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公开(公告)号:DE4433931A1
公开(公告)日:1995-04-06
申请号:DE4433931
申请日:1994-09-23
Applicant: BASF MAGNETICS GMBH
Inventor: BRODT GREGOR DR , VASS ATTILA DR , LOCH WERNER DR , LEHNER AUGUST , LENZ WERNER DR , SCHNEIDER NORBERT
IPC: C08G18/10 , C08G18/62 , C08G18/78 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , C08G18/83
Abstract: The invention concerns magnetic recording media consisting of a nonmagnetic base material and, firmly adherent thereto, at least one magnetisable layer based on a magnetic material dispersed in a binder mixture which contains at least one hydroxyl-containing, preferably low molecular weight polyurea urethane and a polyurethane urea (meth)acrylate, characterised in that the polyurethane urea (meth)acrylate is obtained by reacting a poly(meth)acrylate having up to 2 OH end groups per mole and a molecular weight between 200 and 50000 with a mixture of aliphatic polyisocyanates having an average functionality of 3.0 to 6.0 NCO groups per mole and consisting of 0.1 to 10% by weight of a diisocyanate, 30 to 80% by weight of a triisocyanate, and 20 to 60% by weight of an isocyanate having a functionality of 4 to 10, with the proviso that 1.2 to 3.0 NCO groups are reacted per OH group and the remaining NCO groups are converted with polyfunctional amines or a mixture of various polyfunctional amines in substituted urea end groups.
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公开(公告)号:DE4227870A1
公开(公告)日:1994-02-24
申请号:DE4227870
申请日:1992-08-22
Applicant: BASF MAGNETICS GMBH
Inventor: LEHNER AUGUST , SCHNEIDER NORBERT , ROLLER HERMANN , BALZ WERNER DR , LENZ WERNER DR , KOHL ALBERT
IPC: C09D183/04 , C09D5/23 , C10M107/04 , C10M107/06 , C10M107/50 , C10N40/18 , G11B5/708 , G11B5/71 , G11B5/702
Abstract: The invention relates to magnetic recording media obtained by preparing a dispersion of an anisotropic magnetic material and conventional additives in a solution of a polymer binder in an organic solvent, coating the dispersion onto a non-magnetisable support material, subsequently aligning the anisotropic magnetic material in a magnetic field and solidifying the applied magnetic coating, where the magnetic coating contains finely divided organic hydrophobic supporting pigments and a high-viscosity polysiloxane.
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公开(公告)号:FR2740776B1
公开(公告)日:1998-08-28
申请号:FR9613318
申请日:1996-10-31
Applicant: BASF MAGNETICS GMBH
Inventor: WUNSCH THOMAS , KRESS RIA , LOCH WERNER , LEHNER AUGUST , KOHL ALBERT , SCHNEIDER NORBERT , BURKHART UWE
IPC: C08K3/08 , C08G18/10 , C08G18/32 , C08G18/38 , C08G18/64 , C08G18/72 , C08K3/22 , C08L75/00 , C08L75/04 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , C09D7/00 , G11B5/62
Abstract: Hydroxyl-containing polyurethanes I are composed essentially of a) a diisocyanate of 6 to 30 carbon atoms (component II), b) a component III comprising alpha ) an aliphatic diol of 2 to 20 carbon atoms or beta ) an aromatic-aliphatic or aromatic-cycloaliphatic diol of 8 to 30 carbon atoms having nonphenolic hydroxyl groups as hydroxyl groups of the diol and c) a polyhydric alcohol having at least 3 hydroxyl groups, 3 to 18 carbon atoms and nonphenolic hydroxyl groups as hydroxyl groups of the alcohol (component IV), the amounts of components II to IV being such that the total number of nonphenolic hydroxyl groups is from 1.1 to 5.0 per isocyanate group of II. The polyurethanes can be used as binders or binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:FR2710773B1
公开(公告)日:1997-10-31
申请号:FR9411515
申请日:1994-09-27
Applicant: BASF MAGNETICS GMBH
Inventor: DR BRODT GREGOR , DR VASS ATTILA , DR LOCH WERNER , LEHNER AUGUST , DR LENZ WERNER , SCHNEIDER NORBERT
IPC: C08G18/10 , C08G18/62 , C08G18/78 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702
Abstract: In magnetic recording media consisting of a nonmagnetic substrate and at least one magnetizable layer firmly applied thereon and based on magnetic material dispersed in a binder mixture which contains at least one hydroxyl-containing, preferably low molecular weight polyureaurethane and one polyurethaneurea (meth)acrylate, the polyurethaneurea (meth)acrylate is obtained by reacting a poly(meth)acrylate having up to 2 terminal OH groups per mol and a molecular weight of from 200 to 50,000 with a mixture of aliphatic polyisocyanates having an average functionality of from 3.0 to 6.0 NCO groups per mol, consisting of from 0.1 to 10% by weight of a diisocyanate, from 30 to 80% by weight of a triisocyanate and from 20 to 60% by weight of an isocyanate having a functionality of from 4 to 10, with the proviso that from 1.2 to 3.0 NCO groups react per OH group and the remaining NCO groups are converted into substituted terminal urea groups with a polyfunctional amine or with a mixture of different polyfunctional amines.
