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公开(公告)号：DE19846549A1
公开(公告)日：2000-04-13
申请号：DE19846549
申请日：1998-10-09
Applicant: BASF AG
Inventor： STEINBRENNER ULRICH , NARBESHUBER THOMAS
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公开(公告)号：DE19834593A1
公开(公告)日：2000-02-03
申请号：DE19834593
申请日：1998-07-31
Applicant: BASF AG
Inventor： SIGWART CHRISTOPH , NARBESHUBER THOMAS , GEHRER EUGEN , FISCHER ROLF , STEINBRENNER ULRICH , LIANG SHELUE
Abstract: The invention relates to a method for producing reactive halogen-free polyisobutene containing more than 60 mole % terminal double bonds and having a mean molecular weight Mn of between 800 and 3,000 dalton, by cationic polymerization of isobutene in the liquid phase on an acid, substantially halogen-free heterogeneous catalyst. According to said method a) an isobutene-containing hydrocarbon mixture which consists essentially of C4 hydrocarbons and contains between 10 and 80 % by weight isobutene is used as educt; and b) continuous polymerization is carried out at between -30 and 0 DEG C and mean dwell times of the educt of no more than one hour, the temperature and dwell time being chosen such that isobutene conversion is less than 60 %. After separation of the resulting polyisobutene present in the fully reacted hydrocarbon mixture the isobutene is either enriched and returned to the polymerization stage or fed to another isobutene conversion stage which is coupled to the polymerization stage.
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23.发明专利
公开(公告)号：BRPI0415901B1
公开(公告)日：2016-01-26
申请号：BRPI0415901
申请日：2004-10-29
Applicant: BASF AG
Inventor： STEPHAN JÜRGEN , BOSCH MARCO , BOTTKE NILS , BENFER REGINA , NARBESHUBER THOMAS , STEINBRENNER ULRICH
Abstract: "processo para preparar compostos, composto, uso do mesmo, e, agente de lavagem ou de limpeza". em um processo para preparar compostos de alquilarila mediante a reação de uma mistura de monoolefina c~ 10-14~ com um hidrocarboneto aromático, na presença de um catalisador de alquilação, para formar compostos aromáticos de alquila e, se apropriado, subseqüentemente sulfonando-se e neutralizando-se os compostos de alquilarila resultantes, nas monoolefinas c~ 10-14~, em média, mais do que 0% e até 100% de ramificações metila se acham presentes na cadeia de carbono mais longa, e menos do que 50% das ramificações metila se acham nas posições 2, 3 e 4, calculado partindo-se das extremidades de cadeia da cadeia de carbono mais longa.
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公开(公告)号：ZA200604943B
公开(公告)日：2007-12-27
申请号：ZA200604943
申请日：2006-06-15
Applicant: BASF AG
Inventor： BOTTKE NILS , TROPSCH JURGEN , NARBESHUBER THOMAS , STEPHAN JURGEN , ROPER MICHAEL , STEINBRENNER ULRICH , BENFER REGINA , HEIDEMANN THOMAS
IPC: C07C20090101 , C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
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公开(公告)号：BRPI0417365A
公开(公告)日：2007-04-10
申请号：BRPI0417365
申请日：2004-12-17
Applicant: BASF AG
Inventor： STEINBRENNER ULRICH , HEIDEMANN THOMAS , ROEPER MICHAEL , STEPHAN JUERGEN , NARBESHUBER THOMAS , TROPSCH JUERGEN , BOTTKE NILS , BENFER REGINA
IPC: C07C303/00 , C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
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Patent Agency Ranking
公开(公告)号：BR0317634A
公开(公告)日：2005-11-29
申请号：BR0317634
申请日：2003-12-22
Applicant: BASF AG
Inventor： NARBESHUBER THOMAS , STEINBRENNER ULRICH , WIEBELHAUS DAG , BOTTKE NILS
IPC: C11D1/22 , C11D11/04 , C07C303/06
Abstract: The invention relates to processes for the preparation of alkylarylsulfonates
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公开(公告)号：MY120371A
公开(公告)日：2005-10-31
申请号：MYPI9903275
申请日：1999-07-30
Applicant: BASF AG
Inventor： SIGWART CHRISTOPH , NARBESHUBER THOMAS , GEHRER EUGEN , FISCHER ROLF , STEINBRENNER ULRICH , LIANG SHELUE
Abstract: A PROCESS FOR PREPARING HALOGEN-FREE, REACTIVE POLYISOBUTENE HAVING A TERMINAL DOUBLE BOND CONTENT OF MORE THAN 60 MOL% AND AN AVERAGE MOLECULAR WEIGHT MN OF 800-3000 DALTON BY CATIONIC POLYMERIZATION IN THE LIQUID PHASE OF ISOBUTENE OVER AN ACIDIC, ESSENTIALLY HALOGEN-FREE HETEROGENEOUS CATALYST, WHERE A) A HYDROCARBON MIXTURE OF ESSENTIALLY C4-HYDROCARBONS COMPRISING ISOBUTENE IN AN AMOUNT OF FROM 10 TO 80% BY WEIGHT IS USED AS THE STARTING MATERIAL AND B) POLYMERIZATION IS CARRIED OUT CONTINUOUSLY AT FROM -30 TO 0°C WITH AVERAGE STARTING MATERIAL RESIDENCE TIMES OF ONE HOUR OR LESS, WHERE THE TEMPERATURE AND THE RESIDENCE TIME ARE SELECTED SUCH THAT THE ISOBUTENE CONVERSION IS LESS THAN 60% AND, AFTER SEPARATION FROM THE RESULTING POLYISOBUTENE, THE ISOBUTENE IS EITHER ENRICHED IN THE PARTIALLY CONVERTED HYDROCARBON MIXTURE AND RETURNED TO THE POLYMERIZATION OR PASSED TO ANOTHER ISOBUTENE REACTION COUPLED WITH THE POLYMERIZATION.
