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公开(公告)号:DE10016810A1
公开(公告)日:2001-10-11
申请号:DE10016810
申请日:2000-04-05
Applicant: BASF AG
Inventor: SEYFFER HERMANN , LEMAN TITUS , CLAASSEN PETER , OLFERMANN KAI , WIRTH THOMAS , SCHMIDT-THUEMMES JUERGEN
Abstract: The invention relates to a method for impregnating base paper or nonwovens with an aqueous dispersion of a polymer that is composed of radically polymerizable compounds (monomers), characterized in that methacrylic acid accounts for 0.1 to 5 wt.- % of the monomers. The impregnated base paper or nonwovens are preferably used for producing decorative paper.
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公开(公告)号:DE10008276A1
公开(公告)日:2001-08-30
申请号:DE10008276
申请日:2000-02-23
Applicant: BASF AG
Inventor: SCHMIDT-THUEMMES JUERGEN , WIRTH THOMAS , KIRSCH STEFAN
IPC: D21H19/58
Abstract: The present invention provides paper coating slips comprising a low-crosslink copolymer as their binder.
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公开(公告)号:AU619386B2
公开(公告)日:1992-01-23
申请号:AU4985090
申请日:1990-02-16
Applicant: BASF AG
Inventor: MEISTER MARTIN , ECKERT GUENTER , SCHMIDT-THUEMMES JUERGEN , ZOSEL ALBRECHT
IPC: C08F2/22 , C08F236/12 , C08F265/08 , C08F279/02 , C14C11/00 , C08F210/12
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公开(公告)号:DE502004005281D1
公开(公告)日:2007-11-29
申请号:DE502004005281
申请日:2004-07-08
Applicant: BASF AG
Inventor: GAO JUN , KONG XIANG-MING , HUNGENBERG KLAUS-DIETER , SCHMIDT-THUEMMES JUERGEN
IPC: C08F2/22
Abstract: An aqueous polymer dispersion is prepared by radical aqueous emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of a dispersant by mixing reactants at no greater than the initiation temperature and heating the mixture to a final temperature during the addition of at least one monomer. An aqueous polymer dispersion (I) is prepared by radical aqueous emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of a dispersant. The process comprises: (a) mixing in a reaction vessel, at no greater than the initiation temperature, deionized water, an oil soluble radical initiator, a dispersant, optionally at least a partial amount of a monomer and optionally at least a partial amount of a water-soluble radical initiator followed by; (b) heating the mixture to the initiation temperature, followed by optionally adding; (c) additional water, oil-soluble radical initiator, dispersant and monomer with the main quantity of the water-soluble radical initiator and; (d) heating the mixture to a final temperature during the addition of at least one monomer.
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公开(公告)号:BR0317824A
公开(公告)日:2005-11-29
申请号:BR0317824
申请日:2003-12-24
Applicant: BASF AG
Inventor: SCHMIDT-THUEMMES JUERGEN , HARTMANN JUERGEN , TSCHANG CHUNG-JI
IPC: C08F212/04 , C08F236/04 , C08F257/02 , C08F212/08
Abstract: The present invention provides a process for preparing a stable aqueous copolymer dispersion by free-radically initiated aqueous emulsion polymerization of a) from 19.9 to 80 parts by weight of conjugated aliphatic dienes [monomers a)], b) from 19.9 to 80 parts by weight of vinylaromatic compounds [monomers b)], c) from 0.1 to 10 parts by weight of ethylenically unsaturated carboxylic acids and/or dicarboxylic acids [monomers c)], d) from 0 to 20 parts by weight of ethylenically unsaturated carbonitriles [monomers d)], and e) from 0 to 20 parts by weight of copolymerizable compounds other than monomers b) [monomers e)], the total amount of ethylenically unsaturated monomers a) to e) being 100 parts by weight, in the presence of water and from 0.1 to 5 parts by weight, based on the total monomer amount, of emulsifiers comprising f) sulfuric monoesters of ethoxylated fatty acid alcohols and/or g) salts of esters and monoesters of alkylpolyoxyethylenesulfosuccinates, from 15 to 85% by weight of the total emulsifiers used being added within the time taken to reach up to 40% of the total conversion of the monomers a) to e), and from 1 to 50% of the carboxylic acid groups deriving from the monomers c) being neutralized by addition of base.
