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公开(公告)号:AT278713T
公开(公告)日:2004-10-15
申请号:AT01965130
申请日:2001-07-13
Applicant: BASF AG
Inventor: DUIJZINGS WIL , OEPEN SABINE , NIESSNER NORBERT , BREULMANN MICHAEL , KORB HARDY
IPC: C08C1/07
Abstract: A process for the agglomeration of at least one rubber (A), dispersed in an aqueous phase, by the addition of a dispersion of at least one agglomerating polymer (B) in aqueous phase, in which the agglomerating polymer B used is one containing substantially no free acid groups and the agglomeration is carried out in the presence of at least one basic electrolyte.
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公开(公告)号:DE10040435A1
公开(公告)日:2002-02-28
申请号:DE10040435
申请日:2000-08-18
Applicant: BASF AG
Inventor: NIESNER NORBERT , BREULMANN MICHAEL , GUENTHERBERG NORBERT , MC KEE GRAHAM EDMUND , OEPEN SABINE , DUIJZINGS WIL
IPC: C08F2/24 , C08F236/06 , C08F220/18 , C08J5/00
Abstract: Production of elastomer particles by emulsion polymerization of ethylenically unsaturated monomers, comprises using an emulsifier with a critical micelle concentration (cmc) of at least 10 mole/liter. Production of elastomer particles comprises: (a) emulsifying ethylenically unsaturated monomers, the homo- or copolymers of which have a glass transition temperature (Tg) below 0 deg C, in water under shearing action in the presence of an emulsifier with a cmc of at least 10 mole/liter and a water-soluble initiator; and (b) heating the emulsion to initiate polymerization, optionally with addition of further monomers for grafting.
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公开(公告)号:AU8584101A
公开(公告)日:2002-02-13
申请号:AU8584101
申请日:2001-07-13
Applicant: BASF AG
Inventor: DUIJZINGS WIL , OEPEN SABINE , NIESSNER NORBERT , BREULMANN MICHAEL , KORB HARDY
IPC: C08C1/07
Abstract: A process for the agglomeration of at least one rubber (A), dispersed in an aqueous phase, by the addition of a dispersion of at least one agglomerating polymer (B) in aqueous phase, in which the agglomerating polymer B used is one containing substantially no free acid groups and the agglomeration is carried out in the presence of at least one basic electrolyte.
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公开(公告)号:DE10037280A1
公开(公告)日:2002-02-07
申请号:DE10037280
申请日:2000-07-28
Applicant: BASF AG
Inventor: DUIJZINGS WIL , OEPEN SABINE , NIESNER NORBERT , BREULMANN MICHAEL , KORB HARDY
Abstract: The invention relates to a method for agglomerizing at least one dispersed rubber (A) in an aqueous phase by adding a dispersion of at least one agglomeration polymer (B) in the aqueous phase. The invention is characterised by using an agglomeration polymer as B, containing essentially no free acid groups and by carrying out the agglomerization in the presence of at least one basic electrolyte.
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公开(公告)号:DE10030636A1
公开(公告)日:2002-01-10
申请号:DE10030636
申请日:2000-06-29
Applicant: BASF AG
Inventor: DUIJZINGS WIL , BARGHOORN PETER , DAMES BURKHARDT
Abstract: A thermoplastic molding composition (I) comprises (A) 99-100 wt.% (minus 1 ppb) of a styrene homo- or copolymer (B) 1 ppb-1 wt.% of a polyethyleneimine homo or copolymer and (C) 0-50 wt.% (w.r.t A and B) conventional additives and processing aids. Independent claims are included for (i) molded articles, film, fiber and foam prepared using the molding composition (I) (ii) a process for increasing the impact strength of styrene homo- or copolymers by the addition of 1 ppb-1 wt.% of a polyethylene imine homo- or copolymer (B).
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公开(公告)号:DE10013733A1
公开(公告)日:2001-09-27
申请号:DE10013733
申请日:2000-03-21
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , CZAUDERNA BERNHARD , BREULMANN MICHAEL , OEPEN SABINE , DUIJZINGS WIL , NIESNER NORBERT
IPC: C08F2/00 , C08F2/22 , C08F2/24 , C08F36/00 , C08F36/04 , C08F36/06 , C08F236/04 , C08F212/08 , C08F220/18 , C08F220/44
Abstract: A process for the production of rubber particles containing 80-100 wt.% of a conjugated diene monomer and 0-20 wt.% of a monoethylenically unsaturated comonomer comprises emulsion polymerization in the presence of an emulsifier and an initiator whereby the monomers are added either in polymerized form as a seed latex or in monomeric form via subsequent in-situ polymerization to form a seed latex. A process for the production of rubber particles (I) containing in polymerized form (A) 80-100 wt.% of at least one conjugated diene monomer and (B) 0-20 wt.% of at least one monoethylenically unsaturated comonomer, comprises emulsion polymerization in the presence of an emulsifier and an initiator whereby: (1) a mixture (M1) comprising (M1a) 20-100 wt.% water and (M1b) 0.1-100 wt.% emulsifier is added; (2) simultaneously or thereafter a mixture (M2) comprising (M2a) 90-100 wt.% of styrene, alpha -methylstyrene, butadiene, n-butylacrylate, methylmethacrylate and/or acrylonitrile and (M2b) 0-10 wt.% of at least one copolymerizable monomer whereby monomers (M2a) and (M2b) are added either in polymerized form as a seed latex or in monomeric form via subsequent in-situ polymerization to form a seed latex, or as a mixture of polymerized and monomeric forms, whereby the seed-latex polymer has an average mol. wt. of greater than 2000; (3) the polymerization of the resulting mixture is initiated in the presence of the polymerization initiator at 5-95 [deg]C; (4) simultaneously or thereafter a mixture (M3) comprising (M3a) 0-100 wt.% comonomer (B) (wrt (B)) and (M3b) 0-25 wt.% diene monomer (A) (wrt (A)) is added; (5) simultaneously or thereafter a mixture (M4) comprising (M4a) the residual 75-100 wt.% (A) (wrt (A)) and (M4b) the residual 0-100 wt.% (B) (wrt (B)); and (6) polymerization is carried out to a conversion of 90-95 (wrt the total amount of monomers) whereby the residual 0-80 wt.% of the emulsion water and the residual 0-99.9 wt.% of the emulsifier are added individually or separately at one or more steps (2)-(5). An independent claim is included for the resulting rubber particles (I).
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公开(公告)号:DE19951648A1
公开(公告)日:2001-05-03
申请号:DE19951648
申请日:1999-10-27
Applicant: BASF AG
Inventor: OEPEN SABINE , NIESNER NORBERT , BREULMANN MICHAEL , GUENTHERBERG NORBERT , DUIJZINGS WIL
Abstract: The invention relates to a method for reducing undesired coloration changes (Cold Stress Whitening) in impact-resistant thermoplastic moulding compounds (F), caused by low temperatures. Said moulding compounds contain at least one elastomeric graft polymer (A) and at least one thermoplastic polymer (B). According to the invention, 10 to 200 ppm of at least one polyorganosiloxane (S), based upon the moulding compounds (F) is added to said impact-resistant thermoplastic moulding materials (F).
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