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公开(公告)号：MY120061A
公开(公告)日：2005-08-30
申请号：MYPI9805372
申请日：1998-11-27
Applicant: BASF AG
Inventor： EIERMANN MATTHIAS , NARBESHUBER THOMAS
IPC: C07D201/08 , B01J23/00 , B01J27/18 , B01J27/187
Abstract: THE INVENTION RELATES TO A PROCESS FOR PREPARING LACTAMS BY CYCLIZING HYDROLYSIS OF AMINO NITRILES WITH WATER IN THE GAS PHASE ON CATALYST WHICH COMPRISE OXIDES OR MIXED OXIDES OF THE METALS OF GROUPS 3, 4, 5, 13 AND/OR 14 OF THE PERIODIC TABLE, WHERE APPROPRIATE IN ADDITION A METAL OXIDE OF GROUPS 6, 7, 8, 9 AND/OR 10 AND FURTHER COMPRISE A PHOSPHATE, CARBONATE, SILICATE, ARSENITE, ARSENATE, ANTIMONITE, ANTIMONATE AND/OR NITRATE OF SAID METALS AND/OR, IF METAL OXIDES OF GROUPS 6, 7, 8, 9 OR 10 ARE PRESENT, A SULFATE OF THE ABOVEMENTIONED METALS.
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公开(公告)号：DE10360026A1
公开(公告)日：2005-07-21
申请号：DE10360026
申请日：2003-12-19
Applicant: BASF AG
Inventor： STEINBRENNER ULRICH , HEIDEMANN THOMAS , ROEPER MICHAEL , STEPHAN JUERGEN , NARBESHUBER THOMAS , TROPSCH JUERGEN , BOTTKE NILS , BENFER REGINA
IPC: C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04 , C07B45/04
Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
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公开(公告)号：AU2004230225A1
公开(公告)日：2004-10-28
申请号：AU2004230225
申请日：2004-04-14
Applicant: BASF AG
Inventor： ZEHNER PETER , STEINBRENNER ULRICH , BENFER REGINA , UNGER JORG , ZIMDAHL SOEREN , NARBESHUBER THOMAS
IPC: C07C2/66 , C07C15/107 , C07C303/06 , C07C303/08 , C07C309/31 , C07C2/70
Abstract: Production of alkylaromatic compounds (I), by reacting 3-30C olefins (II) (or alcohols forming (II) under the reaction conditions) with aromatic hydrocarbons (III) in presence of an alkylation catalyst (IV), is carried out in a cascade of at least two reactors each containing (IV), where at least 80 % of (III) is supplied to the first reactor of the cascade and at least 40 % of (II) is supplied after the first reactor. An independent claim is included for the preparation of alkylarylsulfonates (A), by: (1) converting a 4C olefin mixture over a metathesis catalyst to give an olefin mixture containing 2-pentene and/or 2-hexene; (2) catalytically dimerizing the 2-pentene and/or 2-hexene (optionally after isolation) to give a mixture containing 10-12C olefins, optionally separating the 10-12C olefins and separating 5-30 wt. % (based on the 10-12C olefins) of low-boiling components of the 10-12C olefins; (3) reacting the obtained 10-12C olefin mixture with (III) in presence of (IV) to give alkylaromatic compounds (I'), optionally with addition of 0-60 wt. % (based on the 10-12C olefin mixture) of linear olefins before the reaction; (4) sulfonating (I') and neutralizing to give (A), optionally with addition of 0-60 wt. % (based on (I')) of linear alkylbenzenes (provided that no mixing has been carried out in the previous step); and (5) optionally mixing the obtained (A) with optionally with addition of 0-60 wt. % (based on (A)) of linear aralkylsulfonates (provided that no mixing has been carried out either of the previous two steps); The novel feature being that the reaction in the alkylation stage (3) is carried out as for the present procedure for preparing (I).
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