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公开(公告)号:DE59711565D1
公开(公告)日:2004-06-03
申请号:DE59711565
申请日:1997-09-23
Applicant: BASF AG
Inventor: ROTERMUND DR , HEMPEL RENATE , SEIFERT DR , WIEGMANN WERNER
Abstract: A process for the production of rigid polyurethane foam with improved thermodimensional stability and reduced thermal conductivity comprises reacting (a) polyisocyanates with (b) compounds with isocyanate-reactive hydrogen atoms in presence of (c) water and optionally (d) physical blowing agents and (e) catalysts and other additives etc. 60-100 wt% of component (b) consists of a polyol mixture containing (b1) a polyol obtained by addition of ethylene oxide (EO) and/or propylene oxide (PO) to a hexitol or hexitol mixture and (b2) a polyol obtained by addition of EO and/or PO to one or more aromatic amines, such that the total hexitol content and the total amine content of the polyol mixture is 15-30 wt% and 1-10 wt% respectively.
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公开(公告)号:DK0832909T3
公开(公告)日:2004-06-01
申请号:DK97116522
申请日:1997-09-23
Applicant: BASF AG
Inventor: ROTERMUND UDO DR , SEIFERT HOLGER DR , HEMPEL RENATE , WIEGMANN WERNER
Abstract: A process for the production of rigid polyurethane foam with improved thermodimensional stability and reduced thermal conductivity comprises reacting (a) polyisocyanates with (b) compounds with isocyanate-reactive hydrogen atoms in presence of (c) water and optionally (d) physical blowing agents and (e) catalysts and other additives etc. 60-100 wt% of component (b) consists of a polyol mixture containing (b1) a polyol obtained by addition of ethylene oxide (EO) and/or propylene oxide (PO) to a hexitol or hexitol mixture and (b2) a polyol obtained by addition of EO and/or PO to one or more aromatic amines, such that the total hexitol content and the total amine content of the polyol mixture is 15-30 wt% and 1-10 wt% respectively.
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公开(公告)号:DE19900249A1
公开(公告)日:2000-07-13
申请号:DE19900249
申请日:1999-01-07
Applicant: BASF AG
Inventor: HEINZ MARION , BIEDERMANN ANJA , ROTERMUND UDO , REICHELT MICHAEL , WIEGMANN WERNER
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公开(公告)号:HU9800529D0
公开(公告)日:1998-05-28
申请号:HU9800529
申请日:1998-03-10
Applicant: BASF AG
Inventor: BAUM EVA , KNORR GOTTFRIED , ROTERMUND UDO , SEIFERT HOLGER , WIEGMANN WERNER
Abstract: The production of rigid polyurethane (PUR) foam with a low bulk density (I) comprises reacting (a) polyisocyanates and/or modified polyisocyanates with (b) high-mol. wt. compound(s) with at least two reactive hydrogens and optionally (c) low-mol. wt. chain-extenders and/or crosslinkers in presence of (d) blowing agents, (e) catalysts and optionally (f) other additives etc. Component (d) consists of a mixture of (d-1) cyclopentane, (d-2) at least one 3-4C alkane and/or alkene which forms a homogeneous mixture with cyclopentane and (d-3) the carbon dioxide from the reaction of water and isocyanate. Component (b) comprises aromatic nitrogen-containing polyethers.
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公开(公告)号:DE19639121A1
公开(公告)日:1998-03-26
申请号:DE19639121
申请日:1996-09-24
Applicant: BASF AG
Inventor: ROTERMUND UDO DR , HEMPEL RENATE , SEIFERT HOLGER DR , WIEGMANN WERNER
Abstract: A process for the production of rigid polyurethane foam with improved thermodimensional stability and reduced thermal conductivity comprises reacting (a) polyisocyanates with (b) compounds with isocyanate-reactive hydrogen atoms in presence of (c) water and optionally (d) physical blowing agents and (e) catalysts and other additives etc. 60-100 wt% of component (b) consists of a polyol mixture containing (b1) a polyol obtained by addition of ethylene oxide (EO) and/or propylene oxide (PO) to a hexitol or hexitol mixture and (b2) a polyol obtained by addition of EO and/or PO to one or more aromatic amines, such that the total hexitol content and the total amine content of the polyol mixture is 15-30 wt% and 1-10 wt% respectively.
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公开(公告)号:ES2238742T3
公开(公告)日:2005-09-01
申请号:ES98117895
申请日:1998-09-22
Applicant: BASF AG
Inventor: ROTERMUND UDO DR , BIEDERMANN ANJA , HEMPEL RENATE , WIEGMANN WERNER , HEINZ MARION
IPC: C08J3/02 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/66 , C08G101/00 , C08J9/12 , C08J9/14 , C08L75/04
Abstract: EL OBJETO DE LA INVENCION SON EMULSIONES SIN HALOGENOS QUE CONTIENEN AGENTES POROGENOS QUE SON ESTABLES EN ALMACENAMIENTO PARA LA FABRICACION DE ESPUMAS DURAS A BASE DE ISOCIANATO QUE CONTIENEN A) COMPUESTOS QUE CONTIENEN ATOMOS DE HIDROGENO QUE SON REACTIVOS CON LOS GRUPOS ISOCIANATO, B) AGUA, C) AGENTES POROGENOS SIN HALOGENOS QUE ACTUAN FISICAMENTE, ASI COMO OPCIONALMENTE D) ADYUVANTES Y/O ADITIVOS USUALES EN LA QUIMICA DEL POLIURETANO, CARACTERIZADO PORQUE COMO COMPONENTE A) SE UTILIZAN POLIETERALCOHOLES CON UNA FUNCIONALIDAD MAYOR DE 1,5, UN INDICE DE HIDROXILO DE 10 A 100 MG DE KOH/G EN UNA CANTIDAD DE 0,2 % HASTA 80 % EN MASA, CON RELACION A LA MASA DEL COMPONENTE A), Y COMO ESPUMANTES QUE ACTUAN DE MANERA FISICA Y SIN HALOGENOS SE PUEDEN UTILIZAR C) HIDROCARBUROS CON 3 A 10 ATOMOS DE CARBONO.
