公开(公告)号：JPH1072377A

公开(公告)日：1998-03-17

申请号：JP16283697

申请日：1997-06-19

Applicant: BASF AG

Inventor： RUEHL THOMAS DR ,  BREITSCHEIDEL BORIS DR ,  KONRAD KNOLL ,  WEIGUNY SABINE ,  HENKELMAN JOCHEM ,  NAEGELE PAUL ,  HERMANN GAUSEPOHL ,  NIESNER NORBERT ,  HENNE ANDREAS ,  ROLF REEPUKYUUHIYAA

IPC: B01J23/44 ,  B01J23/46 ,  B01J35/10 ,  C07B35/02 ,  C07B61/00 ,  C07C29/141 ,  C07C29/149 ,  C07C29/20 ,  C07C31/12 ,  C07C31/135 ,  C07C31/20 ,  C07C35/08 ,  C07C35/21 ,  C07C209/72 ,  C07C211/35 ,  C08C19/02 ,  C08F4/70 ,  C08F4/80 ,  C08F8/04 ,  C08F36/06 ,  C08F297/04

Abstract: PROBLEM TO BE SOLVED: To enable the obtaining of a process by which a high yield or a quantitative conversion rate can be achieved by reacting an organic compound in the presence of a catalyst containing a specific metal supported on a specified support. SOLUTION: An organic compound is reacted in the presence of a catalyst comprising (B) ruthenium alone or together with at least one group Ib, IIb or VIIIb as an active metal in an amount of 0.01-30wt.%, based on the total weight of the catalyst applied to (A) a support in which 50-90% of the pore volume of the support comprises mesepores having a pore diameter within the range of 2-50nm and the sum of the pores volumes is 100%. The reaction is preferably hydrogenation, dehydrogenation, hydrogenolysis, etc., especially preferably the hydrogenation. The organic compound is low molecular weight monomers and polymeric organic compounds, etc., which can be catalytically reacted. Thereby, the reaction can be carried out at a high space velocity and an ultrahigh turnover number for a long on-stream time, and a high yield and a high purity of a hydrogenation product can be expected.

公开(公告)号：DE10019215A1

公开(公告)日：2001-10-25

申请号：DE10019215

申请日：2000-04-18

Applicant: BASF AG

Inventor： BARGHOORN PETER ,  SCHAEDLER VOLKER ,  MAAS HEIKO ,  NIESNER NORBERT

IPC: C08F2/00 ,  C08F4/40 ,  C08F279/02 ,  C08F279/04 ,  C08F8/04 ,  C08L51/04 ,  C08J3/20 ,  C08J5/18

Abstract: Graft rubbers comprising a graft core and a graft sheath are prepared by selective hydrogenation of ethylenically unsaturated double bonds of the elastomeric rubber polymer graft core with hydrogen in the presence of a catalyst comprising salts and complex compounds of rhodium and/or ruthenium whereby the aqueous rubber polymer dispersion contains upto 20 vol. % of an organic solvent. Graft rubbers (I) comprising a graft core and a graft sheath are prepared by: (A) preparation of an aqueous dispersion of at least one elastomeric rubber polymer prepared from at least one conjugated diene, optionally at least one copolymerizable monomer, optionally at least one modifying monomer; (B) followed by selective hydrogenation of ethylenically unsaturated double bonds of the elastomeric rubber polymer with hydrogen in the presence of a catalyst comprising salts and complex compounds of rhodium and/or ruthenium whereby the aqueous dispersion of the rubber polymer contains upto 20 vol. % of an organic solvent to prepare the graft core; and (C) grafting at least one graft shell onto the graft core prepared from at least one styrene compound of formula (1), optionally at least one monoethylenically unsaturated nitrile compound and optionally at least further monomer. R , R = H or 1-8C alkyl; n = 0-3 Independent claims are included for: (i) mixtures containing 2-70 wt.% graft rubber (I), 30-98 wt.% of at least one thermoplastic polymer and 0-50 wt.% other additives; and (ii) a process for the production of mixtures by melting the components at 100-350 degrees C.

公开(公告)号：DE10003807A1

公开(公告)日：2001-08-02

申请号：DE10003807

申请日：2000-01-28

Applicant: BASF AG

Inventor： EBERLE WOLFGANG ,  NIESNER NORBERT

IPC: C08L59/02 ,  C08L59/04 ,  C08L59/00 ,  C08L51/06 ,  D01F8/18

Abstract: The invention relates to thermoplastic molding materials containing the following: A) 20 to 99 wt. % of a polyoxymethylene homo- or copolymer; B) 1 to 40 wt. % of a graft polymer with an average particle size of 200 to 1000 nm, consisting of b1) 25 to 95 wt. % of at least one graft base consisting of a rubber elastic polymer with b11) 75 to 95 wt. % of a C1 to C10-alkylacrylate and b12) 0.1 to 5 wt. % of a polyfunctional monomer with at least 2 olefinic, non-conjugated double bonds and b13) 0 to 24.9 wt. % other copolymerisable monomers; and b2) 5-75 wt. % of a terminating, rigid, thermoplastic grafted-on component which is polymerized in the presence of an elastomer phase; and c) 0 to 70 wt. % other additives, the weight percentages of components A) to C) weights totaling 100 %.