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公开(公告)号:FR2740776A1
公开(公告)日:1997-05-09
申请号:FR9613318
申请日:1996-10-31
Applicant: BASF MAGNETICS GMBH
Inventor: WUNSCH THOMAS , KRESS RIA , LOCH WERNER , LEHNER AUGUST , KOHL ALBERT , SCHNEIDER NORBERT , BURKHART UWE
IPC: C08K3/08 , C08G18/10 , C08G18/32 , C08G18/38 , C08G18/64 , C08G18/72 , C08K3/22 , C08L75/00 , C08L75/04 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , C09D7/00 , G11B5/62
Abstract: Hydroxyl-containing polyurethanes I are composed essentially of a) a diisocyanate of 6 to 30 carbon atoms (component II), b) a component III comprising alpha ) an aliphatic diol of 2 to 20 carbon atoms or beta ) an aromatic-aliphatic or aromatic-cycloaliphatic diol of 8 to 30 carbon atoms having nonphenolic hydroxyl groups as hydroxyl groups of the diol and c) a polyhydric alcohol having at least 3 hydroxyl groups, 3 to 18 carbon atoms and nonphenolic hydroxyl groups as hydroxyl groups of the alcohol (component IV), the amounts of components II to IV being such that the total number of nonphenolic hydroxyl groups is from 1.1 to 5.0 per isocyanate group of II. The polyurethanes can be used as binders or binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:DE19516784A1
公开(公告)日:1996-11-14
申请号:DE19516784
申请日:1995-05-11
Applicant: BASF MAGNETICS GMBH
Inventor: BRODT GREGOR , WEINGART FRANZ , LEHNER AUGUST , KOHL ALBERT , KRESS RIA , SCHELBLE JOSEF , SCHNEIDER NORBERT
IPC: C08G18/10 , C08G18/62 , C08G18/65 , C08G18/83 , C08L75/00 , C08L101/00 , C08L101/12 , C09D5/23 , G11B5/702 , G11B5/73 , C08L75/04 , C09D17/00
Abstract: Polymeric materials (I), suitable for use as dispersing resins, are obtd. by reacting (1) a polymer (II) of (a) 80-100 mole% (1-25C alkyl)-ester of an alpha , beta -unsatd. carboxylic acid, (b) 0-20 mole% other comonomer(s) and (c) a starter and/or regulator to produce OH end gps. on most of the polymer chains with (2) a polyfunctional isocyanate (III) to give a prod. (IV), using a mole ratio of (NCO gps.):(OH gps. in II) = 1.2-3.9, and (3) reacting (IV) with (a) a cpd. contg. NCO-reactive gps., with a ratio of 2-7 moles reactive gps. per mole free NCO gps. in (IV), and then reacting the prod. obtd. (VI) with a cpd. (VII) which reacts with the free reactive gps. to introduce acid gps., or (b) a NCO-reactive cpd. (VIII) which itself enables the introduction of acid gps. Also claimed is (i) this process as such, (ii) pigment prepns. contg. a pigment (pref. a magnetic pigment) and material (I), and (iii) magnetic recording materials contg. magnetic pigments treated with (I).
