LIQUID STABILIZER MIXTURES
    21.
    发明专利

    公开(公告)号:SG11201401069TA

    公开(公告)日:2014-04-28

    申请号:SG11201401069T

    申请日:2012-09-27

    Abstract: The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185° C. or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90° C. to 140° C. and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90° C. or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.

    Mezclas líquidas de éster y tris fosfito con puente de oxialquileno

    公开(公告)号:ES2390411T3

    公开(公告)日:2012-11-12

    申请号:ES09779878

    申请日:2009-06-23

    Applicant: BASF SE

    Abstract: Una composición líquida que comprendea) un compuesto de la fórmula I **Fórmula**yb) un compuesto de la fórmula II **Fórmula**dondeR es hidrógeno o metilo,n y n' son independientemente un número entero de 1 a 45 yR1, R2 y R3 son cada uno independientemente hidrógeno, alquilo de cadena lineal o ramificada de 1 a 12 átomos decarbono, fenilalquilo de 7 a 9 átomos de carbono, fenilalquilo de 7 a 9 átomos de carbono sustituido sobre el anillofenilo por uno a tres alquilos de cadena lineal o ramificada de 1 a 12 átomos de carbono o R1, R2 y R3 son cada unoindependientemente -(CH2)k-COOR4, donde k es 0, 1 o 2 y R4 es hidrógeno o alquilo de cadena lineal o ramificadade 1 a 20 átomos de carbono.

    LIQUID STABILIZER MIXTURES
    24.
    发明专利

    公开(公告)号:CA2850191C

    公开(公告)日:2019-09-17

    申请号:CA2850191

    申请日:2012-09-27

    Applicant: BASF SE

    Abstract: The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185°C or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90°C to 140°C and maintaining the liquid blend at a temperature of from 90°C to 140°C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90°C or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90°C to 140°C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.

    3-PHENYL-BENZOFURAN-2-ONE DERIVATIVES CONTAINING PHOSPHORUS AS STABILIZERS

    公开(公告)号:ZA201606530B

    公开(公告)日:2018-05-30

    申请号:ZA201606530

    申请日:2016-09-12

    Applicant: BASF SE

    Abstract: The invention relates to a composition comprising an organic material susceptible to oxidative, thermal or light-induced degradation and a compound (101), (102), (103), (104), (105), (106), (107), (108) or (109), which are 3-phenyl-benzofuran-2-one derivatives containing phosphorus. Further embodiments are a compound (101), (102), (103), (104), (105), (106), (107), (108) or (109), a process for protection of the organic material by the compound, the use of the compound for stabilizing the organic material, an additive composition comprising the compound, a process for manufacturing the compound and intermediates involved therein.

    LIQUID OXYALKYLENE BRIDGED BIS- AND TRIS-PHOSPHITE ESTER MIXTURES

    公开(公告)号:CA2729908C

    公开(公告)日:2016-08-16

    申请号:CA2729908

    申请日:2009-06-23

    Applicant: BASF SE

    Abstract: Disclosed are liquid com-positions comprising a) a compound of formula I(I) and b) a compound of for-mula II (II) where R is hydrogen or methyl, n and n' are independently an in-teger from 1 to 45 and R 1, R 2 and R 3 are each independently hydrogen, straight or branched chain alkyl of 1 to 12 carbon atoms, phenylalkyl of 7 to 9 carbon atoms, phenylalkyl of 7 to 9 carbon atoms substituted on the phenyl ring by one to three straight or branched chain alkyl of 1 to 12 carbon atoms or R 1, R 2 and R 3 are each independently -(CH2)k-COOR 4 where k is 0, 1 or 2 and R 4 is hydrogen or straight or branched chain alkyl of 1 to 20 carbon atoms. The compositions compris-ing oxyalkylene bridged bis-and tris--phosphite esters of formulae I and II are liquid at ambient conditions and are effec-tive stabilizers for polyolefins.

    LIQUID STABILIZER MIXTURES
    28.
    发明专利

    公开(公告)号:CA2850191A1

    公开(公告)日:2013-04-18

    申请号:CA2850191

    申请日:2012-09-27

    Applicant: BASF SE

    Abstract: The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185°C or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90°C to 140°C and maintaining the liquid blend at a temperature of from 90°C to 140°C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90°C or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90°C to 140°C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.

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