-
21.
公开(公告)号:AU5592699A
公开(公告)日:2000-04-20
申请号:AU5592699
申请日:1999-10-18
Applicant: BASF AG
Inventor: SCHUHMACHER PETER , PRECHTL FRANK
IPC: A61K8/00 , A61K8/02 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/368 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/72 , A61K8/81 , A61K8/85 , A61K31/74 , A61P17/00 , A61Q5/00 , A61Q17/04 , A61K7/42 , A61K31/765 , A61K31/785
Abstract: Cholesteric liquid-crystalline polymers, especially cholesteric liquid-crystalline polyesters, polycarbonates or polyamides, are used as photostable UV screens in cosmetic and pharmaceutical preparations for protecting the human epidermis or hair against UV radiation, especially in the region from 280 to 450 nm.
-
公开(公告)号:AU5494599A
公开(公告)日:2000-04-20
申请号:AU5494599
申请日:1999-10-15
Applicant: BASF AG
Inventor: HABECK THORSTON , PRECHTL FRANK
IPC: C07D301/12 , C07C45/42 , C07C45/45 , C07C45/51 , C07C45/58 , C07C45/63 , C07C45/64 , C07C45/74 , C07C49/784 , C07C49/796 , C07C49/813 , C07C49/83 , C07C49/84 , C07D303/32 , C07C49/786 , C07C49/794 , C07C49/80 , C07C49/82 , C07D303/12 , C07D303/14
Abstract: Substituted dibenzoylmethanes (I) are prepared by (a) condensing benzaldehydes (II) with acetophenones (III) to chalkones (IV), in which the exocyclic double bond is in the E- or Z-configuration or a mixture of these; and (b) converting (IV) to (I). Substituted dibenzoylmethanes (I) are prepared by (a) condensing benzaldehydes (II) with acetophenones (III) to chalkones (IV), in which the exocyclic double bond is in the E- or Z-configuration or a mixture of these; and (b) converting (IV) to (I): R = R ; and R' = R ; or R = R ; and R' = R ; R = 3-12 C alkyl; R = H, 3-12 C alkyl or 1-12 C alkoxy. Independent claims are also included for: (a) new chalkones of formula (IV); and (b) new diaryl compounds, comprising 1-halo-2-hydroxy-, 1,2-dihalo- and 1,2-epoxy-2-(4-alkyl or alkoxy-phenyl)-ethyl phenyl ketones of formula (V); R = 3-4 carbon (C) alkoxy; R = hydrogen (H) or 1-4 C alkoxy; X = halogen or hydroxyl (OH); R = halogen; or C(X)-C(Y) = an oxiran ring; X = halogen or hydroxyl (OH); R = halogen; or C(X)-C(Y) = an oxiran ring; R = 3-12 carbon (C) alkoxy; R = H, 3-12 C alkyl or 1-12 C alkoxy.
-
23.
公开(公告)号:DE19810906A1
公开(公告)日:1999-09-16
申请号:DE19810906
申请日:1998-03-13
Applicant: BASF AG
Inventor: PRECHTL FRANK , PATSCH MANFRED
IPC: C09B62/51 , C09B62/085 , C09B62/44 , C09B67/22 , D06P1/38 , C09B62/008 , D06P3/10 , D06P3/66 , D06P3/32
Abstract: New reactive azo dyes are 2-amino-1-phenylazonaphthalenesulfonic acid compounds (I) with a 4-sulfoalkylamino-6-halo-1,3,5-triazin-2-yl-amino group. New reactive azo dyes are 2-amino-1-phenylazonaphthalenesulfonic acid compounds of formula (I), with a 4-sulfoalkylamino-6-halo-1,3,5-triazin-2-yl-amino group; n, m = 0 or 1; Y = vinyl or C2H4Q; Q = a group eliminated under alkaline conditions; L = 2-6 carbon (C) alkylene, optionally with 1 or 2 non-adjacent oxygen (O) atoms or 1 or 2 imino groups in the chain; Hal = fluorine (F) or chlorine (Cl); R , R = hydrogen (H) or hydroxysulfonylmethyl; R = carboxy or hydroxysulfonyl; or R may also = H if R and/or R = hydroxysulfonylmethyl. An Independent claim is also included for mixtures containing (I) and 0.1-30 parts weight red, orange, yellow or blue reactive dye per 100 parts weight (I).
