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公开(公告)号：JPH01288341A
公开(公告)日：1989-11-20
申请号：JP11842688
申请日：1988-05-16
Applicant: AGENCY IND SCIENCE TECHN
Inventor： MATSUDA AKIO , MASUDA TAKASHI , MURATA KAZUHISA , NIWA SHUICHI
Abstract: PURPOSE:To obtain a catalyst, which is easy in separation, recovering and recycling after a reaction and capable of producing an aldehyde selectively under a mild condition by using a metal such as stainless steel etc. as a carrier and by making the carrier support rhodium. CONSTITUTION:A metal such as stainless steel or chrome-nickel alloy is used as a carrier of catalyst. This metal is allowed to react with a soluble rhodium compound such as rhodium acetylacetonate etc. in a solvent under pressurized synthesis gas. Solid catalyst for a liquid phase hydroformylation reaction thus obtained is easy in separation, recovering and recycling after the reaction, and capable of producing an aldehyde selectively under a mild condition.
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公开(公告)号：JP2001019747A
公开(公告)日：2001-01-23
申请号：JP19378899
申请日：1999-07-07
Applicant: AGENCY IND SCIENCE TECHN , MASUDA TAKASHI , NAKAYAMA KAZUO
Inventor： MASUDA TAKASHI , SO AMIN , NAKAYAMA KAZUO
IPC: C08G63/00 , C08G63/16 , C08G63/695 , C08L101/16
Abstract: PROBLEM TO BE SOLVED: To produce the subject polymer having the melting temperature to a practically sufficient extent and capable of exhibiting an excellent color tone and an excellent mechanical strength by including plural specific ester parts and further a silicon-containing connecting group derived from a silicon compound in a specific proportion. SOLUTION: This polymer comprises an ether group-containing ester group represented by formula I (R5 is a 1-10C ether group-containing bifunctional aliphatic group; R6 is a 4-12C ether-containing bifunctional aliphatic group; t is 0 or 1) and at least one kind of ester part selected from an oxycarboxylic acid ester part represented by formula II (R3 is a 1-12C bivalent aliphatic group) and a carbonic acid ester part represented by formula III and further a silicon- containing connecting group derived from a silicon compound having a silicon bond represented by SiOR (R is H or an organic group) or forming the silicon bond during a reaction in an amount of 1×107 to 0.1 molar fraction based on the total ester groups in the molecular chain. The polymer is capable of exhibiting biodegradability and chemical recyclability.
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公开(公告)号：JP2000087006A
公开(公告)日：2000-03-28
申请号：JP25962898
申请日：1998-09-14
Applicant: AGENCY IND SCIENCE TECHN
Inventor： ISHIGAMI YUTAKA , SAKAGUCHI HIROSHI , MASUDA TAKASHI , ITO SHOJI , UCHIYAMA HIROO , CHO YAKUGUN
IPC: C09K3/00
Abstract: PROBLEM TO BE SOLVED: To obtain a gelatinizer having biodegradability and high safety to living organism by reacting spiculisporic acid with a basic compound to produce a neutral salt. SOLUTION: This gelatinizer comprises a compound represented by the formula (wherein X is mutually same or different from each other and a metal atom or a group selected from the group consisting of an alkaline earth metal, Li, Al and an arginine residue; and (n) is 1 or 2). The galatinizer is usually used as an aqueous solution. The concentration of the compound of the formula in the aqueous solution is preferably 20 wt.% or below, more preferably 0.5-10 wt.%. To spiculisporic acid [(4S,5S)-4,5-dicarboxyl-4-pentadecanolide] is added an aqueous solution of a basic compound in excess of a calculated amount, and the resulting product is heated to obtain the compound of the formula which has the structure of ring operating of a lactone ring. An oil phase component and alcohol capable of gelation using this gelatinizer are monovalent alcohol, polyvalent alcohol, oil such as hydrocarbons, or the like.
