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    Binder formulations based on aqueous polymer dispersions
    21.
    发明专利
    Binder formulations based on aqueous polymer dispersions 未知

    公开(公告)号：AU777848B2

    公开(公告)日：2004-11-04

    申请号：AU5349200

    申请日：2000-08-18

    Applicant: BASF AG

    Inventor： BAUMSTARK ROLAND ,  KIRSCH STEFAN ,  DERSCH ROLF ,  DOBBELAAR JOHANNES ,  MELAN MICHAEL

    IPC: C08L33/06 ,  C08F2/24 ,  C08F212/02 ,  C08F212/04 ,  C08F220/12 ,  C08K5/00 ,  C08L25/00 ,  C09D5/02 ,  C09D125/02 ,  C09D133/06 ,  E04C2/04 ,  C09D133/08 ,  C08L25/14 ,  C08L33/08 ,  C08L33/10 ,  C09D125/14 ,  C09D133/10

    Abstract: Binder preparation with a minimum film-forming temperature below 10 degrees C, based on a dispersion containing anionic and non-ionic emulsifiers and a copolymer of 20-50 wt% vinyl-aromatic monomer, 45-70 wt% 1-18C alkyl acrylate or 5-18C alkyl methacrylate which forms a homopolymer with a Tg below 10 degrees C, 2-4 wt% methacrylic acid and optionally other comonomers. A binder preparation with a minimum film-forming temperature (MFT) below 10 degrees C, based on a binder polymer (P) in the form of an aqueous dispersion containing anionic emulsifier(s) and non-ionic emulsifier(s), in which (P) is a copolymer of (A1) 20-50 wt% vinyl-aromatic monomer(s), (A2) 0-15 wt% 1-4C alkyl (meth)acrylate(s), (A3) 0-30 wt% (meth)acrylonitrile, (B) 45-70 wt% monomer(s) which form a homopolymer with a glass transition point (Tg) below 10 degrees C, selected from 1-18C alkyl acrylates and 5-18C alkyl methacrylates, (C) 2-4 wt% methacrylic acid, (D) 0-3 wt% monomer(s) selected from amides, 1-4C hydroxyalkyl esters and 1-4C alkyl-polyalkyleneoxide-esters of 3-6C mono-unsaturated monocarboxylic acids and (E) 0-5 wt% other monomer(s), where the total amount of monomers (A1)-(A3) does not exceed 55 wt% of the total monomer content and the content of (A2) is at least 5 wt% if the content of (A3) is less than 0.5 wt%. An Independent claim is also included for emulsion paint containing binder preparation(s) as described.

    23.
    发明专利
    未知

    公开(公告)号：DE19939327A1

    公开(公告)日：2001-02-22

    申请号：DE19939327

    申请日：1999-08-19

    Applicant: BASF AG

    Inventor： BAUMSTARK ROLAND ,  KIRSCH STEFAN ,  DERSCH ROLF ,  DOBBELAAR JOHANNES ,  MELAN MICHAEL

    IPC: C08L33/06 ,  C08F2/24 ,  C08F212/02 ,  C08F212/04 ,  C08F220/12 ,  C08K5/00 ,  C08L25/00 ,  C09D5/02 ,  C09D125/02 ,  C09D133/06 ,  E04C2/04 ,  C08L33/04 ,  C08L25/08

    Abstract: Binder preparation with a minimum film-forming temperature below 10 degrees C, based on a dispersion containing anionic and non-ionic emulsifiers and a copolymer of 20-50 wt% vinyl-aromatic monomer, 45-70 wt% 1-18C alkyl acrylate or 5-18C alkyl methacrylate which forms a homopolymer with a Tg below 10 degrees C, 2-4 wt% methacrylic acid and optionally other comonomers. A binder preparation with a minimum film-forming temperature (MFT) below 10 degrees C, based on a binder polymer (P) in the form of an aqueous dispersion containing anionic emulsifier(s) and non-ionic emulsifier(s), in which (P) is a copolymer of (A1) 20-50 wt% vinyl-aromatic monomer(s), (A2) 0-15 wt% 1-4C alkyl (meth)acrylate(s), (A3) 0-30 wt% (meth)acrylonitrile, (B) 45-70 wt% monomer(s) which form a homopolymer with a glass transition point (Tg) below 10 degrees C, selected from 1-18C alkyl acrylates and 5-18C alkyl methacrylates, (C) 2-4 wt% methacrylic acid, (D) 0-3 wt% monomer(s) selected from amides, 1-4C hydroxyalkyl esters and 1-4C alkyl-polyalkyleneoxide-esters of 3-6C mono-unsaturated monocarboxylic acids and (E) 0-5 wt% other monomer(s), where the total amount of monomers (A1)-(A3) does not exceed 55 wt% of the total monomer content and the content of (A2) is at least 5 wt% if the content of (A3) is less than 0.5 wt%. An Independent claim is also included for emulsion paint containing binder preparation(s) as described.

    CARBOXYL-CONTAINING BUTADIENE-STYRENE COPOLYMERS
    25.
    发明专利
    CARBOXYL-CONTAINING BUTADIENE-STYRENE COPOLYMERS 未知

    公开(公告)号：AU544153B2

    公开(公告)日：1985-05-16

    申请号：AU7488181

    申请日：1981-09-02

    Applicant: BASF AG

    Inventor： DISTLER DIETER ,  MELAN MICHAEL

    IPC: C08L7/00 ,  C08F236/10 ,  C08K5/41 ,  C08K5/42 ,  C08L9/08 ,  C08L21/00 ,  C08L21/02 ,  C08L25/00 ,  C08L25/10 ,  C09D5/08 ,  C09D121/00 ,  C09D125/00 ,  C09D125/10 ,  C08F2/26 ,  C08F212/08 ,  C09D3/76 ,  C09D5/02

    Abstract: Aqueous low-emulsifier dispersions of emulsion copolymers which contain, as copolymerized units, (a) from 35 to 55% by weight of butadiene, (b) from 35 to 60% by weight of styrene, (c) from 1 to 3% by weight of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 6 carbon atoms, (d) from 1 to 3% by weight of amides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, (e) from 1 to 4% by weight of N-methylolamides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, or their alkyl ethers, and (f) from 1 to 3% by weight of acrylic acid and/or methacrylic acid monoesters of alkanediols of 2 to 6 carbon atoms, the emulsion containing, as emulsifier, from 0.1 to 0.8% by weight, based on emulsion copolymers, of fatty alcohol-sulfonates and/or alkylbenzenesulfonates, where alkyl is of 12 to 16 carbon atoms, are of particular value as binders for aqueous anti-corrosion paints.

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