-
公开(公告)号:SI1046391T1
公开(公告)日:2005-04-30
申请号:SI200030535
申请日:2000-03-18
Applicant: BASF AG
Inventor: HABECK THORSTEN , PRECHTL FRANK , WUENSCH THOMAS , WESTENFELDER HORST , HAREMZA SYLKE , BACH THORSTEN , SPIEGEL ANJA
IPC: C07D295/14 , A61K8/00 , A61K8/41 , A61K8/44 , A61K8/49 , A61K31/136 , A61K31/196 , A61K31/24 , A61K31/40 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07C225/00 , C07C225/22 , C07C229/52 , C07D295/10 , C07D295/112 , C09K3/00 , A61K7/42
Abstract: Amino-substituted hydroxybenzophenones (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. Amino-substituted hydroxybenzophenones of formula (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. [Image] R1>, R2>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl or 3-10C cycloalkenyl, or NR1>R2> is a 5- or 6-membered ring; R3>, R4>1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, 1-12C alkoxy, 1-20C alkoxycarbonyl, 1-12C alkylamino, 1-12C dialkylamino, aryl, heteroaryl, nitrile, carboxylate, sulfonate or ammonium; X : H, COOR5> or CONR6>R7>; R5>-R7>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, (YO)oZ or aryl; Y : (CH2)x or CH(Me)CH2; x : 2-4; Z : Et, n-Pr, n-Bu or i-Pr; m : 0-3; n : 0-4; o : 1-20. Independent claims are also included for: (1) use of (I) as UV stabilizers in cosmetic and pharmaceutical compositions; (2) cosmetic and pharmaceutical compositions for protecting human skin or hair against UV light of wavelength 280-400 nm, comprising compounds (I) in a carrier, optionally in combination with other UV absorbers.
-
公开(公告)号:DE50007725D1
公开(公告)日:2004-10-21
申请号:DE50007725
申请日:2000-03-18
Applicant: BASF AG
Inventor: HABECK THORSTEN , PRECHTL FRANK , WUENSCH THOMAS , WESTENFELDER HORST , HAREMZA SYLKE , BACH THORSTEN , SPIEGEL ANJA
IPC: C07D295/14 , A61K8/00 , A61K8/41 , A61K8/44 , A61K8/49 , A61K31/136 , A61K31/196 , A61K31/24 , A61K31/40 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07C225/00 , C07C225/22 , C07C229/52 , C07D295/10 , C07D295/112 , C09K3/00 , A61K7/42
Abstract: Amino-substituted hydroxybenzophenones (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. Amino-substituted hydroxybenzophenones of formula (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. [Image] R1>, R2>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl or 3-10C cycloalkenyl, or NR1>R2> is a 5- or 6-membered ring; R3>, R4>1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, 1-12C alkoxy, 1-20C alkoxycarbonyl, 1-12C alkylamino, 1-12C dialkylamino, aryl, heteroaryl, nitrile, carboxylate, sulfonate or ammonium; X : H, COOR5> or CONR6>R7>; R5>-R7>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, (YO)oZ or aryl; Y : (CH2)x or CH(Me)CH2; x : 2-4; Z : Et, n-Pr, n-Bu or i-Pr; m : 0-3; n : 0-4; o : 1-20. Independent claims are also included for: (1) use of (I) as UV stabilizers in cosmetic and pharmaceutical compositions; (2) cosmetic and pharmaceutical compositions for protecting human skin or hair against UV light of wavelength 280-400 nm, comprising compounds (I) in a carrier, optionally in combination with other UV absorbers.
