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公开(公告)号:DE10155470A1
公开(公告)日:2003-05-22
申请号:DE10155470
申请日:2001-11-12
Applicant: BASF AG
Inventor: BITTERLICH STEFAN , REHFINGER ALWIN , BERG ANNE
IPC: B01D53/22 , B01J19/24 , C07D301/03 , C07D301/12 , C07C7/144 , C07D303/04
Abstract: A method for the synthesis of propylene oxide (PO) by epoxidation of propene with recovery of unreacted propene, in which propene is recovered from part or all of the off-stream by (i) addition of nitrogen, (ii) compression, (iii) condensation, (iv) gas permeation and (v) separation. An Independent claim is also included for apparatus for use in this method, comprising a nitrogen feed, a compression unit, a condensation unit, an organophilic membrane unit and a separation unit.
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公开(公告)号:DE59903972D1
公开(公告)日:2003-02-13
申请号:DE59903972
申请日:1999-02-23
Applicant: BASF AG
Inventor: VOIT GUIDO , OHLBACH FRANK , LUYKEN HERMANN , MERGER MARTIN , REHFINGER ALWIN , FISCHER HARTMUTH , BASSLER PETER , ANSMANN ANDREAS
IPC: B01J23/02 , B01J23/78 , C07B61/00 , C07C209/00 , C07C209/48 , C07C211/09 , C07C211/12 , C07C253/30 , C07C255/24
Abstract: A process for hydrogenation of aliphatic alpha, omega-dinitriles in the presence of a heterogeneous fixed bed catalyst comprises using a reaction mixture comprising from 2 mumol to 30 mmol NA, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, based on 10 mol of aliphatic alpha, omega-dinitrile used.
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公开(公告)号:CA2455718A1
公开(公告)日:2003-02-13
申请号:CA2455718
申请日:2002-07-30
Applicant: BASF AG
Inventor: RIEBER NORBERT , RUDOLF PETER , BASSLER PETER , BERG ANNE , REHFINGER ALWIN , TELES JOAQUIM HENRIQUE
IPC: C07D301/12 , C07D301/32
Abstract: The invention relates to a method for the production of propylene oxide, comprising the following steps: (a) propene is reacted with hydrogen peroxid e in a solvent in the presence of a suitable catalyst in order to obtain a mixture (G0) of propylene oxide, solvent, unreacted propene, unreacted hydrogen peroxide and oxygen, (b) the propylene oxide is separated from the mixture (G0) in such a way that a mixture (G1) of unreacted propene and oxyg en is obtained, and (c) the mixture (G1) is used.
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公开(公告)号:CA2453988A1
公开(公告)日:2003-01-30
申请号:CA2453988
申请日:2002-07-18
Applicant: BASF AG
Inventor: BERG ANNE , BASSLER PETER , RIEBER NORBERT , TELES JOAQUIM HENRIQUE , REHFINGER ALWIN , RUDOLF PETER
IPC: C07D301/12
Abstract: The invention relates to a method for producing propylene oxide, comprising at least the following steps: (a) propene is reacted with a hydroperoxide in a solvent in the presence of a zeolite catalyst, in order to obtain a mixture (G0), said mixture (G0) containing propylene oxide, solvent, non-reacted propene, non-reacted hydroperoxide and oxygen; (b) the propylene oxide is separated from the mixture (G0) in such a way that a mixture (G1) is obtaine d which comprises non-reacted propene and oxygen; (c) the mixture (G1) is brought into contact with a liquid medium containing at least solvent, in order to obtain the mixtures (G2) and (G3), said mixture (G3) containing a part of the non-reacted propene and oxygen, and said mixture (G2) containing the solvent and the rest of the propene, the separated mixture (G3) of non- reacted propene and oxygen having a ratio of oxygen to propene which renders the mixture (G3) non-inflammable, and the mixture (G2) supplying at least on e reaction between the propene and the hydroperoxide.
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公开(公告)号:CA2414779A1
公开(公告)日:2003-01-06
申请号:CA2414779
申请日:2001-07-05
Applicant: BASF AG
Inventor: RIEBER NORBERT , BASSLER PETER , TELES JOAQUIM HENRIQUE , WENZEL ANNE , RUDOLF PETER , REHFINGER ALWIN
IPC: C07D301/12 , C07D301/32
Abstract: The invention relates to a method for the production of propylene oxide in t he presence of methanol, during which propylene oxide is separated off from a mixture, comprising propylene oxide and methanol and the resulting mixture comprising methanol is worked up. The invention is characterised in that on working up, methanol is separated from a mixture containing methanol and methyl formate.
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公开(公告)号:DE10015246A1
公开(公告)日:2001-10-04
申请号:DE10015246
申请日:2000-03-28
Applicant: BASF AG
Inventor: MUELLER ULRICH , TELES JOAQUIM HENRIQUE , RIEBER NORBERT , WALCH ANDREAS , BASLER PETER , REHFINGER ALWIN , WENZEL ANNE , HARDER WOLFGANG
Abstract: Continuous reaction of an organic compound with hydroperoxide using a catalyst comprises using at least two parallel reactors and a high stream flow. An independent claim is included for the apparatus used comprising at least two parallel isothermal fixed bed reactors, a separator(s) and an adiabatic fixed bed reactor(s).