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公开(公告)号:DE59812630D1
公开(公告)日:2005-04-14
申请号:DE59812630
申请日:1998-09-22
Applicant: BASF AG
Inventor: ROTERMUND DR , BIEDERMANN ANJA , HEMPEL RENATE , WIEGMANN WERNER , HEINZ MARION
IPC: C08J3/02 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/66 , C08G101/00 , C08J9/12 , C08J9/14 , C08L75/04
Abstract: Emulsions containing polyether alcohols are used in the production of hard foams based on isocyanates to improve the temperature stability of the foams. Storage-stable halogen-free emulsions used in the production of hard foams based on isocyanates contain: (a) compounds containing hydrogen atoms reactive towards isocyanate groups; (b) water; (c) halogen-free propellants; and optionally (d) usual auxiliary aids and/or additives. (a) is used in an amount of 0.2-80 wt.% and has a functionality of more than 1.5, and an OH number of 10-100 mg KOH/g. (c) consists of 3-10 C hydrocarbons. Independent claims are also included for: (1) the production of the hard foams described; (2) the foams, and (3) the use of the polyether alcohols described.
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公开(公告)号:ES2227734T3
公开(公告)日:2005-04-01
申请号:ES98103629
申请日:1998-03-02
Applicant: BASF AG
Inventor: KNORR GOTTFRIED DR , ROTERMUND UDO DR , BAUM EVA , SEIFERT HOLGER DR , WIEGMANN WERNER
Abstract: ES OBJETO DE LA PRESENTE INVENCION UN PROCEDIMIENTO PARA LA PRODUCCION DE ESPUMAS RIGIDAS DE POLIURETANO CON MENOR DENSIDAD APARENTE MEDIANTE LA REACCION DE A) POLIISOCIANATOS ORGANICOS Y/O MODIFICADOS CON B) AL MENOS UN COMPUESTO DE ELEVADO PESO MOLECULAR CON AL MENOS DOS ATOMOS DE HIDROGENO REACTIVOS Y OPCIONALMENTE, C) ALARGADORES DE CADENA DE BAJO PESO MOLECULAR Y/O RETICULANTES EN PRESENCIA DE D) POROGENOS, E) CATALIZADORES, ASI COMO OPCIONALMENTE F)) OTROS COADYUVANTES Y/O ADITIVOS, QUE SE CARACTERIZA PORQUE COMO POROGENO SE UTILIZA D) UNA MEZCLA DE CICLOPENTANO, AL MENOS UN COMPUESTO QUE SE PUEDA MEZCLAR DE FORMA HOMOGENEA CON CICLOPENTANO DEL GRUPO DE LOS ALCANOS Y/O ALQUENOS CON 3 O 4 ATOMOS DE CARBONO EN LA MOLECULA Y EL DIOXIDO DE CARBONO ORIGINADO A PARTIR DEL AGUA Y DEL ISOCIANATO Y COMO COMPUESTO DE ELEVADO PESO MOLECULAR POLIETERES AROMATICOS Y CON NITROGENO CON AL MENOS DOS ATOMOS DE HIDROGENO REACTIVOS (B). ASIMISMO ES OBJETO DE LA INVENCION EL USO DE LAS ESPUMAS RIGIDAS ASI PRODUCIDAS COMO MATERIAL AISLANTE.
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公开(公告)号:DE10211274A1
公开(公告)日:2003-09-25
申请号:DE10211274
申请日:2002-03-13
Applicant: BASF AG
Inventor: WIEGMANN WERNER , KROGMANN JOERG , BIEDERMANN ANJA
IPC: B32B5/18 , B32B27/04 , C08G18/42 , C08G18/48 , C08J9/40 , E04B1/80 , C08J9/42 , C08G18/00 , B32B7/00 , F16L59/06
Abstract: A cured foam material with a compressive stress of greater than 0.1Mpa, an open cell content of at least 90%, containing open cell flexible foam material wetted with a cured impregnating material is new. Independent claims are included for: (1) a method of preparing the cured foam material involving the steps of: application of an impregnating material onto an opencell flexible foam material; optionally expressing of flexible foam material wetted with impregnating agent (IA); and, curing of IA; (2) vacuum insulation paneling containing the foam material; (3) a process for preparation of the vacuum insulation paneling involving the steps of: application of IA to the open cell flexible foam material; expression of the foam material wetted with IA; curing of the foam material wetted with the IA; surrounding of the cured foam material with a diffusion impervious layer; and, removal of the cell gas and sealing of the diffusion impervious layer.
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公开(公告)号:DE10106947A1
公开(公告)日:2002-08-22
申请号:DE10106947
申请日:2001-02-15
Applicant: BASF AG
Inventor: BIEDERMANN ANJA , WECKMANN WOLFGANG , WIEGMANN WERNER
Abstract: Refrigeration or freezer equipment with a housing, inner and outer walls, insulating material and foil, in which the foil consists of multi-layer film comprising a layer of polyamide, a layer of polyethylene terephthalate (PET), aluminum foil and a layer of high-density polyethylene (HDPE).
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