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    1.
    发明专利
    未知

    公开(公告)号：ES2084490T3

    公开(公告)日：1996-05-01

    申请号：ES93906586

    申请日：1993-03-23

    Applicant: BASF AG

    Inventor： EVERTZ KASPAR ,  SCHLUND RUEGER ,  SCHWEIER GUENTHER ,  BRINTZINGER HANS ,  ROELL WERNER ,  JUTZI PETER

    IPC: C07F17/00 ,  C08F4/42 ,  C08F4/60 ,  C08F4/602 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/642 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00

    Abstract: PCT No. PCT/EP93/00694 Sec. 371 Date Jun. 13, 1994 Sec. 102(e) Date Jun. 13, 1994 PCT Filed Mar. 23, 1993 PCT Pub. No. WO93/20113 PCT Pub. Date Oct. 14, 1993.Catalyst systems for the polymerization of C2-C10-alk-1-enes contain, as active components, a) a metallocene complex of the general formula I III, IV or v of the Periodic Table of elements or a metal selected from the group consisting of the lanthanides, X is fluorine, chlorine, bromine, iodine, hydrogen, C1-C10-alkyl, C6-C15-aryl or -OR7, R7 is C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl, in each case having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, n is the valency of M minus two, R1 to R6 are each hydrogen, C1-C10-alkyl, 5-membered to 7-membered cycloalkyl which in turn may carry C1-C10-alkyl as a substituent, C6-C15-aryl or arylalkyl, where two adjacent radicals together may furthermore form a cyclic group of 4 to 15 carbon atoms, or Si(R8)3, R8 is C1-C10-alkyl, C6-C15-aryl or C3-C10-cycloalkyl, E1 and E2 are independent of one another and are each Si(R9)2, Ge(R9)2, Sn(R9)2 or C(R9)2-C(R9)2 and R9 is C1-C10-alkyl, C3-C10-cycloalkyl or C6-C15-aryl, and b) an open-chain or cyclic alumoxane compound of the general formula II or III II n integer of from 5 to 30.

    2.
    发明专利
    未知

    公开(公告)号：DE10035308A1

    公开(公告)日：2002-01-31

    申请号：DE10035308

    申请日：2000-07-18

    Applicant: BASF AG

    Inventor： KRISTEN MARC OLIVER ,  LILGE DIETER ,  JUTZI PETER ,  MUELLER CHRISTIAN

    IPC: C08F4/602 ,  C08F4/642 ,  C08F4/659 ,  C08F4/70 ,  C08F4/76 ,  C08F4/80 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

    Abstract: The invention relates to a method for the production of polyolefins at pressures of from 1 to 4,000 bar and temperatures of from 20 to 350 DEG C in the presence of a catalyst system, comprising an organometallic compound from the group of the metallocenes or the catalytically active iron, cobalt, nickel, or palladium complexes. The organometallic compound comprises a Lewis base functionality which is arranged such that said functionality can co-ordinate intramolecularly to the central metal atom of the organometallic compound. The reaction temperature is adjusted such that the resulting polyolefin has a bimodal molecular weight distribution MW/MN of

    7.
    发明专利
    未知

    公开(公告)号：DE59700326D1

    公开(公告)日：1999-09-16

    申请号：DE59700326

    申请日：1997-04-28

    Applicant: BASF AG

    Inventor： KRISTEN MARC OLIVER ,  JUTZI PETER ,  REDEKER THOMAS

    IPC: C07F17/00 ,  C08F2/06 ,  C08F4/62 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/68 ,  C08F6/00 ,  C08F6/02 ,  C08F6/08 ,  C08F10/00

    Abstract: A process for the recovery of metallocene complexes of formula (I) used as active catalyst components in the production of polymers of 2-10C alkenes. M = Ti, Zr, Hf, V, Nb or Ta; R -R = H, 1-10C alkyl, 5- to 7-membered cycloalkyl (optionally substituted with 1-10C alkyl), or 6-15C aryl or aralkyl, 4-15C cyclic group (formed by two adjacent groups), Si(R )3, -(CR R )n-YHR R or -(CR R )n-ZHR ; R , R , R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; R , R = H, 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; Y = N, P, As, Sb or Bi; Z = O, S, Se or Te; n = 0-10; R = -(CR R )n1-YHR R or -(CR R )n1-ZHR ; R , R = as for R and R ; R , R = as for R and R ; n1 = 0-10; X -X = F, Cl, Br, I, H, 1-10C alkyl, 6-15C aryl, (1-10C alkyl)-(6-20C aryl), -OR , -NR R or a cyclopentadienyl group substituted with 5 groups R -R ( = Cp); R , R = 1-10C alkyl, 6-15C aryl, alkaryl, aralkyl, fluoroalkyl or fluoroaryl with 1-10C alkyl and 6-20 C aryl groups; R -R = as for R -R , but with R -R = as for R -R respectively and n2 = 0-10 instead of n= 0-10; o, p, q, r = 0-4; o + p + q + r + 1 = the valency of M. The process comprises stopping the polymerisation by addition of acid and recovering (I) from the reaction mixture by extraction. Also claimed is a process for the production of polymers of 2-10C alkenes, especially ethylene, in presence of catalyst systems containing (A) a recovered metallocene complex (I) and (B) a metallocenium ion-forming compound.

    10.
    发明专利
    未知

    公开(公告)号：DE19602543A1

    公开(公告)日：1997-07-31

    申请号：DE19602543

    申请日：1996-01-25

    Applicant: BASF AG

    Inventor： KRISTEN MARC OLIVER DR ,  JUTZI PETER ,  REDEKER THOMAS

    IPC: C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08L23/24

    Abstract: The invention concerns a process for preparing polymers of C2-C10 alkenes in the presence of catalyst systems, those which contain: (A) a metallocene complex of general formula (I), at least one of the R groups corresponding to formula (a), in which R is C1-C10 alkyl, C6-C15 aryl or C3-C10 cycloalkyl, R and R are hydrogen, C1-C10 alkyl, C6-C15 aryl or C3-C10 cycloalkyl, R and R are C1-C10 alkyl, C6-C15 aryl or C3-C10 cycloalkyl, and n is an integer ranging from 0 to 10; and (B) a metallocenium ion-forming compound, as active components being used as catalyst systems.

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