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公开(公告)号：DE10361823A1
公开(公告)日：2005-08-11
申请号：DE10361823
申请日：2003-12-30
Applicant: BASF AG
Inventor： JOHANN THORSTEN , SCHINDLER GOETZ-PETER , BRODHAGEN ANDREAS , CRONE SVEN , BENFER REGINA , SIGL MARCUS , DUDA MARK
Abstract: The disclosure involves a process for the preparation of butadiene and 1-butene. The process includes at least a first catalytic dehydrogenation of n-butane to obtain a gas stream which is followed by at least a second oxidative dehydrogenation to form a second gas stream. The second gas stream is then subjected to distillation and isomeration steps to obtain butadiene and 1-butene.
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公开(公告)号：DE10333755A1
公开(公告)日：2005-03-31
申请号：DE10333755
申请日：2003-07-24
Applicant: BASF AG
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公开(公告)号：DE50103645D1
公开(公告)日：2004-10-21
申请号：DE50103645
申请日：2001-06-08
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , SCHINDLER GOETZ-PETER , TENTEN ANDREAS , HARTH KLAUS , ZEHNER PETER , MUELLER-ENGEL JOACHIM , ROSOWSKI FRANK , BORGMEIER FRIEDER
IPC: C07C27/14 , C07B61/00 , C07C5/333 , C07C11/06 , C07C45/33 , C07C45/35 , C07C47/22 , C07C51/215 , C07C51/25 , C07C57/04 , C07C57/05 , C07C57/07
Abstract: In a process for the preparation of acrolein or acrylic acid or a mixture thereof from propane, the propane is subjected, in a first reaction stage, to a partial dehydrogenation under heterogeneous catalysis to give propene, of the components contained in the product gas mixture formed in the first reaction stage other than propene and propane at least a portion of the molecular hydrogen present is then separated off from said mixture and the product gas mixture is then used for the preparation of acrolein and/or acrylic acid by gas-phase catalytic propylene oxidation, molecular nitrogen being present for diluting the reaction gas mixture during the propylene oxidation.
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公开(公告)号：AT276224T
公开(公告)日：2004-10-15
申请号：AT01960291
申请日：2001-06-08
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , SCHINDLER GOETZ-PETER , TENTEN ANDREAS , HARTH KLAUS , ZEHNER PETER , MUELLER-ENGEL KLAUS JOACHIM , ROSOWSKI FRANK , BORGMEIER FRIEDER
IPC: C07C27/14 , C07B61/00 , C07C5/333 , C07C11/06 , C07C45/33 , C07C45/35 , C07C47/22 , C07C51/215 , C07C51/25 , C07C57/04 , C07C57/05 , C07C57/07
Abstract: In a process for the preparation of acrolein or acrylic acid or a mixture thereof from propane, the propane is subjected, in a first reaction stage, to a partial dehydrogenation under heterogeneous catalysis to give propene, of the components contained in the product gas mixture formed in the first reaction stage other than propene and propane at least a portion of the molecular hydrogen present is then separated off from said mixture and the product gas mixture is then used for the preparation of acrolein and/or acrylic acid by gas-phase catalytic propylene oxidation, molecular nitrogen being present for diluting the reaction gas mixture during the propylene oxidation.
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公开(公告)号：EA004599B1
公开(公告)日：2004-06-24
申请号：EA200300404
申请日：2001-09-14
Applicant: BASF AG
Inventor： SCHINDLER GOETZ-PETER , MACHHAMMER OTTO , HARTH KLAUS , MULLER-ENGEL KLAUS JOACHIM , ZEHNER PETER
IPC: C07C5/333 , B01J23/58 , B01J23/62 , B01J23/63 , B01J23/96 , B01J38/14 , C07B61/00 , C07C5/32 , C07C11/06 , C07C5/48 , B01J21/10
Abstract: Изобретениекасаетсяспособагетерогеннокатализируемогодегидрированияв однойилинесколькихреакционныхзонаходногоилинесколькихподвергаемыхдегидрированиюуглеводородовС-Свреакционнойсмеси, содержащейпоследние, причемпоменьшеймеречастьнеобходимогодлядегидрированиятепланеменеечемв однойреакционнойзонеполучаетсязасчетсгоранияводорода, углеводорода(ов) и/илиуглеродав присутствиисодержащегокислородгазанепосредственнов реакционнойгазовойсмеси, причемгазоваяреакционнаясмесь, котораясодержитдегидрируемыйуглеводородилидегидрируемыеуглеводороды, контактируетс катализаторомдегидрирования - кислотыЛьюиса, которыйв основномнепроявляеткислотностипоБренстеду.
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Patent Agency Ranking
公开(公告)号：BR0115854A
公开(公告)日：2004-01-20
申请号：BR0115854
申请日：2001-12-03
Applicant: BASF AG
Inventor： SCHINDLER GOETZ-PETER , MAGIN WERNER , HARTH KLAUS
Abstract: A process for regenerating a dehydrogenation catalyst comprises the steps (a)-(f): (a) flushing with inert gas at a pressure of from 0.5 to 2.0 bar and a gas hourly velocity of from 1000 to 50 000 h -1 ; (b) passing an oxygen-containing gas mixture comprising an inert gas through the catalyst at a pressure of from 2 to 20 bar and a gas hourly velocity of from 1000 to 50 000 h -1 for from 0.25 to 24 hours while increasing the oxygen concentration stepwise or continuously from an initial value of from 0.01 to 1% by volume of O 2 to a final value of from 10 to 25% by volume of O 2 ; (c) optionally passing an oxygen-containing gas mixture comprising an inert gas through the catalyst at a pressure of from 0.5 to 20 bar and a gas hourly velocity of from 10 to 500 h -1 for from 0.25 to 100 h, with the oxygen concentration being from 10 to 25% by volume of O 2 ; (d) optionally changing the pressure repeatedly, rapidly and in opposite directions by a factor of from 2 to 20 within the range from 0.5 to 20 bar; (e) flushing with an inert gas; (f) activating the catalyst by means of hydrogen; where at least one of the steps (c) or (d) is carried out and the entire regeneration process is carried out at from 300 to 800° C.
