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    22.
    发明专利
    未知

    公开(公告)号：DE19627909A1

    公开(公告)日：1998-01-15

    申请号：DE19627909

    申请日：1996-07-11

    Applicant: BASF AG

    Inventor： STEUERLE ULRICH DR ,  REUTHER WOLFGANG DR ,  MEIXNER HUBERT DR ,  EHLE MICHAEL DR ,  GREINDL THOMAS DR ,  BETZ RAINER DR

    IPC: B01D53/02 ,  B01J20/26 ,  C02F1/56 ,  C08G73/02 ,  C08G73/04 ,  C08L71/02 ,  B01D53/34 ,  C02F1/62 ,  C07B63/00

    Abstract: Method of manufacturing finely divided, water-insoluble polymers of aziridines by polymerization of aziridines, preferably ethylene-imine, in the presence of two or more functional groups containing cross-linking agents in one or more ethers, as well as modified, water-insoluble polymers of aziridines that can be obtained by reacting finely divided, water-insoluble cross-linked polymers of aziridines in an aqueous medium with carbon disulphide or with formaldehyde and a nucleophilic agent from the group comprising alkali-metal cyanides, primary amines, secondary amines, alkali-metal sulphites, and alkali-metal phosphites, and the use of the modified and unmodified finely divided, water-insoluble polymers for immobilizing active ingredients, as absorbents for aldehydes, ketones and acids, for removing heavy-metal ions from liquid effluents, and for removing ozone and/or sour gases from air or inert gases.

    23.
    发明专利
    未知

    公开(公告)号：DE19518987A1

    公开(公告)日：1996-12-05

    申请号：DE19518987

    申请日：1995-05-29

    Applicant: BASF AG

    Inventor： GREINDL THOMAS DR ,  OFTRING ALFRED DR ,  BRAUN GEROLD DR ,  WILD JOCHEN DR ,  POTTHOFF-KARL BIRGIT DR ,  SCHUH GEORG

    IPC: C07C227/18 ,  C07C227/14 ,  C07C227/16 ,  C07C227/24 ,  C07C227/26 ,  C07C229/16

    Abstract: Prepn. of glycine-N,N-diacetic acid derivs. of formula (I), where R = 1-30C alkyl or 2-30C alkenyl, which can also contain, as substits., up to 5 hydroxyl gps., formyl gps., 1-4C alkoxy gps., phenoxy gps. of 1-4C alkoxycarbonyl gps., and which can be interrupted by up to 5 non-adjacent O atoms, alkoxylate groupings of formula -(CH2)k-O-(A O)m-(A O)n-Y, phenyl alkyl gps. with 1-20C atoms in the alkyl, phenyl, a 5- or 6-membered (un)satd. heterocyclic ring with up to 3 heteroatoms from N, O and S which can also be benzo-condensed, whereby all phenyl cores and heterocyclic rings given for R can also contain as substits. up to 3 1-4C alkyl gps., hydroxyl, gps., carboxyl gps., sulpho gps. or 1-4C alkoxy carbonyl gps., or a gp. of formula (II); A = 1-12C alkylene bridge or a chemical bond; A , A = 2-4C 1,2-alkylene gps.; Y = H, 1-12 C alkyl, phenyl or 1-4 C alkoxycarbonyl; k = 1, 2 or 3; m, n = 0-50; m+n = at least 4; and M = H, alkali metal, alkaline earth metal, ammonium or substd. ammonium in the corresp. stoichiometric quantities, comprises reacting corresp. 2-substd. glycines or 2-substd. glycine nitriles or double glycines of formula (III) or double glycine nitriles of formula (IV) or precursors of the glycine derivs. given as starting materials with formaldehyde and alkali metal cyanide in aq. alkaline medium at a pH of 8-14. The novelty is that 0.5-30 % of the quantity of alkali metal cyanide required for reaction is added to the glycine derivs. or their precursors and then the remaining amt. of alkali metal cyanide and the formaldehyde is added simultaneously over 0.5-12 hrs.

    27.
    发明专利
    未知

    公开(公告)号：ES2145341T3

    公开(公告)日：2000-07-01

    申请号：ES96108081

    申请日：1996-05-21

    Applicant: BASF AG

    Inventor： GREINDL THOMAS DR ,  OFTRING ALFRED DR ,  BRAUN GEROLD DR ,  WILD JOCHEN DR ,  POTTHOFF-KARL BIRGIT DR ,  SCHUH GEORG

