: 제일모직주식회사
IPC: C08F279/04
CPC classification number: C08F285/00 , C08F279/04
Abstract: The present invention provides a method of preparing a graft copolymer with a high rubber content showing good mechanical properties, which comprises (i) a first step of preparing a first graft copolymer latex by graft-polymerizing a monomer mixture of styrene and acrylonitrile onto a rubber polymer using an oil-soluble initiator; and (ii) a second step of preparing a second graft copolymer latex by reacting said first graft copolymer latex using a redox catalyst system and an initiator and adding continuously a monomer mixture of styrene and acrylonitrile, a molecular weight controlling agent and an initiator over 2-6 hours.
Abstract translation: 本发明提供一种制备具有良好机械性能的高橡胶含量的接枝共聚物的方法，该方法包括（i）通过将苯乙烯和丙烯腈的单体混合物接枝聚合到橡胶上来制备第一接枝共聚物胶乳的第一步骤 使用油溶性引发剂的聚合物; （ii）通过使用氧化还原催化剂体系和引发剂使所述第一接枝共聚物胶乳反应并且连续添加苯乙烯和丙烯腈的单体混合物，分子量控制剂和引发剂来制备第二接枝共聚物胶乳的第二步骤 -6个小时。
-
公开(公告)号：KR1020030042626A
公开(公告)日：2003-06-02
申请号：KR1020010073352
申请日：2001-11-23
Applicant: 제일모직주식회사
IPC: C08F279/04
CPC classification number: C08F279/04 , C08F212/10
Abstract: PURPOSE: A process for preparing a SAN(acrylonitrile-butadiene-styrene) graft copolymer of core-shell structure having excellent appearance and whiteness and high rubber content is provided. CONSTITUTION: The process for preparing a SAN graft copolymer comprises the steps of: introducing ion exchanged water into which a water soluble initiator is dissolved, and an emulsifier into a polybutadiene elastomeric polymer having an average particle diameter of 0.28 to 0.33 micrometers and gel content of 75 to 85 wt%; heating the mixture to 55 to 65 deg.C in order to swell the water soluble initiator into the elastomeric polymer and in order to decompose to form a radical gradually; introducing continuously an aromatic vinyl compound and an unsaturated nitrile compound which are the monomers to be grafted onto the elastomeric polymer, an emulsifier and a molecular weight modifier; heating the mixture to the final temperature of 75 to 85 deg.C and terminating the polymerization when the conversion is 95 to 98% and solid content is 40 to 44 wt% to obtain a SAN graft copolymer latex; and then introducing a solidifying agent consisting of an aqueous acid solution and aqueous salt solution to solidify the SAN graft copolymer resin.
Abstract translation: 目的：提供具有优异的外观和白度以及高橡胶含量的核 - 壳结构的SAN（丙烯腈 - 丁二烯 - 苯乙烯）接枝共聚物的方法。 构成：制备SAN接枝共聚物的方法包括以下步骤：引入溶解有水溶性引发剂的离子交换水，将乳化剂引入平均粒径为0.28至0.33微米的聚丁二烯弹性体聚合物中，并将凝胶含量 75〜85重量％ 将混合物加热至55至65℃以便将水溶性引发剂溶胀到弹性体聚合物中，并逐渐分解形成基团; 连续引入作为待接枝到弹性体聚合物上的单体的芳族乙烯基化合物和不饱和腈化合物，乳化剂和分子量调节剂; 将混合物加热至75〜85℃的最终温度，当转化率为95〜98％，固体成分为40〜44重量％时终止聚合，得到SAN接枝共聚物胶乳; 然后引入由酸水溶液和盐水溶液组成的固化剂以固化SAN接枝共聚物树脂。
-
25.发明公开
公开(公告)号：KR1020020054103A
公开(公告)日：2002-07-06
申请号：KR1020000082794
申请日：2000-12-27
Applicant: 제일모직주식회사
IPC: C08F279/04
CPC classification number: C08F285/00 , C08F279/04
Abstract: PURPOSE: Provided is a method for preparing a novel graft copolymer having high rubber content and improved natural color, as well as excellent in impact resistance and fluidity. CONSTITUTION: The method comprises the steps of (i) mixing 10-30 wt% of graft monomer mixture with fat-soluble thermal decomposition initiator with stirring, introducing the mixture into rubbery polymer, introducing molecular weight controlling agent and ion exchange water, elevating the temperature with stirring, and continuously stirring within 10 minutes when the temperature reaches 55-65 deg.C to swell most of the introduced graft monomer and polymerization initiator into rubber particles, and introducing an emulsifier and elevating a temperature of reactor to initiate a polymerization, thereby the first copolymer latex being produced; and (ii) introducing redox based catalyst mixture and polymerization initiator in a reactor in the presence of the first graft copolymer latex, stirring the mixture for 5-10 minutes, mixing 90-70 wt% of residual graft monomer mixture and molecular weight controlling agent with stirring, and continuously introducing the latter mixture over 2-5 hours and polymerization initiator at the same time for 2-5 hours to graft react the trace graft monomer and the polymerization initiator, thereby the second copolymer latex being produced.