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公开(公告)号：CA2482790A1
公开(公告)日：2003-11-13
申请号：CA2482790
申请日：2003-05-02
Applicant: BASF AG
Inventor： HESSE MICHAEL , SCHINDLER GOETZ-PETER , HARTH KLAUS , SIMON FALK , HOFSTADT OTTO
IPC: B01J23/62 , B01J21/06 , B01J23/63 , B01J35/00 , B01J35/10 , B01J37/00 , C07B61/00 , C07C5/333 , C07C11/06 , B01J23/24 , C07C5/327 , B01J23/40 , B01J23/70
Abstract: The invention relates to a method for the production of a catalyst carrier, wherein Zirconium dioxide powder is mixed with a binding agent, optionally a pore forming agent, optionally an acid, water and optionally other additives to form a kneadable mass, said mass is homogenized in order to form shaped bodies, dried and calcinated. The binding agent is a monomer, oligomer or polymer organosilicon compound.Suitable binding agents are monomer, oligomer or polymer silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halogensilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also relates to a catalyst carrier thu s produced, a catalyst containing said carrier and the use thereof as a dehydrogenation catalyst.
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公开(公告)号：DE10159615A1
公开(公告)日：2003-06-12
申请号：DE10159615
申请日：2001-12-05
Applicant: BASF AG
Inventor： HARTH KLAUS , SCHINDLER GOETZ-PETER , WALSDORFF CHRISTIAN , KUHRS CHRISTIAN , SIMON FALK
IPC: C07C17/02 , C07C17/15 , C07C17/152 , C07C17/156 , C07C17/158 , C07C17/25 , C07C17/38 , C07C19/045 , C07C21/06
Abstract: The invention relates to a method for the production of 1,2-dichloroethane, comprising the following steps: (A) feeding a feed gas flow containing an ethane into a dehydrogenation zone; dehydrogenating the ethane into ethene while obtaining a product gas flow containing ethane, ethene and minor constituents; (B) feeding the dehydrogenated product gas flow containing the ethane and ethene into a flow or several partial flows, optionally after separating the minor constituents, in one or more chlorination zones; chlorinating ethene into 1,2-dichloroethane while obtaining one or more product gas flows containing 1,2-dichloroethane, ethane and optionally other minor; obtaining 1,2-dichloroethane and one or more circuit gas flows containing ethane and recirculating the circuit gas flow(s) containing ethane to the ethane dehydrogenation.
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公开(公告)号：NO20032501D0
公开(公告)日：2003-06-03
申请号：NO20032501
申请日：2003-06-03
Applicant: BASF AG
Inventor： SCHINDLER GOETZ-PETER , MAGIN WERNER , HARTH KLAUS
Abstract: A process for regenerating a dehydrogenation catalyst comprises the steps (a)-(f): (a) flushing with inert gas at a pressure of from 0.5 to 2.0 bar and a gas hourly velocity of from 1000 to 50 000 h -1 ; (b) passing an oxygen-containing gas mixture comprising an inert gas through the catalyst at a pressure of from 2 to 20 bar and a gas hourly velocity of from 1000 to 50 000 h -1 for from 0.25 to 24 hours while increasing the oxygen concentration stepwise or continuously from an initial value of from 0.01 to 1% by volume of O 2 to a final value of from 10 to 25% by volume of O 2 ; (c) optionally passing an oxygen-containing gas mixture comprising an inert gas through the catalyst at a pressure of from 0.5 to 20 bar and a gas hourly velocity of from 10 to 500 h -1 for from 0.25 to 100 h, with the oxygen concentration being from 10 to 25% by volume of O 2 ; (d) optionally changing the pressure repeatedly, rapidly and in opposite directions by a factor of from 2 to 20 within the range from 0.5 to 20 bar; (e) flushing with an inert gas; (f) activating the catalyst by means of hydrogen; where at least one of the steps (c) or (d) is carried out and the entire regeneration process is carried out at from 300 to 800° C.
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公开(公告)号：DE10060099A1
公开(公告)日：2002-06-06
申请号：DE10060099
申请日：2000-12-04
Applicant: BASF AG
Inventor： SCHINDLER GOETZ-PETER , MAGIN WERNER , HARTH KLAUS
Abstract: The invention relates to a method for the regeneration of a dehydrogenation catalyst, comprising the steps (a)-(f): (a) flushing with inert gas at a pressure of 0.5 to 2.0 bar and a gas loading of 1 000 to 50 000 h ; (b) passage of an oxygen-containing gas mixture, containing an inert gas, at a pressure of 2 to 20 bar and a gas loading of 1,000 to 50,000 h , over a period of 0.25 to 24 h with sequential or continuous increase of the oxygen concentration from an initial value of 0.01 to 1 vol. % O2 to a final value of 10 to 25 vol. % O2; (c) optional passage of an oxygen-containing gas mixture, containing an inert gas, at a pressure of 0.5 to 20 bar and a gas loading of 10 to 500h over a period of 0.25 to 100 h with an oxygen concentration of 10 to 25 vol. % O2; (d) optional repeated rapid cyclical pressure changes of a factor of 2 to 20, within the range 0.5 to 20 bar; (e) flushing with an inert gas; (f) activation of the catalyst with hydrogen, whereby at least one of steps (c) or (d) is carried out and the whole regeneration process occurs at a temperature of between 300 and 800 DEG C.
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