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公开(公告)号:DE4425873A1
公开(公告)日:1996-01-25
申请号:DE4425873
申请日:1994-07-21
Applicant: BASF MAGNETICS GMBH
Inventor: AUWETER HELMUT DR , LOESER WERNER DR , PFANNEBECKER EMIL , SCHNEIDER NORBERT , JAKUSCH HELMUT DR , WIETHOELTER DIETER DIPL ING
Abstract: The process concerns the prodn. of a magnetic recording medium, which has a non-magnetic substrate and coating(s) of magnetic dispersion comprising a mixt. of finely-divided magnetisable pigments which differ in morphology and/or particle size, finely dispersed in a polymeric binder matrix and opt. other additives. The novelty is that the mixed and/or co-compacted pigments are added to the dispersion and the pigment mixt. contains (a) 60-95 wt.% acicular pigment(s) (I) with a BET value of 15-45 m /g and (b) 5-40 wt.% acicular pigment(s) (II) with a BET value at least 5 m /g higher than that of (I).
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公开(公告)号:GB2285807A
公开(公告)日:1995-07-26
申请号:GB9500512
申请日:1995-01-11
Applicant: BASF MAGNETICS GMBH
Inventor: WUENSCH THOMAS , BRODT GREGOR , KRESS RIA , SCHNEIDER NORBERT , KOHL ALBERT , LEHNER AUGUST , BALZ WERNER
IPC: C08G18/12 , C08G18/61 , C08G18/65 , C08G18/66 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702
Abstract: Polymeric materials (I) having an average molecular weight from 4000 to 30,000 are obtainable by reacting 1) A polyurethane (II) comprising a) 1 mol of a diol (III) having an average molecule weight of from 400 to 4000, b) from 0.3 to 9 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms, c) from 0.3 to 9 mol of an aromatic diol (V) of 8 to 30 carbon atoms, d) from 0.01 to 1 mol of a trihydric alcohol (VI) of 3 to 18 carbon atoms, e) from 0.001 to 1 mol of a polyhydric alcohol (VII) of 3 to 14 carbon atoms which contains a tertiary amino group and f) an amount of a diisocyanate (VIII) of 6 to 30 carbon atoms such that the molar ratio of the isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1 with 2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II). The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:DE4233388A1
公开(公告)日:1994-04-07
申请号:DE4233388
申请日:1992-10-05
Applicant: BASF MAGNETICS GMBH
Inventor: LEHNER AUGUST , SCHNEIDER NORBERT , BALZ WERNER DR , LENZ WERNER DR , BOBRICH MICHAEL DR , KOHL ALBERT
IPC: C09D5/23 , C09D133/04 , C09D133/16 , G11B5/702 , G11B5/708 , G11B5/62
Abstract: Magnetic recording substrate comprises a non-magnetic substrate material supporting at least one applied magnetic layer contg. at least 30 wt% ferromagnetic chromium dioxide finely divided in a polymer binding agent and other standard. The content of 0.1-8 wt% (w.r.t. CrO2) perfluoropolyacrylate having a softening pt. greater than 110 deg.C in the magnetic layer. ADVANTAGE - The recording substrates show improved stability to chemical degradation and no less in mechanical properties at high or varying temps. whilst showing no deterioration in magnetic properties.
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公开(公告)号:AU4739593A
公开(公告)日:1994-03-24
申请号:AU4739593
申请日:1993-09-17
Applicant: BASF MAGNETICS GMBH
Inventor: WEBER MANFRED , SCHNEIDER NORBERT , SCHAEFFER NORBERT , BETTINGER GUENTER , STRANSKY REINHARD , BALZ WERNER
IPC: G11B23/087 , G11B5/00
Abstract: The invention relates to tape pressure pads for multi-track tape and cassette systems, laminated coverings of knitted/woven or non-woven material being combined with customary resilient pressing materials or used alone. In systems of relatively high storage density, the said pads advantageously reduce the generation of longitudinal tape oscillations and significantly increase the level uniformity over the tape width. The materials consist of conventional synthetic fibres. The invention can be used for any type of tape recording systems for analog and/or digital signals.
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