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公开(公告)号:CA2481797A1
公开(公告)日:2003-11-06
申请号:CA2481797
申请日:2003-04-15
Applicant: BASF AG
Inventor: SCHMIDT-THUEMMES JUERGEN , HAMERS CHRISTOPH , ETTL ROLAND
IPC: C08F4/40 , C08F212/08 , C08F236/04 , C08F251/00 , C08F251/02 , C08L51/02 , C09D151/02 , D21H17/35 , D21H21/16
Abstract: The invention relates to aqueous polymer dispersions, obtained by the radically initiated copolymerisation of (a) between 0.1 and 99.9 wt. % styre ne and/or methylstyrene, (b) between 0.1 and 99.9 wt. % 1,3-butadiene and/or isoprene and (c) between 0 and 40 wt. % of other ethylenically unsaturated copolymerisable monomers, whereby the sum of the monomers (a), (b) and (c) always equals 100, in the presence of between 10 and 40 wt. %, in relation t o the monomers used, of at least one degraded starch with a molecular weight ranging between 500 and 40,000 Mn and water soluble redox catalysts. The invention also relates to a method for producing the polymer dispersions by the radical polymerisation of the monomers (a), (b) and optionally (c) in an aqueous medium in the presence of a degraded starch with a molecular weight ranging between 500 and 10,000 Mn and redox initiators and to the use of the aqueous polymer dispersions obtained by said method as pulp sizing and surfa ce sizing agents for paper.
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公开(公告)号:DE59804931D1
公开(公告)日:2002-08-29
申请号:DE59804931
申请日:1998-11-30
Applicant: BASF AG
Inventor: LEUBE F , SCHMIDT-THUEMMES JUERGEN , ZELLER EDGAR , MAAS HEIKO
Abstract: A process for selectively hydrogenating ethylenically unsaturated double bonds in polymers P involves reacting the polymers P with hydrogen in the presence of at least one hydrogenation catalyst selected from the salts and complex compounds of rhodium and/or of ruthenium in an aqueous dispersion of the polymers P that comprises not more than 20% by volume of an organic solvent. This process can be used to give hydrogenated polymer dispersions and, from these dispersions, polymers. Also claimed are aqueous polymer dispersions comprising polymers P', which include structural units I, II and III as in claim 10, with or without structural units IV and/or V as in claim 11.
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公开(公告)号:BRPI0517794A
公开(公告)日:2008-10-21
申请号:BRPI0517794
申请日:2005-11-05
Applicant: BASF AG
Inventor: SCHMIDT-THUEMMES JUERGEN , HAMERS CHRISTOPH
IPC: D21H19/42
Abstract: An aqueous paper coating slip comprising organic polymers as binders and inorganic pigments, wherein the binders are present at least partly in the form of a pigment-polymer hybrid in which the binder is chemically or physically bound to the inorganic pigments.
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公开(公告)号:AT366267T
公开(公告)日:2007-07-15
申请号:AT03795966
申请日:2003-12-24
Applicant: BASF AG
Inventor: SCHMIDT-THUEMMES JUERGEN , HARTMANN JUERGEN , TSCHANG CHUNG-JI
IPC: C08F257/02 , C08F212/04 , C08F212/08 , C08F236/04
Abstract: The present invention provides a process for preparing a stable aqueous copolymer dispersion by free-radically initiated aqueous emulsion polymerization of a) from 19.9 to 80 parts by weight of conjugated aliphatic dienes [monomers a)], b) from 19.9 to 80 parts by weight of vinylaromatic compounds [monomers b)], c) from 0.1 to 10 parts by weight of ethylenically unsaturated carboxylic acids and/or dicarboxylic acids [monomers c)], d) from 0 to 20 parts by weight of ethylenically unsaturated carbonitriles [monomers d)], and e) from 0 to 20 parts by weight of copolymerizable compounds other than monomers b) [monomers e)], the total amount of ethylenically unsaturated monomers a) to e) being 100 parts by weight, in the presence of water and from 0.1 to 5 parts by weight, based on the total monomer amount, of emulsifiers comprising f) sulfuric monoesters of ethoxylated fatty acid alcohols and/or g) salts of esters and monoesters of alkylpolyoxyethylenesulfosuccinates, from 15 to 85% by weight of the total emulsifiers used being added within the time taken to reach up to 40% of the total conversion of the monomers a) to e), and from 1 to 50% of the carboxylic acid groups deriving from the monomers c) being neutralized by addition of base.
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公开(公告)号:CA2584919A1
公开(公告)日:2007-04-20
申请号:CA2584919
申请日:2005-11-05
Applicant: BASF AG
Inventor: KROENER HUBERTUS , SCHMIDT-THUEMMES JUERGEN
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