-
公开(公告)号:AU2003250860A1
公开(公告)日:2004-01-19
申请号:AU2003250860
申请日:2003-06-30
Applicant: BASF AG
Inventor: PARKER ROBERT , PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , VILL VOLKMAR , GESEKUS GUNNAR
IPC: C07D309/30 , C09K19/54 , C07D309/00
Abstract: The invention relates to chiral 3,4-dihydro-2H-pyran compounds and diastereomers thereof, and to the use of these compounds as chiral dopants for liquid-crystalline systems. The invention furthermore relates to non-polymerizable or polymerizable liquid-crystalline compositions which comprise at least one chiral 3,4-dihydro-2H-pyran compound according to the invention, to the use of these non-polymerizable or polymerizable liquid-crystalline compositions for the production of optical components, to the use of the polymerizable liquid-crystalline compositions for printing or coating substrates, for the preparation or production of dispersions and emulsions, films or pigments and optical components of this type, printed or coated substrates, dispersions and emulsions, films and pigments.
-
公开(公告)号:DE10061625A1
公开(公告)日:2002-06-13
申请号:DE10061625
申请日:2000-12-11
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE , PARKER ROBERT , KUERSCHNER KATHRIN , BRAUN MANFRED , HAHN ANTJE , FISCHER RALF
Abstract: The use of chiral, uncharged metal compounds containing two tridentate ligands with mesogenic groups, spacer groups and other groups as dopants for liquid crystalline materials. The use of chiral, uncharged compounds of formula (Ia) or (Ib) as dopants for liquid crystalline (LC) materials. ((P -Y -A -Y M -Y -)nL)2Me (Ia) ((P -Y -A -Y -M -Y -)nL)Me(L'(-Y -M -Y -A -Y -P )n')m (Ib) P , P = H, 1-12C alkyl, polymerizable groups, groups suitable for polymerization, or residues bearing such polymerizable groups; Y -Y = single bonds, -O-, -S-, -CO-, -COO-, -OCO-, -CONR-, -NRCO-, -OCOO-, -OCONR-, -NRCOO- or -NRCONR-; R = H or 1-4C alkyl; A , A = 1-30C spacer groups; M , M = mesogenic groups; n, n' = 0 or 1; m = 1, 2 or 3; Me = a transition metal of Period 4, 5 or 6 (other than technetium, silver, cadmium, gold, mercury or lanthanides) or a Main Group 14 element (other than carbon or lead); L = a tridentate ligand of formula (II); U, V, W = nitrogen-, phosphorus- or sulfur-containing groups with N, O, P or S atoms with free electron pair(s) for coordination with the central metal atom (Me); b1, b2 = 2-3C alkylene bridges attached to U and V or V and W, optionally substituted with up to two 1-12C organic residues in the case of 2C bridges and up to 4 such residues in other cases, and in which 2 adjacent carbon atoms may form part of an optionally substituted, optionally anellated benzene ring; L' = a 1-12C organic group. The groups L'(Y -M -Y -A -Y -P )n' in formula (Ib) may be different. Independent claims are also included for the following: (1) New compounds of formula (IIIa) and (IIIb). (2) LC materials containing compound(s) (Ia) and/or (Ib) or (IIIa) and/or (IIIb). ((P -Y -A -Y M -Y -)L)2Me (IIIa) ((P -Y -A -Y -M -Y -)L)Me(L'(-Y -M -Y -A -Y -P )n')m (IIIb) n' = 0 or 1.