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24.发明专利
公开(公告)号：JP2000086541A
公开(公告)日：2000-03-28
申请号：JP25792898
申请日：1998-09-11
Applicant: AGENCY IND SCIENCE TECHN
Inventor： SAKAGUCHI HIROSHI , KAKU TAMAHO , ISHIGAMI YUTAKA , MASUDA TAKASHI
Abstract: PROBLEM TO BE SOLVED: To provide a method for making a liquid or gas state organic compound as a solid state material, and a method for taking the organic material out as an original state from the above solid state material. SOLUTION: This method for solidifying a hydrocarbon is provided by bringing an aliphatic saturated carboxylic acid metal salt dissolved emulsified or suspended in water in contact with an organic compound to form a solid state aggregate with the organic compound. The method for regenerating the organic compound is provided by heating the above solid state aggregate for decomposition to obtain the organic compound.
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公开(公告)号：JPH11172021A
公开(公告)日：1999-06-29
申请号：JP36367797
申请日：1997-12-16
Applicant: AGENCY IND SCIENCE TECHN , NAKAYAMA KAZUO , MASUDA TAKASHI
Inventor： NAKAYAMA KAZUO , MASUDA TAKASHI
Abstract: PROBLEM TO BE SOLVED: To provide a polymer film which mainly comprises polybutylene succinate and has a good transparency and mechanical strength. SOLUTION: An aliphatic polyester film is a film which comprises an aliphatic polyester containing an ester bond of the formula: -[O(CH2 )4 OCO(CH2 )2 CO]- as a main component at the principal chain and has a sonic elastic modulus at 25 deg.C of 1.5 GPa or larger and a haze value of 40% or smaller. The aliphatic polyester film is produced by molding an aliphatic polyester containing the ester bond represented by the formula as a main component at the principal chain into a film form, and rolling the obtained film at a temperature higher than the glass transition temperature of the aliphatic polyester but lower than the melting point thereof, to obtain a film having a sonic elastic modulus at 25 deg.C of 1.5 GPa or larger and a haze value of 40% or smaller.
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Patent Agency Ranking
公开(公告)号：JPH11166044A
公开(公告)日：1999-06-22
申请号：JP34856497
申请日：1997-12-03
Applicant: AGENCY IND SCIENCE TECHN , RES INST INNOVATIVE TECH EARTH , DAICEL CHEM , TOPPAN PRINTING CO LTD
Inventor： MASUDA TAKASHI , ASAI MICHIHIKO , IKEDA YOSHIKAZU , IMADA YASUKI , KAJIKAWA YASUTERU , TANIGUCHI MASAYUKI , MATSUDA AKIO
IPC: C08G63/16 , C08G63/60 , C08G63/66 , C08G63/672 , C08L101/16
Abstract: PROBLEM TO BE SOLVED: To obtain the subject polyesterether having a novel structure and a practically sufficiently high melting temperature and excellent in a mechanical strength and workability, in an industrially advantageous manner by making the polyesterether include specific 3 kinds of ester parts. SOLUTION: This polyesterether is obtained by including (A) an ester part of formula I (R is an 1-12C bivalent aliphatic; R is a 2-12C bivalent aliphatic; (t) is 0 or 1; and (p) is the molar ratio of an ester part of formula I in the polyester ether), (B) an ether group-containing ester part of formula II (R is H or an acyl; (n) is a mean degree of polymerization, i.e., >=1; and (q) is a molar ratio of the ester part of formula II, i.e., 0.0005 to 0.005), and (C) an ester part of formula III (R is an 1-12C bivalent aliphatic; and (f) is a molar ratio of an ester part of formula III in the polyester ether, i.e., 0.02 to 0.3).
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公开(公告)号：JPH08311181A
公开(公告)日：1996-11-26
申请号：JP14543895
申请日：1995-05-19
Applicant: AGENCY IND SCIENCE TECHN , CHIKYU KANKYO SANGYO GIJUTSU
Inventor： TAKAHASHI IKUO , KAWAMOTO KENJI , MATSUDA AKIO , MASUDA TAKASHI
IPC: C08G63/60 , C08L101/16
Abstract: PURPOSE: To obtain a biodegradable aliphatic copolymer having moldability and processability. CONSTITUTION: This biodegradable high-molecular weight aliphatic copolymer comprises an ester part shown by the general formula (OC-R1 -COO-R2 -O)p (R1 is a 1-12C bifunctional aliphatic group; R2 is a 2-12C aliphatic group; (p) is a molar fraction) and an ester part of the general formula (OC-R3 -O)q (R3 is a 1-10C bifunctional aliphatic group; q is a molar fraction), has a p value of 0.02-0.30 and 15,000-80,000 number-average molecular weight and is obtained by subjecting (A) an aliphatic dicarboxylic acid or an aliphatic dicarboxylic acid diester, (B) an aliphatic diol and (C) a hydroxycarboxylic acid, a hydroxycarboxylic acid ester or a lactone to polycondensation in the presence of a catalyst.
