Abstract:
본 발명에 따른 절연 전도성 미립자는 평균입경 1∼10 ㎛ 크기의 기재수지 미립자(41)의 표면에 0.01∼0.1 ㎛ 두께의 니켈 층(42) 및 0.03∼0.3 ㎛ 두께의 금 층(43)이 순차적으로 도금되어 있고, 상기 금 층 표면에 0.05∼1 ㎛ 두께의 무기절연층(44, 45)이 연속적 또는 불연속적으로 피복된 것을 특징으로 한다. 또한, 본 발명에 따른 이방전도성 필름은 상기 절연 전도성 미립자를 10,000∼80,000 개/㎟ 함유하는 것을 특징으로 한다.
Abstract:
본 발명에 따른 완전 상호침투 가교(Full-IPN) 구조를 갖는 고분자 미립자는 장쇄형 가교제, 단량체, 유용성 개시제, 및 분산 안정제를 알코올에 용해하여 분산중합한 후, 세척·건조하여 가교 시드(seed) 입자를 제조하고; 상기 가교 시드 입자를 유화제가 용해된 수용액에 재분산시켜 시드 분산체를 제조하고; 유용성 개시제가 용해된 2차 가교 단량체 및 공중합 단량체를 함께 유화제가 용해된 수용액에 별도로 유화시킨 후, 상기 시드 분산체에 첨가하여 팽윤시켜 고분자 분산체를 제조하고; 그리고 상기 고분자 분산체를 분산 안정제를 이용하여 안정화시켜 중합한 후, 세척·건조하는 단계를 포함하여 제조되는 것을 특징으로 한다. 아울러 본 발명에 따른 완전 상호침투 가교 구조를 갖는 고분자 미립자를 이용하여 액정 표시 장치(LCD)용 스페이서(spacer)를 제조할 수 있다.
Abstract:
본 발명의 단분산성 고분자 입자는 단량체, 다관능성 가교 단량체, 지용성 개시제, 혼합조성의 연속상 용제, 분산안정제 및 보조 분산안정제를 첨가하여 50-90 ℃의 온도범위에서 5-50 시간 동안 분산중합하여 제조되고, 상기 다관능성 가교 단량체는 단량체 전체 중량에 대하여 최소 10 중량%이상 투입되며, 상기 혼합조성의 연속상 용제는 알코올과 에테르알코올의 혼합물 또는 알코올과 벤젠계 용제와의 혼합물인 것을 특징으로 한다.
Abstract:
PURPOSE: A method for preparing a monodisperse functional particle is provided, to obtain a polymer composite particle having various particle structures by controlling the morphology of monodisperse polymer particles. CONSTITUTION: The method comprises the steps of dissolving a monomer, an oil-soluble and a stabilizer in an alcohol and dispersion polymerizing it to prepare a seed particle; re-dispersing the seed particle in the aqueous phase where an emulsifier is dissolved, introducing a swelling agent into the seed dispersed one to swell it, and introducing the monomer where an initiator is dissolved into the seed dispersed one to swell it; and stabilizing the swollen polymer particle by using a dispersion stabilizer and polymerizing the stabilized one. Preferably a crosslinking agent is added in the first step, and the crosslinking agent is a polydimethylsiloxane-based one represented by the formula 1 or 2 (wherein R' is H or CH3 and n is an integer of 5-600); vinyl-terminated or acrylate-terminated polyoxyethylene glycol-based one, polyoxypropylene glycol-based one, or polytetramethylene glycol-based one having a molecular weight of about 500-10,000; or a reactive crosslinking agent selected from epoxy acrylate and urethane acrylate.
Abstract:
The present invention relates to a coating composite having excellent heat resistance and drying processing property by using polyamic acid with high heat-resistance and excellent solubility to a low boiling point solvent. Particularly, the present invention relates to a coating composite containing polyamic acid and a low boiling point solvent of a low boiling point of less than 150 °C. Also, the present invention relates to an electrochemical battery with improved thermal stability by using a separator of which heat resistance is improved by performing a coating process on one or both sides of a polyolefin based base film. [Reference numerals] (AA) Comparative example 1; (BB) Example 1
Abstract:
The present invention relates to a coating agent composition with improved heat resistance and drying performance using polyamic acid with improved solubility in a low boiling solvent and high thermal resistance and more specifically, to a coating agent composition including polyamic acid and a low boiling solvent with a boiling point of less than 150 deg. C. Moreover, the present invention relates to a separator which provides improved heat resistance by coating one or both surfaces of a polyolefin-based base film with the coating agent composition, and an electrochemical cell which provides improved thermal stability using the separator. [Reference numerals] (AA) Comparative example 1; (BB) Example 1
Abstract:
An insulated conductive particle is provided to facilitate removal of an insulation layer upon the connection to an electrode, and to realize excellent conductivity along the z-axis and insulation property in the xy plane direction, as well as high insulation and conduction reliability and solvent resistance. An insulated conductive particle comprises: a conductive particle(10) having a protrusion, which comprises a matrix particle(11), a first metal layer(12) coated on the surface of the matrix particle, a protrusion(13) formed discontinuously on the surface of the first metal layer, and a second metal layer(14) formed on the surface of the first metal layer having the protrusion; and an insulation particle(2) fixed discontinuously to the surface of the conductive particle having a protrusion. The insulation particle has a diameter larger than the height of the protrusion, and 20% or less of the diameter of the conductive particle having a protrusion. Upon the connection to an electrode, the insulation particle is removed from its original position so that the conductive particle having a protrusion and an electrode make electric connection with each other.
Abstract:
A method for preparing a toner, and a toner prepared by the method are provided to omit a washing process by using an alkali-soluble polymer as a polymer emulsifier, thereby decreasing the manufacturing process and reducing the amount of waste water remarkably. A method for preparing a toner comprises the steps of dissolving an alkali-soluble polymer in an alkaline aqueous solution; mixing a colorant and a wax with the alkaline aqueous solution and polymerizing it to prepare a polymer latex particle; coagulating the polymer latex particle in the absence of an emulsifier, a colorant and a wax; and separating the polymerized toner and drying it. Preferably the alkali-soluble polymer is any one selected from the group consisting of an ethylene-acrylic acid copolymer, a styrene-acrylic acid copolymer and a styrene-maleic acid copolymer.