公开(公告)号：DE10211907A1

公开(公告)日：2003-10-02

申请号：DE10211907

申请日：2002-03-18

Applicant: BASF AG

Inventor： BRODHAGEN ANDREAS ,  ROESLER BEATRICE ,  RUEHL THOMAS ,  WOLF HANS-JOSEF ,  ROSOWSKI FRANK

IPC: C07C29/50 ,  C07C45/36 ,  C07C51/265 ,  C07C63/04

公开(公告)号：DE10159817A1

公开(公告)日：2003-09-11

申请号：DE10159817

申请日：2001-12-06

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ROSOWSKI FRANK ,  HAAKE MATHIAS ,  BEY OLIVER ,  SCHWAB EKKEHARD ,  ZEHNER PETER

IPC: B01J19/24 ,  B01J19/32 ,  B01J21/06 ,  B01J23/00 ,  B01J23/22 ,  B01J23/68 ,  B01J27/198 ,  B01J35/00 ,  B01J37/02 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89 ,  B01J8/02 ,  B01J23/66

Abstract: Ordered packing, for a reactor for gas phase oxidation of o-xylene and/or naphthalene with molecular oxygen to form phthalic acid anhydride, has flow channels parallel to the long axis of reactor that fills the reactor cross-section to an edge gap whereby the maximum width of the edge gap measured in the plane at right angles to the long axis of the reactor is less than the hydraulic diameter of the flow channels. An ordered packing (1), for a reactor for the gas phase oxidation of o-xylene and/or naphthalene with a molecular oxygen containing gas stream to form phthalic acid anhydride, has flow channels (2) parallel to the long axis of the reactor that fill the reactor cross-section to an edge gap (3) whereby the maximum width of the edge gap (3) measured in the plane at right angles to the long axis of the reactor is less than the hydraulic diameter of the flow channels (2), preferably less than half of the hydraulic diameter of the flow channels (2) and the packing (1) is coated with an oxidation catalyst for phthalic acid anhydride. Independent claims are included for processes for the application or coating of an oxidation catalyst onto the packing (1) by dipping or spraying a suspension containing the catalyst or catalyst precursor onto the packing (1).

公开(公告)号：DE10028582A1

公开(公告)日：2001-12-20

申请号：DE10028582

申请日：2000-06-14

Applicant: BASF AG

Inventor： MACHHAMMER OTTO ,  SCHINDLER GOETZ-PETER ,  TENTEN ANDREAS ,  HARTH KLAUS ,  ZEHNER PETER ,  MUELLER-ENGEL KLAUS JOACHIM ,  ROSOWSKI FRANK ,  BORGMEIER FRIEDER

IPC: C07C27/14 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C45/33 ,  C07C45/35 ,  C07C47/22 ,  C07C51/215 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/07 ,  C07C45/78

Abstract: Molecular nitrogen is used as a diluent gas in the partial oxidation stage of a 3-stage method for the production of acrolein and acrylic acid from propane by: (A) partial gas-phase dehydrogenation; (B) removal of hydrogen and partial gas-phase oxidation of propene; and (C) separation of product and recycling of unreacted propane to stage (A). Acrolein and acrylic acid are produced from propane by: (A) partial gas-phase dehydrogenation of propane in presence of a heterogeneous catalyst to form a mixture (A) containing molecular hydrogen, propene and unreacted propane; (B) removing at least some of the hydrogen from the components other than propane and propene to give a mixture (A'), feeding (A') into oxidation reactor(s) and subjecting the propylene to selective, gas-phase partial oxidation in presence of heterogeneous catalyst to give a gas mixture (B) containing acrolein and acrylic acid; and (C) separating the required product and recycling unreacted propane (at least) to stage (A). In this process, molecular nitrogen is used as diluent gas in the partial oxidation stage (B).

公开(公告)号：DE19922113A1

公开(公告)日：2000-08-10

申请号：DE19922113

申请日：1999-05-12

Applicant: BASF AG

Inventor： ROSOWSKI FRANK ,  HIBST HARTMUT

IPC: B01J23/00 ,  B01J27/19 ,  B01J35/00 ,  C01G39/00 ,  C04B35/01 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C01G1/02

Abstract: Multimetal oxide composition is a multimetal oxide (I) of molybdenum with vanadium, niobium, tantalum, tungsten and/or rhenium and boron, silicon, phosphorus, germanium, arsenic and/or antimony and optionally other metal(s) in the form of crystallites of constant composition. Multimetal oxide composition is of formula (I); (A)p(B)q (I) Mo12X aX bX cX dX eOx (II) MofX gX hOy (III) A = a multimetal oxide of formula (II); B = a multimetal oxide of formula (III); X = hydrogen, up to 97 mole-% of which may be replaced by ammonium, potassium, rubidium and/or cesium; X = vanadium, niobium (Nb), tantalum (Ta), tungsten and/or rhenium; X = boron, silicon, phosphorus, germanium, arsenic and/or antimony (Sb); X = chromium, manganese, iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), magnesium (Mg), calcium (Ca), strontium (Sr) and/or barium (Ba); X = sulfur; X = Cu, Fe, Co, Ni, Zn, cadmium, Mn, Mg, Ca, Sr and/or Ba; X = Nb, Ta and/or Sb; a = 1-3; b = 0.1-2; c = 0-5; d, e = 0-1; f = 0-2; g = 0.5-1.5; h = 2-4; x, y = values depending on the valency and frequency of elements other than oxygen; p = 1; and q = 0; or p, q not = 0 and p/q = (160-1):1 The standard deviation of the stoichiometric coefficient a of the variable X of individual crystallites of component A is less than 0.40, preferably less than 0.20, especially less than 0.11. An Independent claim is also included for the preparation of multimetal oxide (I).

