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公开(公告)号:AU4246278A
公开(公告)日:1979-06-21
申请号:AU4246278
申请日:1978-12-13
Applicant: BASF AG
Inventor: KEMPTER FRITZ ERDMANN , SCHUPP EBERHARD
IPC: C08G14/00 , C08G14/06 , C08G59/00 , C08G59/62 , C08L61/34 , C08L63/00 , C09D5/44 , C09D163/00 , C25D13/06 , C08G59/14
Abstract: Surface-coating binders and their use. The binders are reaction products of (A) Mannich bases obtained from one or more condensed phenols, free from ether groups, which contain two or more phenolic hydroxyl groups per molecule, one or more butadiene or isoprene homopolymers or copolymers which contain one or more groups per molecule and have a mean molecular weight of from 500 to 6,000, one or more secondary amines which contain one or more hydroxyalkyl groups per molecule, or a mixture of such secondary amines with another secondary amine, and formaldehyde or a formaldehyde donor, with (B) one or more epoxy resins. These surface-coating binders are used especially for the cathodic electrocoating of metal articles.
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公开(公告)号:DE10338447A1
公开(公告)日:2005-03-31
申请号:DE10338447
申请日:2003-08-21
Applicant: BASF AG
Inventor: FRANK JUERGEN , RENZ GUENTER , SCHUPP EBERHARD , STEINMETZ BERNHARD , MOLTER STEFAN , BAYER KARL
Abstract: Process for the preparation of homopolymers or copolymers by homopolymerization or copolymerization of free-radically polymerizable water-soluble and/or water-dispersible monomers, optionally with further comonomers and optionally with at least one crosslinker, in an inverse emulsion polymerization in the presence of at least one redox initiator pair comprising an oxidizing agent and a reducing agent, where the reducing agent is 2-hydroxy-2-sulfinatoacetic acid and/or salt thereof; homopolymers or copolymers preparable by the process according to the invention, water-in-oil emulsions which comprise at least one homopolymer or copolymer according to the invention, solid compositions which comprise at least one homopolymer or copolymer according to the invention, the use of 2-hydroxy-2-sulfinatoacetic acid and/or salt thereof as reducing agent in a process for the preparation of homopolymers or copolymers; the use of the water-in-oil emulsion comprising at least one homopolymer or copolymer according to the invention for the thickening of aqueous solutions, and the use of 2-hydroxy-2-sulfinatoacetic acid and/or salt thereof as reducing component of a redox initiator pair comprising an oxidizing agent and a reducing agent for avoiding induction times during inverse emulsion polymerization.
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公开(公告)号:DE19950229A1
公开(公告)日:2001-04-26
申请号:DE19950229
申请日:1999-10-19
Applicant: BASF AG
Inventor: SCHNELL KLAUS , KERBER MICHAEL , SCHUPP EBERHARD , WISTUBA ECKEHARDT
IPC: C08F218/08 , C08F226/10 , C08J3/03
Abstract: A copolymerisate comprises (wt.% of total) N-vinylpyrrolidone (30-79.5), vinyl acetate (20-69.5), a 4-20C monovinyl ester of a monocarboxylic acid (0.5-25), and another copolymerisable ethylenically unsaturated compound (0-40), is new. Independent claims are included for: (1) An aqueous solution or dispersion of copolymerisate as above; (2) an aqueous polymer dispersion containing the above copolymerisate as thickener.
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公开(公告)号:HU9600334A2
公开(公告)日:1996-12-30
申请号:HU9600334
申请日:1996-02-14
Applicant: BASF AG
Inventor: GYOPAR RAU MARIA , SCHLARB BERNHARD , SCHULZ GUENTHER , SCHUPP EBERHARD , WIESE HARM
IPC: C08F2/22 , C08F2/30 , C08F220/06 , C08F220/12 , C08F222/02 , C09D109/00 , C09D123/00 , C09D125/02 , C09D127/00 , C09D131/02 , C09D133/06 , C09D133/18 , C09D157/00 , C09J157/00 , D06M15/00
Abstract: Aq. polymer dispersions, obtd. by radical polymerisation of monomers in aq. emulsion in presence of a polymeric protective colloid (A) with an average mol. wt. (Mw) of >20,000. Colloid (A) is a copolymer of 5-50 wt. % unsatd. monomer(s) with acid or acid anhydride gp(s). (monomers I), 0.1-80 wt.% (meth)acrylate ester(s) of at least 10C aliphatic alcohols (monomers II), 0-94.9 wt.% "principal monomers", comprising 1-9C alkyl (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, unsatd. nitriles, vinyl halides and/or 2-8C aliphatic hydrocarbons with 1 or 2 double bonds (monomers III) and 0-60 wt.% other monomers (IV). Also claimed is the above process for the prodn. of aq. polymer dispersions.
