21.
    发明专利
    未知

    公开(公告)号:DE59711565D1

    公开(公告)日:2004-06-03

    申请号:DE59711565

    申请日:1997-09-23

    Applicant: BASF AG

    Abstract: A process for the production of rigid polyurethane foam with improved thermodimensional stability and reduced thermal conductivity comprises reacting (a) polyisocyanates with (b) compounds with isocyanate-reactive hydrogen atoms in presence of (c) water and optionally (d) physical blowing agents and (e) catalysts and other additives etc. 60-100 wt% of component (b) consists of a polyol mixture containing (b1) a polyol obtained by addition of ethylene oxide (EO) and/or propylene oxide (PO) to a hexitol or hexitol mixture and (b2) a polyol obtained by addition of EO and/or PO to one or more aromatic amines, such that the total hexitol content and the total amine content of the polyol mixture is 15-30 wt% and 1-10 wt% respectively.

    22.
    发明专利
    未知

    公开(公告)号:DK0832909T3

    公开(公告)日:2004-06-01

    申请号:DK97116522

    申请日:1997-09-23

    Applicant: BASF AG

    Abstract: A process for the production of rigid polyurethane foam with improved thermodimensional stability and reduced thermal conductivity comprises reacting (a) polyisocyanates with (b) compounds with isocyanate-reactive hydrogen atoms in presence of (c) water and optionally (d) physical blowing agents and (e) catalysts and other additives etc. 60-100 wt% of component (b) consists of a polyol mixture containing (b1) a polyol obtained by addition of ethylene oxide (EO) and/or propylene oxide (PO) to a hexitol or hexitol mixture and (b2) a polyol obtained by addition of EO and/or PO to one or more aromatic amines, such that the total hexitol content and the total amine content of the polyol mixture is 15-30 wt% and 1-10 wt% respectively.

    PROCESS FOR PRODUCING LOW DENSITY RIGID POLYURETHANE FOAMS

    公开(公告)号:HU9800529D0

    公开(公告)日:1998-05-28

    申请号:HU9800529

    申请日:1998-03-10

    Applicant: BASF AG

    Abstract: The production of rigid polyurethane (PUR) foam with a low bulk density (I) comprises reacting (a) polyisocyanates and/or modified polyisocyanates with (b) high-mol. wt. compound(s) with at least two reactive hydrogens and optionally (c) low-mol. wt. chain-extenders and/or crosslinkers in presence of (d) blowing agents, (e) catalysts and optionally (f) other additives etc. Component (d) consists of a mixture of (d-1) cyclopentane, (d-2) at least one 3-4C alkane and/or alkene which forms a homogeneous mixture with cyclopentane and (d-3) the carbon dioxide from the reaction of water and isocyanate. Component (b) comprises aromatic nitrogen-containing polyethers.

    25.
    发明专利
    未知

    公开(公告)号:DE19639121A1

    公开(公告)日:1998-03-26

    申请号:DE19639121

    申请日:1996-09-24

    Applicant: BASF AG

    Abstract: A process for the production of rigid polyurethane foam with improved thermodimensional stability and reduced thermal conductivity comprises reacting (a) polyisocyanates with (b) compounds with isocyanate-reactive hydrogen atoms in presence of (c) water and optionally (d) physical blowing agents and (e) catalysts and other additives etc. 60-100 wt% of component (b) consists of a polyol mixture containing (b1) a polyol obtained by addition of ethylene oxide (EO) and/or propylene oxide (PO) to a hexitol or hexitol mixture and (b2) a polyol obtained by addition of EO and/or PO to one or more aromatic amines, such that the total hexitol content and the total amine content of the polyol mixture is 15-30 wt% and 1-10 wt% respectively.

    27.
    发明专利
    未知

    公开(公告)号:DE59812630D1

    公开(公告)日:2005-04-14

    申请号:DE59812630

    申请日:1998-09-22

    Applicant: BASF AG

    Abstract: Emulsions containing polyether alcohols are used in the production of hard foams based on isocyanates to improve the temperature stability of the foams. Storage-stable halogen-free emulsions used in the production of hard foams based on isocyanates contain: (a) compounds containing hydrogen atoms reactive towards isocyanate groups; (b) water; (c) halogen-free propellants; and optionally (d) usual auxiliary aids and/or additives. (a) is used in an amount of 0.2-80 wt.% and has a functionality of more than 1.5, and an OH number of 10-100 mg KOH/g. (c) consists of 3-10 C hydrocarbons. Independent claims are also included for: (1) the production of the hard foams described; (2) the foams, and (3) the use of the polyether alcohols described.

    PROCEDIMIENTO PARA LA OBTENCION DE PLASTICOS CELULARES RIGIDOS DE POLIURETANO CON UNA DENSIDAD BRUTA REDUCIDA.

    公开(公告)号:ES2227734T3

    公开(公告)日:2005-04-01

    申请号:ES98103629

    申请日:1998-03-02

    Applicant: BASF AG

    Abstract: ES OBJETO DE LA PRESENTE INVENCION UN PROCEDIMIENTO PARA LA PRODUCCION DE ESPUMAS RIGIDAS DE POLIURETANO CON MENOR DENSIDAD APARENTE MEDIANTE LA REACCION DE A) POLIISOCIANATOS ORGANICOS Y/O MODIFICADOS CON B) AL MENOS UN COMPUESTO DE ELEVADO PESO MOLECULAR CON AL MENOS DOS ATOMOS DE HIDROGENO REACTIVOS Y OPCIONALMENTE, C) ALARGADORES DE CADENA DE BAJO PESO MOLECULAR Y/O RETICULANTES EN PRESENCIA DE D) POROGENOS, E) CATALIZADORES, ASI COMO OPCIONALMENTE F)) OTROS COADYUVANTES Y/O ADITIVOS, QUE SE CARACTERIZA PORQUE COMO POROGENO SE UTILIZA D) UNA MEZCLA DE CICLOPENTANO, AL MENOS UN COMPUESTO QUE SE PUEDA MEZCLAR DE FORMA HOMOGENEA CON CICLOPENTANO DEL GRUPO DE LOS ALCANOS Y/O ALQUENOS CON 3 O 4 ATOMOS DE CARBONO EN LA MOLECULA Y EL DIOXIDO DE CARBONO ORIGINADO A PARTIR DEL AGUA Y DEL ISOCIANATO Y COMO COMPUESTO DE ELEVADO PESO MOLECULAR POLIETERES AROMATICOS Y CON NITROGENO CON AL MENOS DOS ATOMOS DE HIDROGENO REACTIVOS (B). ASIMISMO ES OBJETO DE LA INVENCION EL USO DE LAS ESPUMAS RIGIDAS ASI PRODUCIDAS COMO MATERIAL AISLANTE.

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