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公开(公告)号:DE4110457A1
公开(公告)日:1992-10-01
申请号:DE4110457
申请日:1991-03-30
Applicant: BASF AG
Inventor: MROSS WOLF DIETER DR , DOCKNER TONI DR , WOLFF DIETRICH DR , FASTRE GUSTAAF DIPL ING , FISCHER KARL DR
IPC: B01J27/10 , B01J27/122 , B01J27/132 , B01J27/138 , C07B61/00 , C07C209/36 , C07C211/44
Abstract: Aromatic amines are prepared by catalytic hydrogenation of nitroaromatics on hydrogenation catalysts at 160 to 450 DEG C and pressures of 1 to 50 bar, the hydrogenation catalyst containing 0.02 to 1% by weight of halogen and/or the reaction mixture containing 0.1 to 50 ppm of a halogen-containing organic compound, relative to the nitroaromatics employed.
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公开(公告)号:DE3905578A1
公开(公告)日:1990-08-30
申请号:DE3905578
申请日:1989-02-23
Applicant: BASF AG
Inventor: HERZOG KLAUS DR , BOEHNING KARL-HEINZ DR , AICHINGER HEINRICH DR , PLUECKHAN JUERGEN DR , MROSS WOLF DIETER DR , SCHWARZMANN MATTHIAS DR
IPC: B01J23/66 , B01J35/10 , B01J37/02 , C07D301/10
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公开(公告)号:DE3923026A1
公开(公告)日:1990-01-18
申请号:DE3923026
申请日:1989-07-13
Applicant: BASF AG
Inventor: BUECHELE WOLFGANG DR , AMBACH EBERHARD DR , HOELDERICH WOLFGANG DR , MROSS WOLF DIETER DR , BIFFAR WERNER DR
IPC: B01J23/86 , B01J23/88 , B01J23/887 , B01J23/888 , C07C5/333
Abstract: Catalyst, in particular for the dehydrogenation of hydrocarbons to give olefinically unsaturated hydrocarbons, which essentially comprises in the sintered, ready-to-use state a) 60 to 95% by weight of at least one iron compound, calculated as Fe2O3; b) 1 to 25% by weight of at least one potassium compound, calculated as K2O; c) 0.1 to 5% by weight of at least one compound of chromium or of aluminium, calculated as Cr2O3 or Al2O3; d) 0.1 to 5% by weight of at least one compound of molybdenum or tungsten, calculated as MoO3 or WO3; e) 0.1 to 2.5% by weight of a vanadium compound, calculated as V2O5; f) 0.1 to 5% by weight of a lithium compound, calculated as Li2O; and conventional contaminants and production-related residues, as is obtained when a mixture of either Fe2O3 or FeOOH or a mixture of Fe2O3 and FeOOH and the subsidiary constituents in the form of their compounds is moulded, dried if appropriate at below 160@C and calcined at 200 to 1000@C, the atomic ratio of vanadium to molybdenum or tungsten being 1 to 2.5 and when Fe2O3 is used as starting material in production, the content of vanadium being selected in such a way that in the finished catalyst it is 0.5 to 2% by weight, when FeOOH is used as starting material it is 0.5 to 2.5% by weight and when a mixture of Fe2O3 and FeOOH is used it is no more than 1.5% by weight, in such a manner that when ... Original abstract incomplete.
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公开(公告)号:DE3819437A1
公开(公告)日:1989-12-14
申请号:DE3819437
申请日:1988-06-08
Applicant: BASF AG
Inventor: AMBACH EBERHARD DR , SPRAGUE MICHAEL JOLYON DR , STEIGLEITER WERNER , MROSS WOLF DIETER DR , GRUENDLER KARL-HEINZ DR , IRGANG MATTHIAS DR
Abstract: The application relates to the preparation of a sulphur-free iron-oxide- and chromium-oxide-containing high temperature conversion catalyst, an iron oxide being used which is prepared from iron carbonyl and which has a mean grain size below 10 mu m and a specific surface area of more than 10 m /g. The chromium oxide component is applied to the iron oxide by precipitation. The chromium component used is CrO3 and is precipitated as insoluble chromium(III) compounds by reducing agents.
