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公开(公告)号:DE10025782A1
公开(公告)日:2001-12-06
申请号:DE10025782
申请日:2000-05-26
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , PARKER ROBERT , KUERSCHNER KATHRIN , SCHUHMACHER PETER , SCHMIDT HANS-WERNER , SCHMITT GEROLD , GIESA REINER
IPC: B32B7/02 , C09B67/00 , C09B67/20 , C09B69/10 , C09D5/00 , C09K19/00 , C09K19/20 , C09K19/34 , C09K19/36 , C09K19/38 , C09K19/54 , C09K19/04 , G02F1/13 , C09D11/02
Abstract: New liquid crystalline mixtures comprise: (a) difunctional mesogenic compound(s) (I); (b) reactive compound(s);and (c) optionally additives. New liquid crystalline mixtures comprise: (a) at least one difunctional mesogenic compound of formula Z1-Y1-A1-Y3-M-Y4-A2-Y2-Z2 (I); (b) at least one reactive compound selected from (i) vinyl or allyl ethers, (ii) vinyl or allyl esters of (un)saturated carboxylic acids, (iii) (meth)acrylate esters of mono- or polyfunctional alcohols, (iv) polyester (meth)acrylates, (v) vinyl (hetero)aromatic compounds, and (vi) N-vinyl amide or amine compounds of formula CH2=CH-NR1R2 (II); and (c) optionally further additives. Z1, Z2 = reactive groups (preferably photopolymerizable groups); Y1 - Y4 = direct bond, O, S, OC(O), OC(O)O, C(O)NR, NRC(O), OC(O)NR, NRC(O)O or NRC(O)NR; R = H or 1-4C alkyl; A1, A2 = 1-30C spacers, in which the carbon chains are optionally substituted by one or more Me, F, Cl or Br and interrupted by one or more O, S or non-adjacent NH or N(1-4C alkyl); M = mesogenic group; R1, R2 = -C(O)R3 or R3; R2, R3 = H or 1-4C alkyl; R2 + R3 = optionally unsaturated 3-5C alkylene (in which 1 or 2 CH2 groups are optionally replaced by NH, N(1-4C alkyl), N(6-10C aryl) or O and 1 or 2 CH group are optionally replaced by N).
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22.
公开(公告)号:CZ20003909A3
公开(公告)日:2001-10-17
申请号:CZ20003909
申请日:1999-04-12
Applicant: BASF AG
Inventor: MEYER FRANK , WAGENBLAST GERHARD , BECK KARIN HEIDRUN , VAMVAKARIS CHRISTOS
Abstract: The present invention relates to a method of marking liquids using at least two markers, wherein said markers absorb in the 600-1200 nm region of the spectrum and reemit fluorescent light and the absorption range of at least one marker overlaps with the absorption range of at least one other marker.The present invention further relates to a method for detecting markers in liquids marked by the method of the invention, which comprises using light sources which emit radiation in the absorption ranges of said markers and detecting the fluorescent light reemitted by said markers, at least one of said light sources emitting radiation in the overlapping absorption range of at least one marker with that of at least one other marker and the number of light sources being less than or equal to the number of markers.The present invention further relates to liquids marked by the method of the invention.
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公开(公告)号:DE10013507A1
公开(公告)日:2001-09-27
申请号:DE10013507
申请日:2000-03-20
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , PARKER ROBERT , KUERSCHNER KATHRIN , VILL VOLKMAR , PAUL MATTHIAS
IPC: G02F1/13 , C07D319/06 , C08F20/30 , C08J5/18 , C09K19/34 , C09K19/38 , C09K19/58 , C07D405/02 , C07D413/02 , C07D417/02 , C07H9/04 , C09D7/02
Abstract: Chiral 2,4,5-tri-substituted 1,3-dioxane compounds (I), with different substituents containing a mesogenic group, and their diastereomers are new. Chiral 2,4,5-tri-substituted 1,3-dioxane compounds of formula (I), with different substituents containing a mesogenic group, and their diastereomers are new: [Image] R1>[P-Y1>-(A1>)m-Y2>-]qM-Y3>-(A2>)n-Y4>- group; R2>, R3>[P-Y1>-(A1>)m-Y2>-]qM-Y3>-(A2>)n-Y4>'-; A1>, A2>spacers with 1-30 carbon atoms; M : a mesogenic group; Y1>, Y2>, Y3>, Y4>a single bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -CO-N(R)-, -(R)N-CO-, -O-CO-O-, -O-CO-N(R)-, -(R)N-CO-O- or -(R)N-CO-N(R)-; Y4>' : -O-, -O-CO-, -O-CO-O- or -O-CO-N(R)-, with the O atom attaching R2>, R3> to the 1,3-dioxane ring; R : hydrogen or 1-4C alkyl; P : H, 1-12C alkyl, a polymerizable group or a group containing a polymerizable group; m, n : 0 or 1; q : 1, 2 or 3. Independent claims are also included for: (a) liquid crystal (LC) compositions containing chiral compound(s) (I); (b) polymerizable LC compositions containing chiral compound(s) (I); (c) optical devices produced using these compositions; (d) printed or coated substrates, dispersions and emulsions, films or pigments prepared using the polymerizable LC compositions.
