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公开(公告)号:DE19805232A1
公开(公告)日:1999-08-12
申请号:DE19805232
申请日:1998-02-10
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , BLANKENBURG RAINER DR , LEHMANN STEPHAN DR , EHLE BEATE DR , BERTLEFF WERNER DR , LUX JUERGEN ALFRED DR
Abstract: The invention relates to the use of copolymers consisting of (a) between 10 and 95 weight % of at least one non-ionic monomer which has a N-vinyl group and at 25 DEG C has a water solubility of at least 60 g/l, (b) between 5 and 90 weight % of at least one hydrophobic monoethylenically unsaturated monomer which at 25 DEG C has a water solubility of less than 60 g/l, and possibly (c) between 0 and 15 weight % of at least one monoethylenically unsaturated monomer having an ionic or ionisable group and (d) between 0 and 10 weight % of at least one monomer which has at least 2 ethylenically unsaturated groups. Said copolymers are used in detergents, in amounts of between 0.1 and 5 weight % in relation to said detergents, as additive which inhibits greying and promotes dirt removal during washing and as a secondary treatment agent for laundry.
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公开(公告)号:DE19650537A1
公开(公告)日:1998-06-10
申请号:DE19650537
申请日:1996-12-05
Applicant: BASF AG
Inventor: BAUR RICHARD DR , EHLE BEATE DR , BOECKH DIETER DR , SCHUERMANN GREGOR DR , PERNER JOHANNES DR , SCHNEIDER JUERGEN DR , KAHMEN MARTIN AUS DEM DR , BECKER RAINER DR
IPC: C11D1/52 , C07C233/18 , C07C67/08 , C07C69/28 , C07C231/02 , C07C305/10 , C11D1/72 , C11D1/74 , C11D3/386 , C12N9/96 , D06L1/12 , D06M13/419
Abstract: Enzyme stabilisers in washing or cleaning agents comprise end group capped fatty acid amide alkoxylates of formula (I): R -CO-NH-(CH2)n-O-(AO)x-R (I) R = 5-21C alk(en)yl ; R = 1-4C alkyl ; A = 2-4C alkylene ; n = 2-3 ; and x = 1-6. Also claimed are (i) detergents containing 0.1-50 wt.% (I) and 0.1-10 wt.% synthesised enzyme, (ii) mixtures comprising (A) compounds (I) and (B) fatty alcohol (poly)ether sulphates, fatty alcohol (poly)alkoxylates and/or fatty acid (poly)alkoxylates, (iii) the preparation of mixtures comprising (A) compounds (I) and (B`) fatty acid (poly)alkoxylates corresponding to (A) in which -NH- is replaced by O, (iv) the use of these mixtures in detergents, and (v) detergents containing 0.1-50 wt.% of these mixtures.
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公开(公告)号:DE19540645A1
公开(公告)日:1997-05-07
申请号:DE19540645
申请日:1995-10-31
Applicant: BASF AG
Inventor: EHLE BEATE DR , SCHUH GEORG , KAHMEN MARTIN AUS DEM DR , HERTEL DIETER
IPC: B01J19/00 , B01J19/24 , C07C231/02 , C07C233/47 , C07C233/49 , C07C309/15 , C07C233/45
Abstract: The invention concerns a process and device for the continuous preparation of N-acylaminocarboxylic acids and N-acylaminosulphonic acids and their alkali metal salts from the alkali metal salts of aminocarboxylic acids and aminosulphonic acids and carboxylic acid halides in a reactor taking the form of a closed circuit. According to the invention the reactants are fed into the closed circuit for immediate reaction and part of the product solution corresponding to the amount fed in is continuously channelled out of the closed circuit. The reactants are circulated by a circulating pump. The temperature in the reactor is controlled and the heat generated during the reaction is expelled.
