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公开(公告)号:JPH08333435A
公开(公告)日:1996-12-17
申请号:JP10980596
申请日:1996-04-30
Applicant: BASF MAGNETICS GMBH
Inventor: BRODT GREGOR , SCHELBLE JOSEF , LEHNER AUGUST , WEINGART FRANZ , KOHL ALBERT , KRESS RIA , SCHNEIDER NORBERT
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公开(公告)号:JPH0850717A
公开(公告)日:1996-02-20
申请号:JP356695
申请日:1995-01-12
Applicant: BASF MAGNETICS GMBH
Inventor: WUENSCH THOMAS , BRODT GREGOR , KRESS RIA , SCHNEIDER NORBERT , KOHL ALBERT , LEHNER AUGUST , BALZ WERNER
IPC: C08G18/12 , C08G18/61 , C08G18/65 , C08G18/66 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702
Abstract: PURPOSE: To provide a coupling agent having improved mechanical characteristics, such as, limit strength, hardness, wear resistance and elasticity, and exhibiting a high crosslinking speed, by causing the coupling agent to contain polyurethane made of predetermined components and a material having a specified molecular weight. CONSTITUTION: Polyurethane contains 1mol of diol having an average molecular weight of 400-4000, 0.3-9mol of aliphatic compound having 2-18 carbon atoms, 0.3-9mol of aromatic diol having 8-30 carbon atoms, and 0.01-1mol of trivalent alcohol having 3-8 carbon atoms. The polyurethane further contains 0.01-1mol of multivalent alcohol having 3-14 carbon atoms and tertiary amino group, and diisocyanate having 6-30 carbon atoms with a molar ratio of isocyanate group to all hydroxyl groups being 1.05:1-1.4:1. This polyurethane and a predetermined compound are caused to react under specified conditions to provide a material having an average molecular weight of 4000-30000, thereby forming a magnetic recording medium.
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公开(公告)号:GB2282338B
公开(公告)日:1997-08-20
申请号:GB9419183
申请日:1994-09-22
Applicant: BASF MAGNETICS GMBH , EMTEC MAGNETICS GMBH
Inventor: BRODT GREGOR , VASS ATTILA , LOCH WERNER , LEHNER AUGUST , LENZ WERNER , SCHNEIDER NORBERT
IPC: C08G18/10 , C08G18/62 , C08G18/78 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , C08L75/04
Abstract: In magnetic recording media consisting of a nonmagnetic substrate and at least one magnetizable layer firmly applied thereon and based on magnetic material dispersed in a binder mixture which contains at least one hydroxyl-containing, preferably low molecular weight polyureaurethane and one polyurethaneurea (meth)acrylate, the polyurethaneurea (meth)acrylate is obtained by reacting a poly(meth)acrylate having up to 2 terminal OH groups per mol and a molecular weight of from 200 to 50,000 with a mixture of aliphatic polyisocyanates having an average functionality of from 3.0 to 6.0 NCO groups per mol, consisting of from 0.1 to 10% by weight of a diisocyanate, from 30 to 80% by weight of a triisocyanate and from 20 to 60% by weight of an isocyanate having a functionality of from 4 to 10, with the proviso that from 1.2 to 3.0 NCO groups react per OH group and the remaining NCO groups are converted into substituted terminal urea groups with a polyfunctional amine or with a mixture of different polyfunctional amines.
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公开(公告)号:FR2714910B1
公开(公告)日:1997-01-31
申请号:FR9500187
申请日:1995-01-10
Applicant: BASF MAGNETICS GMBH
Inventor: DR BRODT GREGOR , LEHNER AUGUST , KOHL ALBERT , DR WUNSCH THOMAS
Abstract: A material suitable as crosslinking binder component for pigment-containing coatings and having an average molecular weight of from 25,000 to 150,000, obtainable by reacting a polyurethane comprising a diol having a molecular weight between 400 and 4,000, an aliphatic or cycloaliphatic diol of 2-18 carbon atoms, an aromatic diol of 8-36 carbon atoms, a trihydric or polyhydric alcohol of 3-18 carbon atoms, a polyhydric alcohol of 3-40 carbon atoms containing a tertiary amino group, and a diisocyanate of 3-34 carbon atoms with a compound containing one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups. The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:DE59304266D1
公开(公告)日:1996-11-28
申请号:DE59304266
申请日:1993-08-10
Applicant: BASF MAGNETICS GMBH
Inventor: LEHNER AUGUST , SCHNEIDER NORBERT , ROLLER HERMANN , BALZ WERNER DR , LENZ WERNER DR , KOHL ALBERT
IPC: C09D183/04 , C09D5/23 , C10M107/04 , C10M107/06 , C10M107/50 , C10N40/18 , G11B5/708 , G11B5/71
Abstract: The invention relates to magnetic recording media obtained by preparing a dispersion of an anisotropic magnetic material and conventional additives in a solution of a polymer binder in an organic solvent, coating the dispersion onto a non-magnetisable support material, subsequently aligning the anisotropic magnetic material in a magnetic field and solidifying the applied magnetic coating, where the magnetic coating contains finely divided organic hydrophobic supporting pigments and a high-viscosity polysiloxane.