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24.
公开(公告)号:CA2316623A1
公开(公告)日:2001-02-27
申请号:CA2316623
申请日:2000-08-24
Applicant: BASF AG
Inventor: HEILMANN PETER , PRECHTL FRANK , SCHNEIDER NORBERT , PARKER ROBERT , SCHUHMACHER PETER , RICHTER VOLKER , MEYER FRANK , KOCH VOLKER
IPC: G02B5/30 , C08F2/46 , C08F20/26 , C09B67/00 , C09B67/02 , C09B67/08 , C09B67/20 , C09D5/29 , C09D5/36 , C09D201/00 , C09K19/00 , G02F1/1335 , C09K19/38 , B05D5/06
Abstract: The invention relates to cholesteric layered material having an improved color impression, to pigments prepared therefrom, and to a process for the production and use thereof.
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公开(公告)号:TR200003066T2
公开(公告)日:2001-01-22
申请号:TR200003066
申请日:1999-04-12
Applicant: BASF AG
Inventor: MEYER FRANK , WAGENBLAST GERHARD , BECK KARIN HEIDRUN , VAMVAKARIS CHRISTOS
Abstract: The present invention relates to a method of marking liquids using at least two markers, wherein said markers absorb in the 600-1200 nm region of the spectrum and reemit fluorescent light and the absorption range of at least one marker overlaps with the absorption range of at least one other marker.The present invention further relates to a method for detecting markers in liquids marked by the method of the invention, which comprises using light sources which emit radiation in the absorption ranges of said markers and detecting the fluorescent light reemitted by said markers, at least one of said light sources emitting radiation in the overlapping absorption range of at least one marker with that of at least one other marker and the number of light sources being less than or equal to the number of markers.The present invention further relates to liquids marked by the method of the invention.
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公开(公告)号:BR9907308A
公开(公告)日:2000-12-19
申请号:BR9907308
申请日:1999-06-04
Applicant: BASF AG
Inventor: SCHUHMACHER PETER , SCHNEIDER NORBERT , WESTENFELDER HORTS , HAREMZA SYLKE , HABECK THORSTEN , MEYER FRANK
IPC: A61K8/00 , A61K8/02 , A61K8/23 , A61K8/25 , A61K8/29 , A61K8/31 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/37 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/73 , A61K8/86 , A61K8/89 , A61K8/97 , A61K8/98 , A61K31/255 , A61K31/34 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q1/10 , A61Q5/00 , A61Q17/04 , A61Q19/00 , C09B67/20 , C09C3/08 , C09K3/00 , A61K7/40
Abstract: Liquid crystal compositions forming a cholesteric phase with a pitch of less than 450 nm, comprising either at least one polymerizable chiral liquid crystal monomer or a mixture of at least one polymerizable achiral liquid crystal monomer and at least one chiral additive, are used as ultraviolet filters for protecting skin or hair against solar radiation. Liquid crystal compositions forming a cholesteric phase with a pitch of less than 450 nm, comprising either: (a) at least one polymerizable chiral liquid crystal monomer of formula (I); or (b) a mixture of at least one polymerizable achiral liquid crystal monomer of formula (II) and at least one chiral additive, are used as ultraviolet (UV) filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation: A -A = spacers with a chain length of 1-30C; Y -Y = bonds, O, S, C(O)O, OC(O), CH=CHC(O)O, OC(O)O, C(O)N(R), N(R)C(O), CH2O, OCH2, CH=N, N=CH or N=N; M , M = mesogenic groups; R = H or 1-4C alkyl; Z = H, 1-4C alkyl or a polymerizable group, at least one being a polymerizable group; Z , Z = H, 1-4C alkyl or polymerizable groups, at least one being a polymerizable group; X = an n-valent chiral group; m, o, p = 0 or 1; n = 1-6. Independent claims are also included: (1) use of the liquid crystal compositions as photostable UV reflectors; (2) use of the liquid crystal compositions as UV stabilizers in cosmetic and pharmaceutical formulations; (3) pigments containing the polymerized liquid crystal compositions.
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27.
