Abstract:
PURPOSE: To provide a coupling agent having improved mechanical characteristics, such as, limit strength, hardness, wear resistance and elasticity, and exhibiting a high crosslinking speed, by causing the coupling agent to contain polyurethane made of predetermined components and a material having a specified molecular weight. CONSTITUTION: Polyurethane contains 1mol of diol having an average molecular weight of 400-4000, 0.3-9mol of aliphatic compound having 2-18 carbon atoms, 0.3-9mol of aromatic diol having 8-30 carbon atoms, and 0.01-1mol of trivalent alcohol having 3-8 carbon atoms. The polyurethane further contains 0.01-1mol of multivalent alcohol having 3-14 carbon atoms and tertiary amino group, and diisocyanate having 6-30 carbon atoms with a molar ratio of isocyanate group to all hydroxyl groups being 1.05:1-1.4:1. This polyurethane and a predetermined compound are caused to react under specified conditions to provide a material having an average molecular weight of 4000-30000, thereby forming a magnetic recording medium.
Abstract:
PCT No. PCT/EP95/00695 Sec. 371 Date Sep. 9, 1996 Sec. 102(e) Date Sep. 9, 1996 PCT Filed Feb. 25, 1995 PCT Pub. No. WO95/24443 PCT Pub. Date Sep. 14, 1995Magnetic powder and substrate material are separately recovered from finely chopped wastes of magnetic recording media consisting of a polymeric substrate and a magnetic layer present thereon in which finely divided magnetic powder is dispersed in crosslinked or uncrosslinked polymeric binder by treating the finely chopped wastes of magnetic recording media in a solution consisting of the potassium salt of a polyunsaturated fatty acid, or a biodegradable cleaning agent comprising phosphates, surfactants and a complexing agent, and one or more organic solvents or water while being subjected to mechanical action, and separately removing the magnetic powder from the substrate material by washing or sedimentation or in a magnetic separator.
Abstract:
A material (I) suitable as crosslinkable binder component for pigment-containing coatings and having an average molecular weight of from 25,000 to 150,000 is obtainable by reacting (1) a polyurethane (II) comprising a) 1 mol of a diol (III) having an average molecular weight of from 400 to 4,000, b) from 0.1 to 10 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms, c) from 0.01 to 10 mol of an aromatic diol (V) of 8 to 36 carbon atoms, d) from 0.01 to 2 mol of a trihydric or polyhydric alcohol (VI) of 3 to 18 carbon atoms, e) from 0.01 to 8 mol of a polyhydric alcohol (VII) of 3 to 40 carbon atoms which contains a tertiary amino group and f) an amount of a diisocyanate (VIII) of 6 to 34 carbon atoms such that the molar ratio of isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1, with (2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive towards isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II). The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
Abstract:
Preparation of materials (I) having an average molecular weight from 4000 to 30,000, obtainable by reacting 1) a polyurethane (II) comprising a) 1 mol of a diol (III) having an average molecular weight of from 400 to 4000, b) from 0.3 to 9 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms, c) from 0.3 to 9 mol of an aromatic diol (V) of 8 to 30 carbon atoms, d) from 0.01 to 1 mol of a trihydric alcohol (VI) of 3 to 18 carbon atoms, e) from 0.001 to 1 mol of a polyhydric alcohol (VII) of 3 to 14 carbon atoms which contains a tertiary amino group and f) an amount of a diisocyanate (VIII) of 6 to 30 carbon atoms such that the molar ratio of the isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1 with 2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II). The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
Abstract:
Curable binder component (1) with a mol.wt. of 4000-30000, useful for pigmented coatings, is prepd. from a polyurethane (II) obtd. by reacting (a) 1 mole diol with a mol.wt. of 400-4000, (b) 0.3-9 mole 2-18C (cyclo)aliphatic diol, (c) 0.3-9 mole 8-30 C aromatic diol, (d) 0.01-1 mole 3-18C triol and (e) 0.001-1 mole 3-14C polyol contg. a tert. amino gp. with (f) a 6-30 C diisocyanate, using a molar ratio of NCO gps. in (f) to total OH gp. in (a-e) of (1.05-1.4):1. (I) is prepd. by reacting (II) with a cpd. (III) having OH gp(s). and also NCO-reactive amino gp(s). in such an amt. that the no. of reaction amino gps. in (III) corresponds to the no. of NCO gps. in (II). Also claimed are articles with a coating, esp. a coating contg. a magnetic pigment, and magnetic recording materials contg. (I); and the coating process.