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公开(公告)号:BG63299B1
公开(公告)日:2001-09-28
申请号:BG10163197
申请日:1997-06-17
Applicant: BASF AG
Inventor: MELDER JOHANN-PETER , SCHNURR WERNER , FLICK KLEMENS , EBEL KLAUS , WITZEL TOM , FISCHER ROLF , HARDER WOLFGANG , REHFINGER ALWIN
IPC: B01J23/89 , B01J23/76 , B01J23/889 , B01J27/18 , B01J37/02 , C07B61/00 , C07C253/30 , C07C255/24
Abstract: The invention relates to the preparation of aliphatic -aminonitriles by partial hydrogenation of aliphatic dinitriles at elevated temperature and higher pressure, in the presence of a solvent and catalyst. Catalyst, containing the following is used: (a) compound based on metal, e.g. nickel, cobalt, iron, ruthenium and rhodium; (b) from 0.01 to 25 wt.% promotor to component (a) based on metal such as palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic, antimony, bismith, silicon, titanium, zirconium and the rare earth elements, and (c) from 0 to 5 wt.% compound to component (a) based on alkali or alkaliearth metal, provided that component (a) is different from an iron-based compound or from iron, as well as from the metals cobalt, ruthenium or rhodium when component (b) is promotor based on a metal from the group containing titanium, managanese, chromium and molybdenum. An additional condition is that when component (a) is a compound based on ruthenium or rhodium separately, or of ruthenium and rhodium, or of nickel and rhodium, promotor (b) can optionally be dropped. 8 claims
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公开(公告)号:ES2156401T3
公开(公告)日:2001-06-16
申请号:ES97941948
申请日:1997-08-21
Applicant: BASF AG
Inventor: VOIT GUIDO , FLICK KLEMENS , LUYKEN HERMANN , REHFINGER ALWIN , BASSLER PETER
IPC: B01J23/78 , C07B61/00 , C07C209/48 , C07C211/12 , C07C253/30 , C07C255/24
Abstract: PCT No. PCT/EP97/04542 Sec. 371 Date Mar. 10, 1999 Sec. 102(e) Date Mar. 10, 1999 PCT Filed Aug. 21, 1997 PCT Pub. No. WO98/11051 PCT Pub. Date Mar. 19, 1998A process for coproduction of 6-aminocapronitrile and hexamethylenediamine starting from a mixture comprising a phosphorus-containing compound and essentially adiponitrile and obtained by reaction of butadiene with hydrocyanic acid in the presence of a catalyst comprising a phosphorus-containing compound comprises (1) reducing the weight proportion of phosphorus-containing compound, calculated as phosphorus, in the mixture, (2) partially hydrogenating the resulting mixture in the presence of a catalyst to form an alpha , omega -aminonitrile, and (3) removing 6-aminocapronitrile and hexamethylenediamine from the mixture.
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公开(公告)号:BR9913250A
公开(公告)日:2001-05-22
申请号:BR9913250
申请日:1999-08-17
Applicant: BASF AG
Inventor: LUYKEN HERMANN , OHLBACH FRANK , ANSMANN ANDREAS , BASSLER PETER , FISCHER ROLF , MELDER JOHANN-PETER , MERGER MARTIN , REHFINGER ALWIN , VOIT GUIDO , ACHHAMMER G NTHER
IPC: C07B61/00 , C07C209/48 , C07C209/84 , C07C211/12 , C07C253/30 , C07C253/34 , C07C255/24
Abstract: A process for the coproduction of 6-aminocapronitrile and hexamethylenediamine starting from adiponitrile bya) hydrogenating adiponitrile in the presence of a catalyst comprising an element of the eighth transition group as catalytically active component, to obtain a mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers,b) distillatively removing hexamethylenediamine from the mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers, and eithercl) distillatively removing 6-aminocapronitrile, and thend1) distillatively removing adiponitrile, orc2) simultaneously distillatively removing 6-aminocapronitrile and adiponitrile into separate fractionsis characterized by base of column temperatures below 185° C. in steps d1) or c2).
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公开(公告)号:DE19954055A1
公开(公告)日:2001-05-17
申请号:DE19954055
申请日:1999-11-10
Applicant: BASF AG
Inventor: BERRSCHE HELMUT , GABEL SABINE , IFFLAND GABRIELE , CIPRIAN JUERGEN , WENZEL ANNE , TELES JOAQUIM HENRIQUE , REHFINGER ALWIN
IPC: B01J47/00 , B01J47/02 , B01J47/026 , C01B15/013 , C07D301/12
Abstract: A device for removal of at least one salt from a hydrogen peroxide solution, by ion exchange, is characterised in that the device comprises at least one ion exchange bed (I) with a flow area F and height H, whereby the height H of the ion exchange bed is less than or equal to 2, 5.F .
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