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公开(公告)号:DE19624701A1
公开(公告)日:1998-01-02
申请号:DE19624701
申请日:1996-06-20
Applicant: BASF AG
Inventor: EHLE BEATE DR , BAUR RICHARD DR , OETTER GUENTER DR , KAHMEN MARTIN AUS DEM DR , KARL ULRICH DR
IPC: C11D1/10 , C11D1/29 , C11D1/52 , C11D1/66 , C11D1/72 , C11D1/83 , C11D3/08 , C11D3/10 , C11D3/12 , C11D3/33 , C11D17/00 , C11D17/06 , C11D3/02 , C11D3/386 , C11D3/395
Abstract: Phosphate free washing agent comprising (a) 1-60 wt. % of at least one inorganic builder, (b) 0.1-25 wt. % of at least one anionic detergent of formula R -CH(OH)-CH(R )-N(R )-Y-COOM (I) , (c) optionally 0-40 wt. % of at least one further anionic detergent, (d) 0.5-30 wt. % of at least one nonionic detergent, and optionally washing and cleaning agents. R , R = H, aryl, alkyl or alkenyl (both optionally substituted with 1-3 residues selected from aryloxy or alkoxycarbonyl and/or interrupted by 1-5 non-adjacent O atoms), or R and R together with the groups to which they are bound may form the residue of a mono- or polyunsaturated fatty acid which forms, by way of an ester bond, part of a triglyceride, which (depending on the original number of double bonds in its fatty acid residue, having up to 9 groups of formula (I) (sic), R = H, alkyl, -CHR -CH(OH)-R (IIa) or -(CH2)n-COOM (IIb); n = 1-4; R , R = as for R and R , and the sum of the C atoms in R , R , R and R \- 4; Y = alkylene (optionally substituted by OH and/or COOM), or R +N+Y = a 5- or 6-membered, saturated or unsaturated heterocyclic ring; M = H, alkali(ne earth) metal, optionally substituted ammonium.
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公开(公告)号:DE19611977A1
公开(公告)日:1997-10-02
申请号:DE19611977
申请日:1996-03-26
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , STEUERLE ULRICH DR , MEIXNER HUBERT DR , EHLE BEATE DR , PAULUS WOLFGANG DR , LUX JUERGEN ALFRED DR , HAEUSLING LUKAS DR
Abstract: The use of an amine with an average pKs of 1 to 14 as a washing power enhancer, preferably in textile detergents, especially for washing coloureds, and detergent formulations containing said amines.
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公开(公告)号:DE19526501A1
公开(公告)日:1997-01-23
申请号:DE19526501
申请日:1995-07-20
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , KAHMEN MARTIN AUS DEM DR , EHLE BEATE DR , BAUR RICHARD DR , KLINGELHOEFER PAUL DR , SCHNEIDER JUERGEN DR , RULAND ALFRED DR , TRAPP HORST DR , OTT CHRISTIAN DR
IPC: C07C67/31 , C07C69/708 , C09K23/00 , D21H17/06 , D21H21/12 , C07D303/02 , B01D19/04 , C08G65/32 , C11D3/20 , C11D3/37 , C09K7/02 , C14C1/00 , C23G5/00
Abstract: Hydroxy mixed ethers are claimed which are obtd. by ring-opening reaction of unsatd. fatty acid ester epoxides (I) with polyglycol ethers of formula R1-O-(CH2.CHR2.O)n-H (II) in presence of Lewis acids with exclusion of protons (where, R1 = H, 1-30C alkyl or 8-30C alkenyl; R2 = H, Me or Et; and n = 1-50 (R1 not = H) or 2-50 (R1 = H)).
