公开(公告)号：DE102004044402A1

公开(公告)日：2006-03-30

申请号：DE102004044402

申请日：2004-09-14

Applicant: BASF AG

Inventor： BECKER HEIKE ,  NIED STEPHAN

IPC: C11D3/37

Abstract: Rinse agent formulations for machine dishwashing, comprising as components: a) 1% to 20% by weight of copolymers of a1) 20% to 80% by weight of at least one monomer from the group consisting of monoethylenically unsaturated C 3 -C 10 monocarboxylic or dicarboxylic acids or their anhydrides, a2) 10% to 80% by weight of at least one monomer of the general formula (I) in which R 1 , R 2 and R 3 independently of one another are H, CH 3 or C 2 H 5 , R 4 is a linear, branched or cyclic radical having 1 to 6 carbon atoms or an aromatic radical having 6 to 12 carbon atoms, and a3) 0% to 80% by weight of at least one further monomer, selected from the group consisting of olefins having 10 or more carbon atoms or mixtures thereof and reactive polyisobutenes having on average 12 to 100 carbon atoms, b) 1% to 30% by weight of low-foaming nonionic surfactants, c) 0% to 50% by weight of nonaqueous solvents, d) 0% to 15% by weight of solubilizers, e) 0% to 15% by weight of acidifiers, f) 0% to 10% by weight of one or more further additives such as anionic, cationic, zwitterionic and amphoteric surfactants, dyes, fragrances and corrosion inhibitors; g) water to 100% by weight.

公开(公告)号：BR0311490A

公开(公告)日：2005-03-15

申请号：BR0311490

申请日：2003-06-04

Applicant: BASF AG

Inventor： BAUM PIA ,  MICHL KATHRIN ,  WEINGART FRANZ ,  NIED STEPHAN ,  BRODT GREGOR

IPC: C08F290/06 ,  C11D3/37

Abstract: The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its a water soluble (50-93), (b) methacrylic acid and/or one of its a water soluble salts (5-30), and (c) at least one nonionic monomer (2-20), statistically or block polymerized as washing and cleaning material additives is new. The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its water soluble salts (50-93); (b) methacrylic acid and/or one of its a water soluble salts (5-30); and (c) at least one nonionic monomer (2-20) of formula (I). R1 = H or Me, R2 = chemical bond or optionally branched 1-6C alkylene, R3 = optionally branched 2-4C alkylene, R4 = optionally branched 1-6C alkyl, n = 3-50, statistically or block polymerized as washing and cleaning material additives. An Independent claim is also included for a washing and cleaning material containing the copolymer as a coating inhibiting additive.

公开(公告)号：DE10225594A1

公开(公告)日：2003-12-18

申请号：DE10225594

申请日：2002-06-07

Applicant: BASF AG

Inventor： BAUM PIA ,  MICHL KATHRIN ,  WEINGART FRANZ ,  NIED STEPHAN ,  BRODT GREGOR

IPC: C08F290/06 ,  C11D3/37

Abstract: The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its a water soluble (50-93), (b) methacrylic acid and/or one of its a water soluble salts (5-30), and (c) at least one nonionic monomer (2-20), statistically or block polymerized as washing and cleaning material additives is new. The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its water soluble salts (50-93); (b) methacrylic acid and/or one of its a water soluble salts (5-30); and (c) at least one nonionic monomer (2-20) of formula (I). R1 = H or Me, R2 = chemical bond or optionally branched 1-6C alkylene, R3 = optionally branched 2-4C alkylene, R4 = optionally branched 1-6C alkyl, n = 3-50, statistically or block polymerized as washing and cleaning material additives. An Independent claim is also included for a washing and cleaning material containing the copolymer as a coating inhibiting additive.

公开(公告)号：CA2436359A1

公开(公告)日：2002-08-22

申请号：CA2436359

申请日：2002-01-30

Applicant: BASF AG ,  RECKITT BENCKISER NV

Inventor： WIEDEMANN RALF ,  NIED STEPHAN ,  KISTENMACHER AXEL ,  GUZMANN MARCUS

IPC: C11D7/22 ,  C11D3/37 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54 ,  C11D11/00 ,  C11D17/06

Abstract: The invention relates to cleaner formulations and to the use of said cleaner formulations for preventing plastic articles from discoloring when cleaned i n a dishwasher. The cleaner formulations comprise the following components: a) copolymers containing a1) 10 to 60 % by weight of at least one monomer component (A) from the group of the monoethylenically unsaturated C3-C10 mon o- or dicarboxylic acids or the anhydrides thereof; a2) 40 to 90 % by weight of at least one monomer component (B) of the general formula (I), wherein R1, R 2 and R3 independently represent H, CH3, C2H5, C3H7, COOH or OH, Y represents - C(=O)-, -C(=O)-O-, -O-, -O-C(=O)-, -O-C(=O)-O- or -C(=O)-NH-, n equals 0 or 1, R4 is a linear or branched, cyclic or acyclic aliphatic group with 7 to 100 carbon atoms; and a3) 0 to 30 % by weight of at least one further monomer component (C) that can be copolymerized with the monomer components (A) and (B) and that is selected from the group consisting of C1-C6 (meth)acrylic esters, C1-C6 vinylethers, C2-C8 olefins, styrenes, acrylnitriles, acrylamides, vinylformamides, allylalcohols, vinylphosphonates, vinyl- substituted heterocycles and unsaturated organosulfonic acids; b) a bleachin g system that comprises at least one component of the group consisting of bleaching agents, bleaching activators and bleaching catalysts.