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公开(公告)号：JPH08168800A
公开(公告)日：1996-07-02
申请号：JP22731294
申请日：1994-08-29
Applicant: AGENCY IND SCIENCE TECHN , MINI PUBLIC WORKS , ORGANO KK
Inventor： YOKOYAMA SHINYA , OGI TOMOKO , TSUCHIDE YUTAKA , MINOWA TOMOAKI , YASUNAKA TOKUJI , SATO KAZUAKI , MASUDA TAKASHI , NAKAMURA TADASHI , SUZUKI AKIRA , ITO SHINJI
Abstract: PURPOSE: To provide a method for efficiently incinerating an org. sludge assuming a solid state. CONSTITUTION: In the incinerating method of the org. sludge assuming a solid state, the org. sludge is kept at >=150 deg.C and under a pressure higher than saturated vapor pressure of a temp. concerned to be fluidized, and this fluidized matter under high temp. and high pressure is subjected to flash depressurization and the resultant flash depressurized residue is incinerated.
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公开(公告)号：JPH0827062A
公开(公告)日：1996-01-30
申请号：JP19196494
申请日：1994-07-22
Applicant: AGENCY IND SCIENCE TECHN , CHIKYU KANKYO SANGYO GIJUTSU
Inventor： MATSUDA AKIO , MASUDA TAKASHI , TAKAHASHI IKUO , KAWAMOTO KENJI
Abstract: PURPOSE:To obtain the subject compound under mild conditions in high yield in a significantly advantageous way in terms of cost, by using, as catalyst, a complex composed of cobalt carbonyl and a pyridine base so as to enable both the catalyst and solvent used in the reaction to be easily circulated and reused. CONSTITUTION:This compound is obtained by reaction between (A) an acrylic lower alkyl ester, (B) hydrogen-contg. carbon monoxide and (C) a lower saturated aliphatic monohydric alcohol in (D) a solvent, a mixture of (1) an aromatic hydrocarbon and (2) a saturated aliphatic hydrocarbon in the presence of (E) a catalyst, a complex composed of (3) cobalt carbonyl and (4) a pyridine base. It is preferable that the resultant reaction liquor is cooled to enough low temperatures to cause phase separation of the component (E) in the liquor; this component (E) is separated as a catalytic liquor and reused as a catalyst for the reaction; the component (D) is a mixture at the weight ratio (1)/(2) of 1:(1.5-10), and the component (4) is a 3-alkylpyridine.
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公开(公告)号：JPH06124826A
公开(公告)日：1994-05-06
申请号：JP18021391
申请日：1991-06-25
Applicant: AGENCY IND SCIENCE TECHN
Inventor： MURATA KAZUHISA , MATSUDA AKIO , MASUDA TAKASHI
IPC: H01F1/10 , C07C211/14 , G03G9/083 , H01F1/00 , H01F1/42
Abstract: PURPOSE:To provide a stable organic magnetic body which is easily manufactured, having high saturation magnetization, by making it consist of a carbide in which an organic compound, composition ratio of hydrogen and carbon is specific value, is on the progress to graphite, and further, hydrogen atom of the specific percentage is contained. CONSTITUTION:An amorphous carbide of organic compound, on the progress to graphite, in which composition ratio of hydrogen and carbon is 1.7 or more is manufactured. The carbide contains 1-50 hydrogen atoms per 100 carbon atoms. The organic compound, here, is aliphatic hydrocarbon or cycloparaffin, or, crown compound, aza compound, or alkylamine. So the organic magnetic body, consisting of amorphous carbide of specific compound, is, in addition to its light weight, stable and easy in manufacture, and it is capable of having high saturation magnetization.
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