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公开(公告)号:DE19643133A1
公开(公告)日:1998-04-23
申请号:DE19643133
申请日:1996-10-18
Applicant: BASF AG
Inventor: MEIXNER HUBERT DR , STEUERLE ULRICH DR , DECKER JUERGEN DR , PAULUS WOLFGANG DR , BOECKH DIETER DR , LUX JUERGEN ALFRED DR , EHLE BEATE DR
Abstract: The invention concerns the use of water-soluble or water-dispersible cross-linked nitrogenated compounds obtained by crosslinking (a) compounds containing at least three NH groups with (b) at least bifunctional crosslinking agents which react with NH groups, in washing and cleaning agents, in particular as soil-release agents. Preferably, the compounds (a) are selected from the group comprising oligo- and polyamines, polyalkylene polyamines, polyamidoamines, polyamidoamines grafted with (poly)ethyleneimine and mixtures thereof.
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公开(公告)号:DE19624702A1
公开(公告)日:1998-01-02
申请号:DE19624702
申请日:1996-06-20
Applicant: BASF AG
Inventor: EHLE BEATE DR , POTTHOFF-KARL BIRGIT DR , KAHMEN MARTIN AUS DEM DR , KARL ULRICH DR , ZIMMERMANN NORBERT , WAGENMANN HENRIC DR
IPC: C09B67/46 , C09K23/00 , C09K23/28 , C11D3/33 , C11D3/42 , D06L3/12 , D06L4/614 , D06L4/671 , D06M13/342 , D06M13/35 , D06P1/16 , D06P1/22 , D06P1/642 , D06P1/647 , B01F17/28 , C09B67/02 , C14C3/08 , C14C3/28
Abstract: Hydroxyalkylaminocarboxylic acid derivatives of formula (I) R -CH(OH)-CH(R )-N(R )-Y-COOM (I) are used as dispersing agent in dyestuffs or in preparations containing UV absorbers or optical brighteners. In (I), R and R = H, aryl, alkyl or alkenyl and the alkyl or alkenyl groups may be substituted with 1,2 or 3 residues selected from aryloxy or alkoxycarbonyl and/or interrupted by 1, 2, 3,4 or 5 non-adjacent O atoms, or R and R together with the groups to which they are bound may form the residue of a mono- or polyunsaturated fatty acid which forms, by way of an ester bond, part of a triglyceride, this triglyceride, depending on the original number of double bonds in its fatty acid residue, having up to 9 groups of formula (I), R = H, alkyl, -CHR -CH(OH)-R (IIa) or -(CH2)n-COOM (IIb) (where n = a whole number 1-4, R and R = as for R and R , and the sum of the C atoms in R , R , R and R = at least 4), Y = alkylene which may be substituted by an OH group and/or a group of formula COOM), or R and Y may together complete a 5- or 6-membered, saturated or unsaturated heterocyclic ring and M = H, alkali(ne earth) metal, ammonium or substituted ammonium. Also claimed is use of (I) in dye baths for dyeing with dispersion dyes using the exhaustion process, in dye baths for dyeing with vat dyes and in textile treatment liquors containing UV absorbers or optical brighteners.
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公开(公告)号:DE19543162A1
公开(公告)日:1997-05-22
申请号:DE19543162
申请日:1995-11-18
Applicant: BASF AG
Inventor: POTTHOFF-KARL BIRGIT DR , EHLE BEATE DR , FUNHOFF ANGELIKA DR , KIESSLING DIETER DR , BAUR RICHARD DR , GREINDL THOMAS DR
IPC: C11D1/10 , C11D1/14 , C11D1/22 , C11D1/29 , C11D1/72 , C11D1/88 , C11D1/94 , C11D3/06 , C11D3/08 , C11D3/10 , C11D3/12 , C11D3/33 , C11D17/06
Abstract: Proposed is a solid washing-agent formulation for textiles, the formulation containing: (A) 1 to 60 % by wt. of inorganic builders made from crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates, (B) 0.1 to 25 % by wt. of one or more glycine-N,N-diacetic acid derivatives (I), in which R is an organic group and M is hydrogen or a cation, used as organic co-builders, (C) 1 to 40 % by wt. of anionic surfactants and (D) 0.5 to 30 % by wt. of non-ionic surfactants.
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