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公开(公告)号:DE3661008D1
公开(公告)日:1988-12-01
申请号:DE3661008
申请日:1986-04-11
Applicant: BASF AG
Abstract: Alkylbenzenes are prepared by converting an alkyl-, alkylidene- or alkenylcyclohexene or an alkyl- or alkenylcyclohexadiene in the presence of an acidic zeolite catalyst of the pentasil type, in the gas phase or liquid phase.
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公开(公告)号:AT38166T
公开(公告)日:1988-11-15
申请号:AT86110546
申请日:1986-07-30
Applicant: BASF AG
Inventor: BOEHNING KARL-HEINZ DR , MROSS WOLF DIETER DR , SCHWARZMANN MATTHIAS DR , BECKER HANS-JUERGEN DR , PLUECKHAN JUERGEN DR , RENNER KLAUS-CHRISTIAN DR
IPC: B01J23/66 , B01J35/10 , C07D301/10
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公开(公告)号:DE3465463D1
公开(公告)日:1987-09-24
申请号:DE3465463
申请日:1984-06-25
Applicant: BASF AG
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公开(公告)号:DE3607449A1
公开(公告)日:1987-09-10
申请号:DE3607449
申请日:1986-03-07
Applicant: BASF AG
Inventor: EICHHORN HANS-DIETER DR , MROSS WOLF DIETER DR , SCHACHNER HELMUT DR , SCHWARZMANN MATTHIAS DR
IPC: B01J27/122 , B01J35/02 , C07B61/00 , C07C17/00 , C07C17/156 , C07C19/045 , C07C67/00 , B01J21/04
Abstract: A molded supported catalyst which contains from 2 to 13% by weight of copper ions in the form of copper(II) chloride and/or copper oxychloride and from 0.2 to 3% by weight of alkali metal ion on a columnar carrier and has a diameter of from 4 to 7 mm and a height which is from 0.35 to 0.75 times the diameter is particularly suitable for preparing 1,2-dichloroethane by oxychlorination of ethylene.
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公开(公告)号:DE3522473A1
公开(公告)日:1987-01-02
申请号:DE3522473
申请日:1985-06-22
Applicant: BASF AG
Inventor: EICHHORN HANS-DIETER DR , MROSS WOLF DIETER DR , SCHACHNER HELMUT DR , SCHWARZMANN MATTHIAS DR , CORDEMANS LUC DR
IPC: B01J27/122 , C07B61/00 , C07C17/00 , C07C17/156 , C07C19/045 , C07C67/00 , B01J23/72 , B01J23/78
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公开(公告)号:DE3521766A1
公开(公告)日:1987-01-02
申请号:DE3521766
申请日:1985-06-19
Applicant: BASF AG
Inventor: HOELDERICH WOLFGANG DR , BIFFAR WERNER DR , IRGANG MATTHIAS DR , MROSS WOLF DIETER DR , KROENER MICHAEL DR , AMBACH EBERHARD DR
IPC: B01J23/06 , B01J23/84 , B01J23/85 , B01J23/88 , B01J27/18 , B01J27/188 , B01J27/198 , B01J27/199 , B01J35/04 , C01B3/16 , C07B61/00 , C07C1/00 , C07C5/333 , C07C15/46 , C07C67/00 , C07C231/00 , C07C231/12 , C07C233/03 , B01J23/74 , B01J23/76 , B01J27/185
Abstract: A honeycomb catalyst consisting of from 30 to 95% by weight, calculated as Fe2O3, of an iron compound and from 0.1 to 60% by weight, calculated as Al2O3, CeO2 or Cr2O3, of an aluminum, cerium and/or chromium compound and/or from 1 to 50% by weight of an alkali metal compound, in particular potassium, calculated as K2O, and/or from 0.2 to 20% by weight, calculated as MeO3, of an element of sub-group 6, preferably MoO3 and WO3, and/or from 0.1 to 20% by weight, calculated as V2O5, of a compound of vanadium and/or from 0.1 to 20% by weight, calculated as P2O5, of a compound of phosphorus, a process for the preparation of the honeycomb catalyst, and the use of the catalyst for organic reactions.
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