-
公开(公告)号:DE19949284A1
公开(公告)日:2001-04-19
申请号:DE19949284
申请日:1999-10-12
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , PARKER ROBERT , VILL VOLKMAR , GESEKUS GUNNAR
IPC: C09K19/30 , A61K8/00 , A61K8/02 , A61K8/49 , A61K47/32 , A61Q1/00 , A61Q1/04 , A61Q5/00 , A61Q17/04 , C07D493/04 , C07H9/04 , C07H15/04 , C07H15/20 , C09K19/34 , C09K19/58 , A61K7/42
Abstract: Chiral glucosides of the type 2,4,7-trioxa-bicyclo(4.4.0)decane compounds are new. Chiral glucosides of the type 2,4,7-trioxa-bicyclo(4.4.0)decane compounds of formula (I) are new (when R = R = H). An Independent claim is also included for cholesteric liquid crystal compositions comprising a wider range of compounds of formula (I) (when R = R = as below), optionally in admixture with achiral liquid crystal polymerizable monomers of formula (II). R = Z -Y -(A )m-Y -M -Y -(A )n-Y -; R = H, 1-12C alkyl, 1-12C alkylcarbonyl, aryl, arylcarbonyl or Z -Y -(A )o-Y -M -Y -(A )p-Y -; R = H, 1-12C alkyl, aryl or OR ; R = H, 1-12C alkyl, aryl or OR ; R , R = H, 1-12C alkyl, 1-12C alkylcarbonyl, aryl, arylcarbonyl or Z -Y -(A )q-Y -M -Y -(A )r-Y -; A -A = 1-30C spacer group; M -M = mesogenic group; Y -Y and Y -Y = bond, -O-, -S-, -C(=O)-, -C(=O)-O-, -O-C(=O)-, -CH=CH-C(=O)-O-, -O-C(=O)-O-, -C(=O)-N(R)-, -(R)N-C(=O)-, -CH2-O-, -O-CH2-, -CH=N-, -N=CH- or -N=N-; Y , Y = bond, -C(=O)-, -O-C(=O)-, -CH=CH-C(=O)-, -(R)N-C(=O)-, -CH2- or -O-CH2-; R = H or 1-4C alkyl; Z -Z = H, 1-12C alkyl, polymerizable group or a residue containing a polymerizable group; and m-t = 0 or 1.
-
公开(公告)号:ES2228322T3
公开(公告)日:2005-04-16
申请号:ES00105806
申请日:2000-03-18
Applicant: BASF AG
Inventor: HABECK THORSTEN , PRECHTL FRANK , WUENSCH THOMAS , WESTENFELDER HORST , HAREMZA SYLKE , BACH THORSTEN , SPIEGEL ANJA
IPC: C07D295/14 , A61K8/00 , A61K8/41 , A61K8/44 , A61K8/49 , A61K31/136 , A61K31/196 , A61K31/24 , A61K31/40 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07C225/00 , C07C225/22 , C07C229/52 , C07D295/10 , C07D295/112 , C09K3/00 , A61K7/42
Abstract: Empleo de hidroxibenzofenonas aminosubstituidas de la fórmula general Ib, en la que los substituyentes tienen, independientemente entre sí, el siguiente significado: R1 y R2 significan hidrógeno, alquilo con 1 a 12 átomos de carbono, pudiendo formar los substituyentes R1 y R2 junto con el átomo de nitrógeno, con el que están enlazados, un anillo con 5 o 6 miembros; R5 significa hidrógeno, alquilo con 1 a 12 átomos de carbono, cicloalquilo con 3 a 6 átomos de carbono, como filtros de los UV-A, fotoestables, en preparaciones cosméticas y farmacéuticas para la protección de la piel humana o del cabello humano frente a las irradiaciones solares, solos o junto con compuestos que absorben en el intervalo UV, en sí conocidos, para preparaciones cosméticas y farmacéuticas.
-
公开(公告)号:DE10229530A1
公开(公告)日:2004-01-15
申请号:DE10229530
申请日:2002-07-01
Applicant: BASF AG
Inventor: PARKER ROBERT , PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , VILL VOLKMAR , GESEKUS GUNNAR
IPC: C07D309/30 , C09K19/54 , C07D309/16 , C09K19/34
Abstract: The invention relates to chiral 3,4-dihydro-2H-pyran compounds and diastereomers thereof, and to the use of these compounds as chiral dopants for liquid-crystalline systems. The invention furthermore relates to non-polymerizable or polymerizable liquid-crystalline compositions which comprise at least one chiral 3,4-dihydro-2H-pyran compound according to the invention, to the use of these non-polymerizable or polymerizable liquid-crystalline compositions for the production of optical components, to the use of the polymerizable liquid-crystalline compositions for printing or coating substrates, for the preparation or production of dispersions and emulsions, films or pigments and optical components of this type, printed or coated substrates, dispersions and emulsions, films and pigments.
-
-
-
-
-
-
-
-
-