Abstract translation: 目的：提供一种具有高橡胶含量和改进的自然色，以及耐冲击性和流动性优异的新型接枝共聚物的方法。 方法：该方法包括以下步骤：（i）将10-30重量％的接枝单体混合物与脂溶性热分解引发剂搅拌混合，将混合物引入橡胶状聚合物，引入分子量控制剂和离子交换水， 在温度达到55-65摄氏度的10分钟内连续搅拌，将大多数引入的接枝单体和聚合引发剂溶胀到橡胶颗粒中，并引入乳化剂并升高反应器的温度以引发聚合反应， 从而产生第一共聚物胶乳; 和（ii）在反应器中在第一接枝共聚物胶乳存在下引入氧化还原型催化剂混合物和聚合引发剂，将混合物搅拌5-10分钟，混合90-70重量％的残余接枝单体混合物和分子量控制剂 在2-5小时内连续引入后者混合物，同时将聚合引发剂同时进行2-5小时，以使接枝单体和聚合引发剂接枝反应，从而制备第二共聚物胶乳。
-
Patent Agency Ranking
公开(公告)号：KR1020000055262A
公开(公告)日：2000-09-05
申请号：KR1019990003788
申请日：1999-02-04
Applicant: 제일모직주식회사
IPC: C08F2/22
CPC classification number: C08F212/10 , C08F2/22 , C08F2/38
Abstract: PURPOSE: A method for preparing a thermoplastic resin having good high impact property and natural color is provided to obtain a thermoplastic resin that maintains excellent gloss and flow property of ABS resin and has improved high impact property and natural color. CONSTITUTION: A method for preparing a thermoplastic resin having good high impact property and natural color according to the present invention comprises mixing and processing a graft copolymer and SAN resin to obtain a thermoplastic resin wherein the method is characterized by comprising the steps: a) first graft reacting step wherein 40 to 60 parts by weight of rubber latex which has average particle diameter of graft copolymer between 0.25 and 0.34 micrometer and 70 to 90% of gel content is copolymerized with 60 to 40 parts by weight of graft monomer mixture comprising styrene and acrylonitrile in the presence of a liposoluble initiator inside the rubber; and b) second graft copolymerizing step wherein the said graft reacted copolymer envelops the surfaces of rubber particles in the presence of a water-soluble pyrolysis initiator.
