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公开(公告)号：AT260893B
公开(公告)日：1968-03-25
申请号：AT686965
申请日：1965-07-26
Applicant: BASF AG
Inventor： PALM CHRISTOF DR , PLATZ ROLF DR , NOHE HEINZ DR
IPC: B01J23/28
Abstract: Acrylonitrile (or methacrylonitrile) from propylene (or isobutylene) is made by ammoxidation at elevated temperature using supported catalysts containing MoO3 and SuO2 and optionally BrO3, the catalyst having been prepared by impregnating the carrier with a solution of the metal oxides on the corresponding sulphates in conc. H2SO4, followed by drying. Examples describe the passage of gaseous mixtures of olefine + oxygen + ammonia + nitrogen and/or steam over suitably prepared catalysts at 480-500 DEG C.ALSO:Catalysts of MoO3, SuO2 \sB B2O3 on a carrier are made by impregnation using solutions of oxides or sulphates in concentrated H2So4. Preferred carrier is SiO2, but Al2O3, SiC, diatomaceous earth and pumice are also mentioned. Particle sizes and bulk density data are given.
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公开(公告)号：AT257562B
公开(公告)日：1967-10-10
申请号：AT746065
申请日：1965-08-12
Applicant: BASF AG
Inventor： KROEPER HUGO DR , WEITZ HANS-MARTIN DR , PLATZ ROLF DR , SCHLOEMER KARL DR
Abstract: Tertiary alkyl acrylates or methacrylates of the formula wherein R1 denotes an H atom or the -CH3 group and the R2 radicals which may be the same or different denote an alkyl group having from 1 to 4 C atoms, are prepared by reacting acrylic or methacrylic acid with a tertiary olefin of formula where R2 has the above meaning and R3 denotes an alkylidene group with 1 to 4 C atoms, in the presence of an active bleaching earth containing from 0.005 to 0.1 milliequivalents per gram of free titratable acid at atmospheric or superatmospheric pressure and at a temperature of from 0 DEG C. to 40 DEG C. A suitable bleaching earth comprises 50 to 70% of SiO2, 10 to 30% of Al2O3, 2 to 8% of Fe2O3, 1 to 9% of MgO and small amounts of the oxides of the other alkaline earth metals (all percentages are by weight). Examples describe the production of tertiary-butyl acrylate.
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公开(公告)号：AT247494B
公开(公告)日：1966-06-10
申请号：AT727964
申请日：1964-08-21
Applicant: BASF AG
Inventor： PLATZ ROLF DR , SCHMIDT HELMUT DR , WOLF WILLY DR
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公开(公告)号：DE3265263D1
公开(公告)日：1985-09-12
申请号：DE3265263
申请日：1982-10-20
Applicant: BASF AG
Inventor： MERGER FRANZ DR , NESTLER GERHARD DR , PLATZ ROLF DR , TOWAE FRIEDRICH DR , HELLBACH HANS
IPC: C07C263/04 , C07C265/04 , C07C118/00
Abstract: Organic isocyanates, preferably alkyl, mono-, di- and/or polyisocyanates or aryl-mono-, di- and/or polyisocyanates, are prepared by thermally cleaving the corresponding urethanes at temperatures of 175 DEG C. to 600 DEG C. in the presence of carbon, preferably in an agitated carbon bed or in a fluidized bed containing carbon.
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公开(公告)号：DE3169674D1
公开(公告)日：1985-05-09
申请号：DE3169674
申请日：1981-07-13
Applicant: BASF AG
Inventor： RIEBER NORBERT DR , BOEHM HEINRICH DR , PLATZ ROLF DR , FUCHS WERNER DR
IPC: C07D498/04 , C07D498/08
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Patent Agency Ranking
公开(公告)号：DE3260283D1
公开(公告)日：1984-08-02
申请号：DE3260283
申请日：1982-02-18
Applicant: BASF AG
Inventor： WEITZ HANS-MARTIN DR , SCHNABEL ROLF DR , PLATZ ROLF DR
IPC: C07C29/136 , B01J23/00 , B01J23/72 , B01J23/76 , C07B61/00 , C07C27/00 , C07C29/132 , C07C29/149 , C07C29/17 , C07C31/20 , C07C67/00
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公开(公告)号：CH630335A5
公开(公告)日：1982-06-15
申请号：CH800177
申请日：1977-06-29
Applicant: BASF AG
Inventor： PLATZ ROLF DR , KUMMER RUDOLF DR , SCHNEIDER HEINZ-WALTER DR , SCHWIRTEN KURT DR
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公开(公告)号：DE2327867A1
公开(公告)日：1975-01-02
申请号：DE2327867
申请日：1973-06-01
Applicant: BASF AG
Inventor： SCHECKER HANS-GEORG DR , PATSCH MANFRED DR , FISCHER MARTIN DR , EILINGSFELD HEINZ DR , BAUR KARL GERHARD DR , PLATZ ROLF DR
IPC: C07C17/26 , C07C17/281 , C07C25/18
Abstract: 1-Methyl-3-halophenylindanes of formula (I) useful as intermediates for the prepn. of dyes and parasiticides, and dihalo-1-methyl-3-phenylindanes of formula (II), are prepd. by reacting a mixt. of a styrene of formula (II), are prepd. halostyrene of formula (IV) in the presence of phosphoric acid having a concn. of >=75% and opt. of org. cpds. absorbing light between 2000 and 8000 A, or by a similar reaction using halostyrenes of formula (IV) as starting materials. (where R1, R2 and R3 are each H, or alkyl, and R4 is halogen) (I) and (II) are given in good yields and method is commercially possible.
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29.发明专利
公开(公告)号：DE2144149A1
公开(公告)日：1973-03-15
申请号：DE2144149
申请日：1971-09-03
Applicant: BASF AG
Inventor： BRESSEL ULRICH DR , FUCHS WERNER DR , PLATZ ROLF DR
Abstract: Dehydrogenation of volatile 2-20C organic cpds in the presence of halogen (source) and O2 at 400-800 degrees C, in which most of the reactants are introduced through nozzles at is not 5 m/s into (consecutive) mixing zone(s) along the reactor, is carried out in a reactor with the dia. of the first mixing zone 2-100 times the nozzle dia. and length 3-30 times its dia. the mixing zone being at the lower end (in the flow direction) of a circulation tube with dia. 0.1-0.95 times the inside dia of the reaction zone, as in DT 2144148. The reaction gases leaving the reaction zone are allowed to react to completion in an after-reactor contg. a fixed catalyst. This process is suitable for dehydrogenation of such cpds. as methyl isobutyrate to methyl methacrylate in high yield (78%) and conversion (41%) and also ethylbenzene and cumene. A MgSiO3/Co3O4 catalyst is pref.
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公开(公告)号：DE1643671B1
公开(公告)日：1971-08-12
申请号：DE1643671
申请日：1967-10-06
Applicant: BASF AG
Inventor： PLATZ ROLF DR , MERGER FRANZ DR
IPC: C07C69/675 , G11B19/265
Abstract: 1,233,796. Purification of 2,2-dimethyl-1,3- propandiol mono (hydroxypivalate). BADISCHE ANILIN- & SODA-FABRIK A.G. 4 Oct., 1968 [6 Oct., 1967], No. 47184/68. Heading C2C. 2,2 - Dimethyl - 1,3 - propanediol mono (hydroxypivolate) is purified by treating at from 0 C. to 100 C. with an acid cation-exchanger. Phenolsulphonic acid, polystyrenesulphonic acid resins and bifunctional condensation resins are mentioned.
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