    IPC: C07C227/18 ,  C07C227/14 ,  C07C227/16 ,  C07C227/24 ,  C07C227/26 ,  C07C229/16

    Abstract: Prepn. of glycine-N,N-diacetic acid derivs. of formula (I), where R = 1-30C alkyl or 2-30C alkenyl, which can also contain, as substits., up to 5 hydroxyl gps., formyl gps., 1-4C alkoxy gps., phenoxy gps. of 1-4C alkoxycarbonyl gps., and which can be interrupted by up to 5 non-adjacent O atoms, alkoxylate groupings of formula -(CH2)k-O-(A O)m-(A O)n-Y, phenyl alkyl gps. with 1-20C atoms in the alkyl, phenyl, a 5- or 6-membered (un)satd. heterocyclic ring with up to 3 heteroatoms from N, O and S which can also be benzo-condensed, whereby all phenyl cores and heterocyclic rings given for R can also contain as substits. up to 3 1-4C alkyl gps., hydroxyl, gps., carboxyl gps., sulpho gps. or 1-4C alkoxy carbonyl gps., or a gp. of formula (II); A = 1-12C alkylene bridge or a chemical bond; A , A = 2-4C 1,2-alkylene gps.; Y = H, 1-12 C alkyl, phenyl or 1-4 C alkoxycarbonyl; k = 1, 2 or 3; m, n = 0-50; m+n = at least 4; and M = H, alkali metal, alkaline earth metal, ammonium or substd. ammonium in the corresp. stoichiometric quantities, comprises reacting corresp. 2-substd. glycines or 2-substd. glycine nitriles or double glycines of formula (III) or double glycine nitriles of formula (IV) or precursors of the glycine derivs. given as starting materials with formaldehyde and alkali metal cyanide in aq. alkaline medium at a pH of 8-14. The novelty is that 0.5-30 % of the quantity of alkali metal cyanide required for reaction is added to the glycine derivs. or their precursors and then the remaining amt. of alkali metal cyanide and the formaldehyde is added simultaneously over 0.5-12 hrs.

    Complexing agents for textile dyeing and pre- or post- treatment
    28.
    发明专利
    Complexing agents for textile dyeing and pre- or post- treatment 未知

    公开(公告)号：DE19703447A1

    公开(公告)日：1998-08-06

    申请号：DE19703447

    申请日：1997-01-30

    Applicant: BASF AG

    Inventor： POTTHOFF-KARL BIRGIT DR ,  GREINDL THOMAS DR ,  KARL ULRICH DR ,  FREYBERG PETER DR ,  HOIS PIA DR

    IPC: C07C229/16 ,  D06M13/192 ,  D06M13/342 ,  D06P1/647 ,  D06P5/06 ,  D06P5/22

    Abstract: The use of bis-(dicarboxylic acid) diaminoalkylene derivatives of formula (I) as complex-forming agents in textile dyeing and pre- or post-treatment is claimed. In (I), R , R = H, 1-8C alkyl, 2-8C alkenyl, phenyl, benzyl, or 1-4C hydroxyalkyl or hydroxy-halo-alkyl; M = H, alkali metal, ammonium or substituted ammonium; l, m, n = 0-6; A1 = 2-3C alkylene, optionally substituted on one, two or all C atoms with one or two hydroxy, 1-6C alkyl, 2-6C alkenyl, 3-6C cycloalkyl, or 3-8C cycloalkenyl, aryl, alkylaryl, heteroaryl or alkyl-heteroaryl groups. Also claimed are: (i) a process for the pretreatment, post-treatment or dyeing of textiles or textile precursors in the manufacture or processing of textiles, in which the material is subjected to a treatment bath containing 0.01-20 (preferably 0.1-10, more preferably 0.5-3) g/l (I), and (ii) baths used for this process containing (I) in the above amounts.

    Poly:alkyl:amine derivatives
    29.
    发明专利
    Poly:alkyl:amine derivatives 未知

    公开(公告)号：DE19606846A1

    公开(公告)日：1997-08-28

    申请号：DE19606846

    申请日：1996-02-23

    Applicant: BASF AG

    Inventor： JULIUS MANFRED DR ,  ETTL ROLAND DR ,  GUENTHER WOLFGANG DR ,  GREINDL THOMAS DR

    IPC: C07C235/88 ,  C08F8/30 ,  C10L1/22 ,  C10L1/224 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2387 ,  C10L10/00 ,  C10M133/16 ,  C10M133/52 ,  C07D305/12 ,  C08F8/32 ,  C10M133/56 ,  C10M149/00

    Abstract: Polyalkylamine derivatives of formula ZCH2NH2-nHn (I) are new. (where, n = 0 or 1; z = polyalkyl residue of molecular weight 150-40000; Y = residue of formula (IIa) or (IIb); R, R1 and R2 = H, optionally substituted alk(en)yl, alkinyl, and optionally substituted cycloalkyl, aryl(alkyl) having heteroatom(s); A = alkylene imine residues of formula (III); m = 0-10; Alk = optionally substituted alkylene; R3 = H, alk(en)yl, alkinyl, or aryl or when Y is a residue of formula (IIa) keto residue of formula (IVa); in (IVa): R = as above or when Y = group of formula (IIb), is a cyano residue of formula (IVb) (where, R1 and R2 = as above) or when n = 0 one of the residues Y is optionally a polyoxyalkylene residue (V) (where, q = 1-30; Alk = as above; and E = H or 1-6C alkyl). Preparation of the derivatives is also claimed. Also claimed are lubricant and fuel compositions containing the above derivatives.

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