Abstract:
Hydroxyl-containing polyurethanes I are composed essentially of a) a diisocyanate of 6 to 30 carbon atoms (component II), b) a component III comprising alpha ) an aliphatic diol of 2 to 20 carbon atoms or beta ) an aromatic-aliphatic or aromatic-cycloaliphatic diol of 8 to 30 carbon atoms having nonphenolic hydroxyl groups as hydroxyl groups of the diol and c) a polyhydric alcohol having at least 3 hydroxyl groups, 3 to 18 carbon atoms and nonphenolic hydroxyl groups as hydroxyl groups of the alcohol (component IV), the amounts of components II to IV being such that the total number of nonphenolic hydroxyl groups is from 1.1 to 5.0 per isocyanate group of II. The polyurethanes can be used as binders or binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
Abstract:
Hydroxyl-containing polyurethanes I are derived from a) a diisocyanate of 6 to 30 carbon atoms (component II) with b) a component III comprising * small Greek alpha *) an aliphatic diol of 2 to 20 carbon atoms or * small Greek beta *) an aromatic-aliphatic or aromatic-cycloaliphatic diol of 8 to 30 carbon atoms having nonphenolic hydroxyl groups as hydroxyl groups of the diol, and c) a polyhydric alcohol having at least 3 hydroxyl groups, 3 to 18 carbon atoms and nonphenolic hydroxyl groups as hydroxyl groups of the alcohol (component IV), the amounts of components II to IV being such that the total number of nonphenolic hydroxyl groups is from 1.1 to 5.0 per isocyanate group of II. The polyurethanes can be used as binders or binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
Abstract:
PCT No. PCT/EP95/00695 Sec. 371 Date Sep. 9, 1996 Sec. 102(e) Date Sep. 9, 1996 PCT Filed Feb. 25, 1995 PCT Pub. No. WO95/24443 PCT Pub. Date Sep. 14, 1995Magnetic powder and substrate material are separately recovered from finely chopped wastes of magnetic recording media consisting of a polymeric substrate and a magnetic layer present thereon in which finely divided magnetic powder is dispersed in crosslinked or uncrosslinked polymeric binder by treating the finely chopped wastes of magnetic recording media in a solution consisting of the potassium salt of a polyunsaturated fatty acid, or a biodegradable cleaning agent comprising phosphates, surfactants and a complexing agent, and one or more organic solvents or water while being subjected to mechanical action, and separately removing the magnetic powder from the substrate material by washing or sedimentation or in a magnetic separator.
Abstract:
Preparation of materials (I) having an average molecular weight from 4000 to 30,000, obtainable by reacting 1) a polyurethane (II) comprising a) 1 mol of a diol (III) having an average molecular weight of from 400 to 4000, b) from 0.3 to 9 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms, c) from 0.3 to 9 mol of an aromatic diol (V) of 8 to 30 carbon atoms, d) from 0.01 to 1 mol of a trihydric alcohol (VI) of 3 to 18 carbon atoms, e) from 0.001 to 1 mol of a polyhydric alcohol (VII) of 3 to 14 carbon atoms which contains a tertiary amino group and f) an amount of a diisocyanate (VIII) of 6 to 30 carbon atoms such that the molar ratio of the isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1 with 2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II). The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
Abstract:
Preparation of materials (I) having an average molecular weight from 4000 to 30,000, obtainable by reacting 1) a polyurethane (II) comprising a) 1 mol of a diol (III) having an average molecular weight of from 400 to 4000, b) from 0.3 to 9 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms, c) from 0.3 to 9 mol of an aromatic diol (V) of 8 to 30 carbon atoms, d) from 0.01 to 1 mol of a trihydric alcohol (VI) of 3 to 18 carbon atoms, e) from 0.001 to 1 mol of a polyhydric alcohol (VII) of 3 to 14 carbon atoms which contains a tertiary amino group and f) an amount of a diisocyanate (VIII) of 6 to 30 carbon atoms such that the molar ratio of the isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1 with 2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II). The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.