公开(公告)号：CA2640033A1

公开(公告)日：2007-08-16

申请号：CA2640033

申请日：2007-01-31

Applicant: BASF AG

Inventor： GOETHLICH ALEXANDER ,  SCHORNICK GUNNAR ,  KLIPPEL FRANK ,  BUECHNER KARL-HEINZ ,  NIED STEPHAN

IPC: C02F5/10 ,  C02F1/44 ,  C02F5/14 ,  C08F222/06 ,  C09K8/508 ,  C09K8/575

公开(公告)号：CA2435487A1

公开(公告)日：2002-08-22

申请号：CA2435487

申请日：2002-01-25

Applicant: BASF AG

Inventor： NIED STEPHAN ,  KISTENMACHER AXEL

IPC: C11D7/22 ,  C08F210/14 ,  C08F220/04 ,  C08F222/02 ,  C08F232/04 ,  C08F236/20 ,  C11D3/00 ,  C11D3/37 ,  C11D7/10 ,  C11D7/12 ,  C11D11/00 ,  C11D17/00 ,  C11D17/06 ,  C11D17/08

Abstract: The invention relates to the use of copolymers in cleaner formulations for preventing glass from corroding when cleaned in a dishwasher. The copolymers contain: a) 20 to 70 % by weight of at least one monomer component (A) from the group of the monoethylenically unsaturated C3-C10 mono- and dicarboxylic acids or the anhydrides thereof; b) 30 to 80 % by weight of at least one monomer component (B) of the general formula (I), wherein R1, R2 and R3 independently represent H, CH3, C2H5, C3H7, COOH or OH, Y represents -C(=O)- , - C(=O)-O-, -O-, -O-C(=O)-, -O-C(=O)-O- or -C(=O)-NH-, n equals 0 or 1, R4 is either an aromatic or a linear, branched or cyclic aliphatic group with 1 to 6 carbon atoms, and R2 and R4 optionally form together an alkyl moiety with 3 to 6 carbon atoms, which can be optionally substituted by C1-C3 alkyl groups, thereby forming a cycle; c) 0 to 25 % by weight of at least one further monomer component (C) that can be copolymerized with the monomer components (A) and (B) and that is selected from the group consisting of .alpha. olefin s with 10 or more carbon atoms, polyisobutenes with an average of 12 to 100 carbon atoms, Cn-(meth)acrylates wherein n is greater than 6, hydroxy- (meth)acrylates, Cn vinylesters or Cn vinylethers wherein n is greater than 6, acrylnitriles, acrylamides, vinylformamides, allylalcohols, vinylphosphonate s, vinyl-substituted heterocycles and unsaturated organosulfonic acids.

公开(公告)号：DE10104469A1

公开(公告)日：2002-08-08

申请号：DE10104469

申请日：2001-02-01

Applicant: BASF AG

Inventor： KISTENMACHER AXEL ,  NIED STEPHAN

IPC: C11D7/22 ,  C08F210/14 ,  C08F220/04 ,  C08F222/02 ,  C08F232/04 ,  C08F236/20 ,  C11D3/00 ,  C11D3/37 ,  C11D7/10 ,  C11D7/12 ,  C11D11/00 ,  C11D17/00 ,  C11D17/06 ,  C11D17/08

Abstract: The invention relates to the use of copolymers in cleaner formulations for preventing glass from corroding when cleaned in a dishwasher. The copolymers contain: a) 20 to 70 % by weight of at least one monomer component (A) from the group of the monoethylenically unsaturated C3-C10 mono- and dicarboxylic acids or the anhydrides thereof; b) 30 to 80 % by weight of at least one monomer component (B) of the general formula (I), wherein R , R and R independently represent H, CH3, C2H5, C3H7, COOH or OH, Y represents -C(=O)-, -C(=O)-O-, -O-, -O-C(=O)-, -O-C(=O)-O- or -C(=O)-NH-, n equals 0 or 1, R is either an aromatic or a linear, branched or cyclic aliphatic group with 1 to 6 carbon atoms, and R and R optionally form together an alkyl moiety with 3 to 6 carbon atoms, which can be optionally substituted by C1-C3 alkyl groups, thereby forming a cycle; c) 0 to 25 % by weight of at least one further monomer component (C) that can be copolymerized with the monomer components (A) and (B) and that is selected from the group consisting of alpha olefins with 10 or more carbon atoms, polyisobutenes with an average of 12 to 100 carbon atoms, Cn-(meth)acrylates wherein n is greater than 6, hydroxy-(meth)acrylates, Cn vinylesters or Cn vinylethers wherein n is greater than 6, acrylnitriles, acrylamides, vinylformamides, allylalcohols, vinylphosphonates, vinyl-substituted heterocycles and unsaturated organosulfonic acids.