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公开(公告)号:CA2169129A1
公开(公告)日:1996-08-16
申请号:CA2169129
申请日:1996-02-08
Applicant: SCHLARB BERNHARD , SCHUPP EBERHARD , RAU MARIA GYOPAR , SCHULZ GUENTHER , WIESE HARM , BASF AG
Inventor: SCHLARB BERNHARD , SCHUPP EBERHARD , RAU MARIA GYOPAR , SCHULZ GUENTHER , WIESE HARM
IPC: C08F2/22 , C08F2/30 , C08F220/06 , C08F220/12 , C08F222/02 , C09D109/00 , C09D123/00 , C09D125/02 , C09D127/00 , C09D131/02 , C09D133/06 , C09D133/18 , C09D157/00 , C09J157/00 , D06M15/00 , C09J9/00 , C09D5/02
Abstract: An aqueous polymer emulsion obtainable by free radical polymerization of monomers in aqueous emulsion in the presence of a polymeric protective colloid contains, as components, - from 5 to 50% by weight of at least one ethylenically unsaturated monomer having at least one acid or acid anhydride group (monomers I), - from 0.1 to 80% by weight of at least one (meth)acrylate of an aliphatic alcohol of at least 10 carbon atoms (monomers II), - from 0 to 94.9% by weight of main monomers selected from the group consisting of C1-C8-alkyl (meth)acrylates, vinyl esters of carboxylic acids of up to 20 carbon atoms, vinyl aromatics of up to 20 carbon atoms, ethylenically unsaturated nitrites, vinyl halides and aliphatic hydrocarbons having 2 to 8 carbon atoms and 1 or 2 double bonds (monomers III) and - from 0 to 60% by weight of further monomers (monomers IV), the stated weights being based on the polymeric protective colloid.
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公开(公告)号:AT81348T
公开(公告)日:1992-10-15
申请号:AT86109185
申请日:1986-07-04
Applicant: BASF AG
Inventor: GOECKEL ULRICH , PETERSEN HARRO , OSTERLOH ROLF , SCHUPP EBERHARD , LOCH WERNER , SCHWERZEL THOMAS
IPC: C07D239/10 , C08G12/02 , C08G12/10 , C08G12/40 , C08G14/06 , C08G18/38 , C08G18/54 , C09D5/44 , C09D161/34
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公开(公告)号:CA1263980A
公开(公告)日:1989-12-19
申请号:CA484057
申请日:1985-06-14
Applicant: BASF AG
Inventor: KEMPTER FRITZ E , NIEBERLE JUERGEN , SCHUPP EBERHARD
Abstract: A heat-curable aqueous coating agentcontains, as a binder, a mixture or precondensate of (A) a resin possessing basic nitrogen groups and (3) a phenol resin based on a resol ether which is bonded via o,o'-methylene ether groups and whose p-posi-tions predominantly carry hydrogen and/or methylolalkyl ether groups. After protonation with an acid, the said coating agent is particularly useful as a binder for the cathodic electrocoating of metal articles.
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公开(公告)号:BR8502880A
公开(公告)日:1986-02-25
申请号:BR8502880
申请日:1985-06-17
Applicant: BASF AG
Inventor: KEMPTER FRITZ ERDMANN , PETERSEN HARRO , SCHUPP EBERHARD , SABELUS GUENTHER , SCHMIDT HORST
IPC: C08G59/00 , C08G59/10 , C08G59/28 , C08G59/32 , C08L63/00 , C09D5/44 , C09D163/00 , C09D3/49 , C09D5/46
Abstract: The heat-curable coating agent according to the invention contains a combination of a binder, which possesses basic nitrogen groups and is rendered water-dilutable by protonation with an acid, and a crosslinking agent and, if required, pigments, fillers, corrosion inhibitors, surface coating assistants and catalysts, and the binder used is a reaction product of a dicarboxylic acid or of a dicarboxylate or of a (meth)acrylate oligomer or polymer with an adduct of a di- or triglycidyl ether and a polyamine, the polyamine containing 2 or more amine nitrogen atoms per molecule and one or more alkylene chains of 3 or more carbon atoms between the amino groups, and has an NH amine number of from 50 to 150 mg of KOH/g and is combined with aminoplasts and/or phenoplasts as crosslinking agents. The novel coating agent is useful as a binder for the cathodic electrocoating of metal articles.
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公开(公告)号:CA1173994A
公开(公告)日:1984-09-04
申请号:CA381763
申请日:1981-07-15
Applicant: BASF AG
Inventor: KEMPTER FRITZ E , SCHUPP EBERHARD
IPC: C08C19/36 , C08G14/00 , C08G14/06 , C08G14/14 , C08G59/00 , C08G59/14 , C08G59/40 , C08G59/62 , C09D5/44 , C09D163/00 , C08G8/28 , C25D13/06 , C08G59/08
Abstract: A polyadduct/polycondensate, which is water-dilutable when protonated with an acid, and which contains basic nitrogen groups, is obtained by polyaddition reaction of (A) Mannich bases obtained from monophenols and/or polyphenols, one or more secondary amines which contain one or more hydroxyalkyl groups,or a mixture of such a secondary amine with another secondary amine, and formaldehyde or a formaldehyde donor, with (B) an epoxy resin, the polyadduct/polycondensate of (A) and (B) containing groups, bonded to aromatic rings, of the formula (I) (I) with or without groups of the general formula II (II) where R1 is a polydienyl radical, R2 and R3 are hydrogen or methyl and R4 and R5 are alkyl, hydroxyalkyl or alkoxyalkyl or are linked to one another to form a 5-membered or 6-membered ring. The polyadduct/polycondensate can be used, for example, as a surface-coating binder for the cathodic electrocoating of metal articles.
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公开(公告)号:BR8306626A
公开(公告)日:1984-07-10
申请号:BR8306626
申请日:1983-12-02
Applicant: BASF AG
Inventor: SCHUPP EBERHARD , LOCH WERNER , OSTERLOH ROLF
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