Abstract translation: 目的：提供一种制备具有良好的高冲击性和自然色的热塑性树脂的方法，以获得保持ABS树脂优异的光泽和流动性并且具有改善的高冲击性和自然色的热塑性树脂。 构成：根据本发明的制备具有良好的高冲击性和天然色的热塑性树脂的方法包括混合和加工接枝共聚物和SAN树脂以获得热塑性树脂，其中该方法的特征在于包括以下步骤：a）第一 接枝反应步骤，其中将40至60重量份的接枝共聚物的平均粒径为0.25至0.34微米和70至90％的凝胶含量的橡胶胶乳与60至40重量份的包含苯乙烯和 在橡胶中存在可溶性引发剂的丙烯腈; 和b）第二接枝共聚步骤，其中所述接枝反应的共聚物在水溶性热解引发剂的存在下包封橡胶颗粒的表面。
-
公开(公告)号：KR1020110077195A
公开(公告)日：2011-07-07
申请号：KR1020090133689
申请日：2009-12-30
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided to ensure excellent impact resistance by chlorinated polyethylene within an acrylonitrile-chlorinated polyethylene-styrene resin and high compatibility with brominated diphenylethanes and acrylonitrile-butadiene-styrene-based resins. CONSTITUTION: A flame retardant thermoplastic resin composition comprises 100 parts by weight of a base resin and 5-40 parts by weight of a brominated diphenylethanes mixture. The base resin includes 50~90 weight% of an acrylonitrile-butadiene-styrene resin and 5~40 weight% of an acrylonitrile-chlorinated polyethylene-styrene resin. The composition includes 1-6 parts by weight of antimony trioxide based on 100 parts by weight of a base resin. The acrylonitrile-butadiene-styrene resin comprises 10~20 parts by weight of a diene-based rubber, 40~60 parts by weight of a vinyl aromatic compound, and 20~30 parts by weight of a vinyl cyanide compound.
Abstract translation: 目的：提供阻燃热塑性树脂组合物，以确保丙烯腈 - 氯化聚乙烯 - 苯乙烯树脂内的氯化聚乙烯具有优异的抗冲击性，并与溴化二苯乙烷和丙烯腈 - 丁二烯 - 苯乙烯基树脂具有高相容性。 构成：阻燃热塑性树脂组合物包含100重量份的基础树脂和5-40重量份的溴化二苯乙烷混合物。 基础树脂包括50〜90重量％的丙烯腈 - 丁二烯 - 苯乙烯树脂和5〜40重量％的丙烯腈 - 氯化聚乙烯 - 苯乙烯树脂。 基于100重量份的基础树脂，该组合物包含1-6重量份的三氧化锑。 丙烯腈 - 丁二烯 - 苯乙烯树脂包含10〜20重量份的二烯系橡胶，40〜60重量份的乙烯基芳香族化合物和20〜30重量份的乙烯基氰化合物。
-
公开(公告)号：KR1020110076686A
公开(公告)日：2011-07-06
申请号：KR1020090133443
申请日：2009-12-29
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided to ensure excellent weather resistance and low gloss property and to avoid the deterioration of impact resistance and fluidity. CONSTITUTION: A low gloss thermoplastic resin composition includes (A) 30~80 weight% of an acrylic grafted copolymer resin in which the rubber particle diameter is 0.3~0.8 micron and (B) 20~70 weight% of an aromatic vinyl-cyanide vinyl copolymer resin. In the acrylic grafted copolymer resin, 40~70 weight% of the aromatic vinyl-cyanide vinyl copolymer is graft-polymerized with 30~60 weight% of acrylic rubbers. The vinyl cyanide monomer is selected from the group consisting of acrylonitrile, methacrylonitrile, ethacrylonitrile and a mixture thereof.