公开(公告)号:AU2250300A
公开(公告)日:2000-09-28
申请号:AU2250300
申请日:2000-03-23
Applicant: BASF AG
Inventor: MEYER FRANK , SCHUHMACHER PETER , PRECHTL FRANK
IPC: C07D493/04 , A61K8/00 , A61K8/02 , A61K8/37 , A61K8/49 , A61Q5/00 , A61Q17/04 , C09K3/00 , C09K19/00 , C09K19/04 , C09K19/20 , C09K19/58 , C09B69/10 , C09K19/36 , C08F220/26 , A61K7/48 , A61K7/42 , A61K7/06
Abstract: New chiral doping agents (I) comprise dianhydrohexitol derivatives containing at least one polymerizable group. Chiral doping agents of formula (I) are new. Z1-Y1-(A1)m-Y2-M-Y3-X-Y4-(A2)n-Y5-Z 2 (I) A1, A2 = spacers having a chain length of 1-30C; Y1-Y5 = direct bond, O, S, C(O), C(O)O, OC(O), CH=CHC(O)O, OC(O)O, C(O)N(R), N(R)C(O), CH2O, CH=N, N=CH or N=N; M = mesogenic group; R = H or 1-4C alkyl; Z1, Z2 = H, 1-4C alkyl, polymerizable group (PG) or residue carrying a PG, provided that at least one is a PG or residue carrying a PG; X = dianhydrosorbitol, dianhydromannitol or dianhydroiditol residue; m, n = 0 or 1. An Independent claim is included for cholesteric liquid crystal compositions (A) (which preferably reflect left-circular polarized light in the UV region), comprising at least one chiral liquid crystalline monomer (I) which provides a cholesteric liquid crystalline phase having a pitch of less than 450 nm, optionally mixed with at least one achiral liquid crystalline monomer of formula (II). Z1-Y1-(A1)m-Y2-M-Y4-(A2)n-Y5-Z2 (II)
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公开(公告)号:CA2359729A1
公开(公告)日:2000-08-17
申请号:CA2359729
申请日:2000-02-05
Applicant: BASF AG
Inventor: SCHUHMACHER PETER , MEYER FRANK , NEUMANN HORST , ISHIDA HIROKI
IPC: G02F1/13 , B41M5/52 , B41M7/00 , C09D4/00 , C09D5/36 , C09D11/50 , C09K19/00 , C09K19/20 , C09K19/38 , C09K19/54
Abstract: The invention relates to liquid crystalline substance mixtures which contain at least one compound selected from the group consisting of the compounds of the formula (Ia): Z1-Y1-A1-Y3-M1-Y4-A2-Y2-Z2 and of the formula (Ib): Z3-Y5- A3- Y7-M2-P, wherein the variable P means hydrogen, C1-C15-alkyl or a -Y8-A4-Y6- Z4 group, Z1 to Z4 polymerisable groups, Y1 to Y8 linking groups, A1 to A4 spac er and M1 and M2 mesogenic groups. Said liquid crystalline mixtures of substanc es optionally contain further additives selected from photoinitiators, reactive diluents and diluents, auxiliaries, colourants and stabilisors. The inventio n also relates to the use of such liquid crystalline mixtures of substances as printing ink, for printing or coating substrates, in electrooptic components , for forgery-proof marking of objects and for producing films or coatings.
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公开(公告)号:CZ416399A3
公开(公告)日:2000-05-17
申请号:CZ416399
申请日:1998-05-13
Applicant: BASF AG
Inventor: MEYER FRANK , VAMVAKARIS CHRISTOS , BECK KARIN HEIDRUN , WAGENBLAST GERHARD , ALBERT BERNHARD
IPC: C07D487/22 , C07D209/00 , C07D259/00 , C07D487/00 , C07D491/107 , C07D519/00 , C09B47/04 , C09B47/067 , C09B47/22 , C09B47/30 , C09K11/06 , C10L1/00 , C10L1/22 , C10L1/232 , C10L1/28 , C10L1/30 , C10M101/02 , C10M133/44 , C10N30/20
Abstract: Phthalocyanines of the formulawhereMe is twice hydrogen, twice lithium, magnesium, zinc, copper, nickel, VO, TiO, AlCl, AlOH, AlOCOCH3, AlOCOCF3, SiCl2 or Si(OH)2,at least four of the radicals R1 to R16 are each independently of the others a five- or six-membered saturated nitrogen-containing heterocyclic radical which is bonded to the phthalocyanine structure via a ring nitrogen atom and which can additionally contain further hetero atoms, andany remaining radicals R1 to R16 are each hydrogen, halogen, hydroxysulfonyl or C1-C4-dialkylsulfamoyl,subject to the proviso that tetrakispiperidinylphthalocyanine shall be excluded,and heterocyclyl-substituted phthalocyanines are useful for marking liquids, in particular mineral oils.
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公开(公告)号:NO20001845A
公开(公告)日:2000-04-10
申请号:NO20001845
申请日:2000-04-10
Applicant: BASF AG
Inventor: SIEMENSMEYER KARL , SCHUHMACHER PETER , MEYER FRANK , SCHNEIDER NORBERT , ISHIDA HIROKI
CPC classification number: G02B5/282 , C03C17/32 , G02B5/3016 , Y10T428/10 , Y10T428/1005
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