公开(公告)号：DE19951679A1

公开(公告)日：2001-05-03

申请号：DE19951679

申请日：1999-10-27

Applicant: BASF AG

Inventor： MC KEE GRAHAM EDMUND ,  GAUSEPOHL HERMANN ,  NIESNER NORBERT ,  GUENTHERBERG NORBERT

IPC: C08F279/02 ,  C08F279/04 ,  C08L55/02 ,  C08L9/00 ,  C08L9/06

Abstract: A process for the production of impact-resistant plastics involves: (a) making crosslinked rubber particles from a monomer mixture (1) containing at least 50 wt.% conjugated diene; (b) adding the rubber particles to another monomer mixture (2) containing at least 85 (preferably at least 90, most preferably at least 98) wt.% styrene and (c) polymerizing mixture 2. An Independent claim is also included for impact resistant plastics obtained by this process.

公开(公告)号：DE19917675A1

公开(公告)日：2000-10-26

申请号：DE19917675

申请日：1999-04-19

Applicant: BASF AG

Inventor： BRINKMANN-RENGEL SUSANNE ,  NIESNER NORBERT ,  SUTORIS HEINZ FRIEDRICH ,  MC KEE GRAHAM EDMUND ,  KNOLL KONRAD ,  CHRISTIE DAVID

IPC: C08F293/00 ,  C08F297/04 ,  C08L53/02 ,  C09D153/02 ,  C08F297/00

Abstract: Preparation of rubber-elastic block copolymer (I), consisting of block (A) formed from vinyl aromatic monomers as rigid phase, or block (B) formed from diene monomers as flexible phase; and block (B)/(A) formed from vinyl aromatic and diene monomers as flexible phase, is claimed. The monomers are polymerized using radical polymerization initiator(s) (II). Preparation of rubber-elastic block copolymer (I), consisting of block(s) (A) formed from vinyl aromatic monomers and having glass transition temperature (Tg) of at least 25 deg C as rigid phase; or block(s) (B) formed from diene monomers as flexible phase; and block(s) (B)/(A) formed from vinyl aromatic and diene monomers and having Tg below 25 deg C as (possibly additional) flexible phase, is claimed. The monomers are polymerized using radical polymerization initiator(s) (II). An Independent claim is included for the polymers (I) obtained by the process.

公开(公告)号：DE102006023585A1

公开(公告)日：2007-01-25

申请号：DE102006023585

申请日：2006-05-19

Applicant: BASF AG

Inventor： BILLOUARD CYRILLE ,  KOCH JUERGEN ,  DESBOIS PHILIPPE ,  NIESNER NORBERT ,  WARZELHAN VOLKER

IPC: C08L25/02 ,  C08J5/00 ,  C08L25/10 ,  C08L55/02 ,  C08L71/02

Abstract: A polymer blend comprises by weight (A) a rubber-free styrene polymer (50-99.9%); (B) an oxirane homopolymer (0.1-50%); (C) a filler (0-30%); and (D) a lubricant, colorant, pigment, flame retardant, antioxidant, UV stabilizer or antistat (0-10%). An independent claim is also included for a blend of the above blend (5-95 wt.%) with a high-impact polystyrene (5-95 wt.%).

公开(公告)号：DE19529402C2

公开(公告)日：2001-11-29

申请号：DE19529402

申请日：1995-08-10

Applicant: BASF AG

Inventor： NIESNER NORBERT ,  HOVE ARNOLD VAN DEN ,  LOHRBAECHER VOLKER

IPC: B32B27/08 ,  B32B27/28 ,  B32B1/02 ,  B32B27/34 ,  C08J5/18 ,  C08L53/02

公开(公告)号：DE10003509A1

公开(公告)日：2001-08-02

申请号：DE10003509

申请日：2000-01-27

Applicant: BASF AG

Inventor： MC KEE GRAHAM EDMUND ,  GAUSEPOHL HERMANN ,  NIESNER NORBERT

IPC: C08F285/00 ,  C08L51/04

Abstract: The invention relates to a method for producing impact resistant plastics on the basis of grafted cross-linked rubber particles. The invention further relates to an impact resistant plastic that is obtained using the inventive method. The method for producing the impact resistant plastic comprises the following steps: (a) producing particles of a cross-linked rubber from a first monomer mixture that has a diene composition content of

公开(公告)号：DE10051363A1

公开(公告)日：2001-05-03

申请号：DE10051363

申请日：2000-10-17

Applicant: BASF AG

Inventor： MCKEE GRAHAM EDMUND ,  NIESNER NORBERT

IPC: C08F261/04 ,  C08F279/02 ,  C08F236/04

Abstract: The production of rubber-elastic polymer particles involves dispersing 20-85 parts by weight (pts. wt.) of a mixture (A) of 60-100 wt.% conjugated diene and 0-40 wt.% comonomer(s) in 15-80 pts. wt. water in presence of 0.1-10 wt% protective colloid and 0-10 wt.% emulsifier (based on A) and polymerizing the dispersed droplets with a radical initiator. Independent claims are also included for: (a) rubber-elastic polymer particles (I) obtained by this process; (b) impact-resistant plastics with a matrix of thermoplastic polymer containing embedded particles of (I).

公开(公告)号：DE19920977A1

公开(公告)日：2000-11-16

申请号：DE19920977

申请日：1999-05-06

Applicant: BASF AG

Inventor： NIESNER NORBERT ,  GOTTSCHALK AXEL ,  SCHOLZ GUENTER ,  BRUENING INES

IPC: C08G18/08 ,  C08G18/66 ,  C08L75/04 ,  C08L51/06 ,  C08L53/00