Abstract translation: 目的：提供热塑性树脂组合物以确保优异的耐候性和低光泽性，并且避免耐冲击性和流动性的劣化。 构成：低光泽热塑性树脂组合物包含（A）30〜80重量％的丙烯酸接枝共聚物树脂，其中橡胶粒径为0.3〜0.8微米，（B）20〜70重量％的芳族乙烯基 - 氰化物乙烯基 共聚树脂。 在丙烯酸接枝共聚物树脂中，40〜70重量％的芳族乙烯基氰化物乙烯基共聚物与30〜60重量％的丙烯酸橡胶接枝聚合。 乙烯基氰单体选自丙烯腈，甲基丙烯腈，乙基丙烯腈及其混合物。
-
公开(公告)号：KR100887316B1
公开(公告)日：2009-03-06
申请号：KR1020070130674
申请日：2007-12-14
Applicant: 제일모직주식회사
Abstract: A high weather resistant and heat-resistant thermoplastic resin composition is provide to improve injection stability and colorability, and to maintain the properties like weather resistance and impact strength by adding a maleimide heat-resistant resin to a blend consisting of an acryl graft-copolymer, a diene graft-copolymer, and vinyl cyanide-aromatic vinyl-heat resistant alpha-methylstyrene ter-polymer. A high weather resistant and heat-resistant thermoplastic resin composition comprises (A) an acrylic graft copolymer 20-50 weight% which is grafted with a monomer mixture consisting of an aromatic vinyl compound and a vinyl cyanide compound to the acrylic rubber; (B) a diene-based graft copolymer 5-10 weight% which is grafted with a monomer mixture consisting of an aromatic vinyl compound and a vinyl cyanide compound to the diene-based rubber; (C) vinyl cyanide-aromatic vinyl copolymer 20-50 weight%; (D) an alpha-methyl styrene-based compound 10-20 weight% which is a terpolymer copolymerized with an aromatic vinyl compound, a vinyl cyanide compound and an alpha-methyl styrene compound; and (E) a copolymer 5-10 weight% of an N-substituted maleimide compound and an aromatic vinyl compound.
Abstract translation: 提供高耐候性和耐热性的热塑性树脂组合物以提高注射稳定性和着色性，并且通过向由丙烯酸接枝共聚物组成的共混物中加入马来酰亚胺耐热树脂来保持耐候性和冲击强度的性能， 二烯接枝共聚物和乙烯基氰 - 芳族乙烯基耐热α-甲基苯乙烯三元共聚物。 高耐候性和耐热性热塑性树脂组合物包含（A）20-50重量％的丙烯酸接枝共聚物，其与由芳族乙烯基化合物和乙烯基氰化合物组成的单体混合物接枝到丙烯酸橡胶上; （B）5-10重量％的二烯基接枝共聚物，其与由芳族乙烯基化合物和乙烯基氰化合物组成的单体混合物接枝到二烯基橡胶上; （C）乙烯基氰 - 芳族乙烯基共聚物20-50重量％; （D）与芳族乙烯基化合物，乙烯基氰化合物和α-甲基苯乙烯化合物共聚的三元共聚物的α-甲基苯乙烯基化合物10-20重量％ 和（E）5-10重量％的N-取代马来酰亚胺化合物和芳族乙烯基化合物的共聚物。
-
公开(公告)号：KR100806123B1
公开(公告)日：2008-02-22
申请号：KR1020050120597
申请日：2005-12-09
Applicant: 제일모직주식회사
IPC: C08F279/04 , C08F279/02
Abstract: 본 발명에 따른 열가소성 수지 조성물의 제조 방법은 (ⅰ) 부타디엔계 고무질 중합체에 이온교환수 및 반응성 유화제를 반응기에 투입하고, 방향족비닐 단량체와 시안화비닐 단량체로 이루어진 단량체 혼합물과 분자량 조절제를 넣고 교반하면서 승온하여 55∼65℃에 이르면 가교제, 그라프트제 및 지용성 열분해 개시제를 첨가하여 중합을 개시하여 1차 그라프트 ABS를 제조하고; 그리고 (ⅱ) 상기 1차 그라프트 ABS의 존재 하에 수용성 개시제를 투입하여 교반한 다음 상기 단량체 혼합물 및 분자량 조절제를 2∼5 시간에 걸쳐 투입하여 2차 그라프트 반응을 하여 그라프트 아크릴로니트릴-부타디엔-스티렌(g-ABS) 공중합체를 제조하는 단계를 포함하여 이루어진다.
열가소성 수지, 그라프트 ABS, 반응성 유화제, 유화중합, 저휘발성, 사출체류 변색성,
-
-
-
-
-
-
-
-
-
Search Results
33
records
(took 0.024 seconds)