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公开(公告)号:GB2286192A
公开(公告)日:1995-08-09
申请号:GB9500515
申请日:1995-01-11
Applicant: BASF MAGNETICS GMBH
Inventor: BRODT GREGOR , WUENSCH THOMAS , LEHNER AUGUST , KOHL ALBERT
Abstract: A material (I) suitable as crosslinkable binder component for pigment-containing coatings and having an average molecular weight of from 25,000 to 150,000 is obtainable by reacting (1) a polyurethane (II) comprising a) 1 mol of a diol (III) having an average molecular weight of from 400 to 4,000, b) from 0.1 to 10 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms, c) from 0.01 to 10 mol of an aromatic diol (V) of 8 to 36 carbon atoms, d) from 0.01 to 2 mol of a trihydric or polyhydric alcohol (VI) of 3 to 18 carbon atoms, e) from 0.01 to 8 mol of a polyhydric alcohol (VII) of 3 to 40 carbon atoms which contains a tertiary amino group and f) an amount of a diisocyanate (VIII) of 6 to 34 carbon atoms such that the molar ratio of isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1, with (2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive towards isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II). The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:GB2282338A
公开(公告)日:1995-04-05
申请号:GB9419183
申请日:1994-09-22
Applicant: BASF MAGNETICS GMBH
Inventor: BRODT GREGOR , VASS ATTILA , LOCH WERNER , LEHNER AUGUST , LENZ WERNER , SCHNEIDER NORBERT
IPC: C08G18/10 , C08G18/62 , C08G18/78 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , C08L75/04
Abstract: A magnetic recording medium comprises a nonmagnetic substrate and at least one magnetizable layer firmly applied thereon and based on a magnetic material dispersed in a binder mixture which contains at least one hydroxyl-containing, preferably low molecular weight, polyureaurethane and at least one polyurethane-urea (meth)acrylate. The polyurethane-urea (meth)acrylate is obtained by reacting a poly(meth)acrylate having up to 2 terminal OH groups per mol and a molecular weight of from 200 to 50,000 with a mixture of aliphatic polyisocyanates having an average functionality of from 3.0 to 6.0 NCO groups per mol. The mixture comprises from 0.1 to 10% by weight of a diisocyante, from 30 to 80% by weight of a triisocyanate, and from 20 to 60% by weight of an isocyanate having a functionality of from 4 to 10. From 1.2 to 3.0 NCO groups react per OH group and the remaining NCO groups are converted into substituted terminal urea groups with a polyfunctional amine or with a mixture of two or more different polyfunctional amines.
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公开(公告)号:DE4142643A1
公开(公告)日:1993-06-24
申请号:DE4142643
申请日:1991-12-21
Applicant: BASF MAGNETICS GMBH
Inventor: LEHNER AUGUST , SCHNEIDER NORBERT , BALZ WERNER DR , LENZ WERNER DR , KOHL ALBERT , BETTINGER GUENTER , KLEIN URSULA
Abstract: A magnetic recording material is produced using a dispersion of anisotropic magnetic material and additional material in a solution of a polymer binding agent and an organic fluid. The mixture is spread over the surface of a non magnetic corner and the magnetic particles are oriented by a magnetic filed. Te mixture has carbon containing water repellent polysilicic acid of 0.3 to 5 percent by weight in combination with 0il to 0.5 percent by weight high viscosity polysiloxane. ADVANTAGE - High wear resistant fine particle structur%
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公开(公告)号:DE4141839A1
公开(公告)日:1993-06-24
申请号:DE4141839
申请日:1991-12-18
Applicant: BASF MAGNETICS GMBH
Inventor: LEHNER AUGUST , SCHNEIDER NORBERT , BOBRICH MICHAEL DR , LENZ WERNER DR , BALZ WERNER DR , KOHL ALBERT , RUDOLF PETER DR , BRODT GREGOR DR
Abstract: The material has magnetisable layer(s) on a nonmagnetic carrier, and contains a binder mixt. of a polyurethane urea (meth)acrylate (1) and polyurethane elastomer, a high MW OH- gp. contg. polyurethane urea and/or a low MW OH- contg. polyurethane urea. (1) is made by reaction of a poly(meth)acrylate with up to 2 OH-end gps. and a MW 200-50000 and a mixt. aliphatic polyisocyanates with an NCO- functionality of 3-6 per mole. The polyisocyanates contain 0.1-10 wt.% of diisocyanates, 20-80 wt.% triisocyanates and 20-60 wt.% of isocyanates with a functionality of 4-10. There are 1.2-3 NCO gps. per OH gp., and the remaining NCO gps are converted to urea gps. with ammonia or with prim. or sec. amines.
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公开(公告)号:DE4141838A1
公开(公告)日:1993-06-24
申请号:DE4141838
申请日:1991-12-18
Applicant: BASF MAGNETICS GMBH
Inventor: BOBRICH MICHAEL DR , LEHNER AUGUST , ROLLER HERMANN , SUETTINGER RUDOLF DR , KRESS RIA DR , SCHNEIDER NORBERT , LENZ WERNER DR , ENGELHARDT PETER , RUDOLF PETER DR , BRODT GREGOR DR
Abstract: The material has magnetisable layer(s) on a nonmagnetic carrier, and contains a binder mixt. of a polyurethane urea (meth)acrylate (1) and polyurethane elastomer, a high MW OH- gp. contg. polyurethane urea and/or a low MW OH- contg. polyurethane urea. (1) is made by reaction of a poly(meth)acrylate with up to 2 OH-end gps. and a MW 200-50000 and a mixt. aliphatic polyisocyanates with an NCO- functionality of 3-6 per mole. The polyisocyanates contain 0.1-10 wt.% of diisocyanates, 20-80 wt.% triisocyanates and 20-60 wt.% of isocyanates with a functionality of 4-10. There are 1.2-3 NCO gps. per OH gp., and the remaining NCO gps are converted to urea gps. with ammonia or with prim. or sec. amines.
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