公开(公告)号：CZ304023B6

公开(公告)日：2013-08-28

申请号：CZ20024057

申请日：2001-06-08

Applicant: BASF AG

Inventor： MACHHAMMER OTTO ,  SCHINDLER GOETZ-PETER ,  TENTEN ANDREAS ,  HARTH KLAUS ,  ZEHNER PETER ,  MUELLER-ENGEL KLAUS JOACHIM ,  ROSOWSKI FRANK ,  BORGMEIER FRIEDER

IPC: C07C27/14 ,  C07C45/33 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C45/35 ,  C07C47/22 ,  C07C51/215 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/07

Abstract: Zpusob prípravy akroleinu nebo kyseliny akrylové nebo jejich smesi z propanu, pri kterém se propan podrobí v první reakcní etape cástecné dehydrogenaci za podmínek heterogenní katalýzy pro získání propenu, ze slozek obsazených v produktové plynné smesi, vytvorené v první reakcní etape, jiných nez propen a propan, se potom odseparuje alespon cást prítomného molekulárního vodíku z uvedené smesi a produktová plynná smes se potom pouzívá pro prípravu akroleinu a/nebo kyseliny akrylové katalytickou oxidací propylenu v plynné fázi, pricemz molekulární dusík je prítomen pro zredení reakcní plynné smesi behem oxidace propylenu.

公开(公告)号：ES2280968T3

公开(公告)日：2007-09-16

申请号：ES04734261

申请日：2004-05-21

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZUHLKE JURGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: C07C51/265 ,  C07C51/31 ,  C07C63/16

Abstract: Procedimiento para la obtención de anhídrido de ácido ftálico, en el que se conduce una corriente gaseosa, que comprende un hidrocarburo aromático seleccionado entre o-xileno y/o naftalina, y un gas que contiene oxígeno molecular, a temperatura elevada a través de un lecho de un primer catalizador, y un lecho de un segundo catalizador dispuesto en el sentido de circulación de la corriente gaseosa, con la corriente respecto al primer catalizador, con actividad más elevada que el primer catalizador, conteniendo la masa con actividad catalítica del primer catalizador, al menos óxido de vanadio, dióxido de titanio y óxido de antimonio, y ascendiendo la proporción de vanadio, calculado como V2O5, respecto a antimonio, calculado como Sb2O3, a 3, 5:1 4, 5:1, preferentemente 3, 8:1 a 4, 5:1, en el primer catalizador.

公开(公告)号：IN411CH2006A

公开(公告)日：2007-07-06

申请号：IN411CH2006

申请日：2006-02-01

Applicant: BASF AG

Inventor： NETO SAMUEL ,  ZUEHLKE JUERGEN ,  STORCK SEBASTIAN ,  ROSOWSKI FRANK

IPC: B01J21/06 ,  B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07C51/265

Abstract: A catalyst for gas-phase oxidations which comprises an inert support and a catalytically active composition comprising transition metal oxides applied thereto, or a precatalyst, is described. The (pre)catalyst is obtained by treating the inert support with an aqueous suspension or solution of the transition metal oxides or their precursor compounds, where the suspension contains a binder dispersion and the binder is a copolymer of an alpha-olefin and a vinyl-C 2 -C 4 -carboxylate whose vinyl C 2 -C 4 -carboxylate content is at least 62 mol %.

公开(公告)号：PL1636161T3

公开(公告)日：2007-06-29

申请号：PL04734261

申请日：2004-05-21

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZÜHLKE JÜRGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: C07C51/265 ,  C07C51/31 ,  C07C63/16

公开(公告)号：AT360480T

公开(公告)日：2007-05-15

申请号：AT04763675

申请日：2004-07-30

Applicant: BASF AG

Inventor： NETO SAMUEL ,  ZUEHLKE JUERGEN ,  STORCK SEBASTIAN ,  ROSOWSKI FRANK

IPC: B01J21/06 ,  B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07C51/265 ,  B01J31/06 ,  C07C51/215

Abstract: A catalyst for gas-phase oxidations which comprises an inert support and a catalytically active composition comprising transition metal oxides applied thereto, or a precatalyst, is described. The (pre)catalyst is obtained by treating the inert support with an aqueous suspension or solution of the transition metal oxides or their precursor compounds, where the suspension contains a binder dispersion and the binder is a copolymer of an alpha-olefin and a vinyl-C 2 -C 4 -carboxylate whose vinyl C 2 -C 4 -carboxylate content is at least 62 mol %.

公开(公告)号：DE50306580D1

公开(公告)日：2007-04-05

申请号：DE50306580

申请日：2003-02-04

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ROSOWSKI FRANK ,  BAIER MICHAEL ,  TENTEN ANDREAS ,  WOLF HANS-JOSEF

IPC: C07C51/265 ,  C07D307/89 ,  B01J23/22 ,  B01J35/00 ,  C07B61/00 ,  C07C51/31 ,  C07C63/16

Abstract: Production of phthalic anhydride by gas-phase oxidation of o-xylene or naphthalene in a tubular reactor involves using three or more different catalyst beds with controlled hot-spot temperatures. A method for the production of phthalic anhydride (I) by gas-phase oxidation of xylene and/or naphthalene in a thermostatted tube-bank reactor on 3 or more solid-bed catalysts in 3 different layers involves carrying out the process in such a way that the peak temperature (T2) in the second catalyst layer (in the direction of flow) is up to 50 degrees C below the peak temperature (T1) in the first layer and the peak temperature (T3) in the third layer is 30-100 degrees C below T1.