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    SUPPORTED CATALYST SYSTEM
    24.
    发明专利
    SUPPORTED CATALYST SYSTEM 未知

    公开(公告)号：CA2246360A1

    公开(公告)日：1997-08-28

    申请号：CA2246360

    申请日：1997-02-19

    Applicant: BASF AG

    Inventor： G RTZ HANS-HELMUT ,  SCHWEIER GUENTHER ,  FISCHER DAVID ,  LYNCH JOHN

    IPC: C08F4/12 ,  C08F4/44 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02 ,  C08F4/62 ,  C08F4/02

    Abstract: Supported catalyst obtainable by A) reacting an inorganic carrier material with a metal compound of the general formula (I): M1(R1)r(R2)s(R3)t(R4)u in which M1 is an alkalyne or alkalyne earth metal or a metal of main group III or IV of the periodic system; R1 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R2 to R4 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; r is a whole number from 1 to 4; and s, t and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M1; B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide form and a metallocenium ion-forming compound; and C) subsequent reaction with a metal compound of the general formula (II): M2(R5)o(R6)p(R7)q in which M2 is an alkalyne or alkalyne earth metal or a metal of main group III of the periodic system; R5 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R6 to R7 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; o is a whole number from 1 to 3; and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M2.

    25.
    发明专利
    未知

    公开(公告)号：DE59301806D1

    公开(公告)日：1996-04-11

    申请号：DE59301806

    申请日：1993-03-23

    Applicant: BASF AG

    Inventor： EVERTZ KASPAR ,  SCHLUND RUEGER ,  SCHWEIER GUENTHER ,  BRINTZINGER HANS ,  ROELL WERNER ,  JUTZI PETER ,  MIELING INGRID ,  MENGELE WINFRIED

    IPC: C07F17/00 ,  C08F4/42 ,  C08F4/60 ,  C08F4/602 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/642 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00

    Abstract: PCT No. PCT/EP93/00694 Sec. 371 Date Jun. 13, 1994 Sec. 102(e) Date Jun. 13, 1994 PCT Filed Mar. 23, 1993 PCT Pub. No. WO93/20113 PCT Pub. Date Oct. 14, 1993.Catalyst systems for the polymerization of C2-C10-alk-1-enes contain, as active components, a) a metallocene complex of the general formula I III, IV or v of the Periodic Table of elements or a metal selected from the group consisting of the lanthanides, X is fluorine, chlorine, bromine, iodine, hydrogen, C1-C10-alkyl, C6-C15-aryl or -OR7, R7 is C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl, in each case having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, n is the valency of M minus two, R1 to R6 are each hydrogen, C1-C10-alkyl, 5-membered to 7-membered cycloalkyl which in turn may carry C1-C10-alkyl as a substituent, C6-C15-aryl or arylalkyl, where two adjacent radicals together may furthermore form a cyclic group of 4 to 15 carbon atoms, or Si(R8)3, R8 is C1-C10-alkyl, C6-C15-aryl or C3-C10-cycloalkyl, E1 and E2 are independent of one another and are each Si(R9)2, Ge(R9)2, Sn(R9)2 or C(R9)2-C(R9)2 and R9 is C1-C10-alkyl, C3-C10-cycloalkyl or C6-C15-aryl, and b) an open-chain or cyclic alumoxane compound of the general formula II or III II n integer of from 5 to 30.

    PREPARATION OF PROPYLENE/ETHYLENE POLYMERS OF THE TOUGHENED POLYPROPYLENE TYPE
    29.
    发明专利
    PREPARATION OF PROPYLENE/ETHYLENE POLYMERS OF THE TOUGHENED POLYPROPYLENE TYPE 未知

    公开(公告)号：CA1333828C

    公开(公告)日：1995-01-03

    申请号：CA607986

    申请日：1989-08-10

    Applicant: BASF AG

    Inventor： KERTH JUERGEN ,  WERNER RAINER A ,  ZOLK RALF ,  RUEMPLER KLAUS-DIETER ,  SCHWEIER GUENTHER ,  MUELLER-MALL RUDOLF ,  GRUBER WOLFGANG

    IPC: C08F2/34 ,  C08F4/02 ,  C08F4/58 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F297/08

    Abstract: Propylene/ethylene block copolymers are prepared by a continuous process in which, in each case in an agitated fixed bed of finely divided polymer from the gas phase, first (I) in a first polymerization zone, propylene is homopolymerized by feeding in a Ziegler-Natta catalyst system consisting of (1) a titanium component which contains titanium, magnesium, chlorine and a phthalic acid derivative, (2) an aluminumalkyl component and (3) a silane component, and (II) in a second polymerization zone, a mixture of propylene and ethylene is polymerized with the propylene homopolymer present in the reaction mixture obtained in the first polymerization zone by feeding in the said reaction mixture. In the process, (A) a titanium component (1) is used which is obtained by a method in which (1.1) first, (1.1.1) in a liquid hydrocarbon, (1.1.2) a finely divided magnesium halide, (1.1.3) an alkanol, (1.1.4) a certain phthalic acid derivative and (1.1.5) titanium tetrachloride are reacted with one another under certain conditions, (1.2) the solid intermediate obtained from (1.1) is extracted with titanium tetrachloride or a liquid alkylbenzene until the remaining solid substance has become substantially richer in magnesium, and (1.3) finally, the solid substance remaining in (1.2) is washed with an alkane in a certain manner, (B) a specific silane is used as (3), and (C) specifically selected polymerization parameters are employed, with relationships between the first and second polymerization zones.

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