-
公开(公告)号:SG11201401069TA
公开(公告)日:2014-04-28
申请号:SG11201401069T
申请日:2012-09-27
Applicant: BASF SE , YU JIONG , KING ROSWELL EASTON
Inventor: YU JIONG , KING ROSWELL EASTON
Abstract: The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185° C. or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90° C. to 140° C. and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90° C. or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.
-
公开(公告)号:ES2390411T3
公开(公告)日:2012-11-12
申请号:ES09779878
申请日:2009-06-23
Applicant: BASF SE
Inventor: KING ROSWELL EASTON , PADEGIMAS STANLEY J , BAKKE BRIAN , MOORE LUCAS R , SHUM SAI PING , CORDOVA ROBERT
Abstract: Una composición líquida que comprendea) un compuesto de la fórmula I **Fórmula**yb) un compuesto de la fórmula II **Fórmula**dondeR es hidrógeno o metilo,n y n' son independientemente un número entero de 1 a 45 yR1, R2 y R3 son cada uno independientemente hidrógeno, alquilo de cadena lineal o ramificada de 1 a 12 átomos decarbono, fenilalquilo de 7 a 9 átomos de carbono, fenilalquilo de 7 a 9 átomos de carbono sustituido sobre el anillofenilo por uno a tres alquilos de cadena lineal o ramificada de 1 a 12 átomos de carbono o R1, R2 y R3 son cada unoindependientemente -(CH2)k-COOR4, donde k es 0, 1 o 2 y R4 es hidrógeno o alquilo de cadena lineal o ramificadade 1 a 20 átomos de carbono.
-
公开(公告)号:AT474011T
公开(公告)日:2010-07-15
申请号:AT07803038
申请日:2007-08-30
Applicant: BASF SE
Inventor: FINK JOCHEN , PFAENDNER RUDOLF , KING ROSWELL EASTON , SHUM SAI PING , PADEGIMAS STANLEY J
IPC: C08G79/02 , C07F9/59 , C08G79/025 , C08G79/04 , C08K5/529 , C08K5/5373 , C08L85/02
Abstract: Novel liquid polymeric compounds of the formula (I) wherein the general symbols are as defined in claim 1, are disclosed as stabilizers for protecting organic materials against oxidative, thermal or light-induced degradation.
-
公开(公告)号:CA2850191C
公开(公告)日:2019-09-17
申请号:CA2850191
申请日:2012-09-27
Applicant: BASF SE
Inventor: YU JIONG , KING ROSWELL EASTON
Abstract: The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185°C or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90°C to 140°C and maintaining the liquid blend at a temperature of from 90°C to 140°C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90°C or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90°C to 140°C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.
-
公开(公告)号:AU2015216958B2
公开(公告)日:2018-08-30
申请号:AU2015216958
申请日:2015-02-13
Applicant: BASF SE
Inventor: HOLZL WERNER , ROTZINGER BRUNO , SCHONING KAI-UWE , KING ROSWELL EASTON
IPC: C08K5/523 , C08K5/5393 , C08L23/00
Abstract: The invention relates to a composition comprising an organic material susceptible to oxidative, thermal or light-induced degradation and a compound of formula l-P, 1-O or I-M. Further embodiments are a compound of formula l-P, l-O or l-M, a process for protection of the organic material by the compound, the use of the compound for stabilizing the organic material, an additive composition comprising the compound, a process for manufacturing the compound and intermediates involved therein.
-
公开(公告)号:ZA201606530B
公开(公告)日:2018-05-30
申请号:ZA201606530
申请日:2016-09-12
Applicant: BASF SE
Inventor: KING ROSWELL EASTON , SCHÖNING KAI-UWE , HÖLZL WERNER , ROTZINGER BRUNO
Abstract: The invention relates to a composition comprising an organic material susceptible to oxidative, thermal or light-induced degradation and a compound (101), (102), (103), (104), (105), (106), (107), (108) or (109), which are 3-phenyl-benzofuran-2-one derivatives containing phosphorus. Further embodiments are a compound (101), (102), (103), (104), (105), (106), (107), (108) or (109), a process for protection of the organic material by the compound, the use of the compound for stabilizing the organic material, an additive composition comprising the compound, a process for manufacturing the compound and intermediates involved therein.
-
公开(公告)号:CA2729908C
公开(公告)日:2016-08-16
申请号:CA2729908
申请日:2009-06-23
Applicant: BASF SE
Inventor: KING ROSWELL EASTON , PADEGIMAS STANLEY J , BAKKE BRIAN , MOORE LUCAS R , SHUM SAI PING , CORDOVA ROBERT
Abstract: Disclosed are liquid com-positions comprising a) a compound of formula I(I) and b) a compound of for-mula II (II) where R is hydrogen or methyl, n and n' are independently an in-teger from 1 to 45 and R 1, R 2 and R 3 are each independently hydrogen, straight or branched chain alkyl of 1 to 12 carbon atoms, phenylalkyl of 7 to 9 carbon atoms, phenylalkyl of 7 to 9 carbon atoms substituted on the phenyl ring by one to three straight or branched chain alkyl of 1 to 12 carbon atoms or R 1, R 2 and R 3 are each independently -(CH2)k-COOR 4 where k is 0, 1 or 2 and R 4 is hydrogen or straight or branched chain alkyl of 1 to 20 carbon atoms. The compositions compris-ing oxyalkylene bridged bis-and tris--phosphite esters of formulae I and II are liquid at ambient conditions and are effec-tive stabilizers for polyolefins.
-
公开(公告)号:CA2850191A1
公开(公告)日:2013-04-18
申请号:CA2850191
申请日:2012-09-27
Applicant: BASF SE
Inventor: YU JIONG , KING ROSWELL EASTON
Abstract: The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185°C or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90°C to 140°C and maintaining the liquid blend at a temperature of from 90°C to 140°C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90°C or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90°C to 140°C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.
-
公开(公告)号:PL2061829T3
公开(公告)日:2010-12-31
申请号:PL07803038
申请日:2007-08-30
Applicant: BASF SE
Inventor: FINK JOCHEN , PFAENDNER RUDOLF , KING ROSWELL EASTON , SHUM SAI PING , PADEGIMAS STANLEY J
IPC: C08G79/02 , C07F9/59 , C08G79/025 , C08G79/04 , C08K5/529 , C08K5/5373 , C08L85/02
-
公开(公告)号:ES2349199T3
公开(公告)日:2010-12-28
申请号:ES07803038
申请日:2007-08-30
Applicant: BASF SE
Inventor: FINK JOCHEN , PADEGIMAS STANLEY J , KING ROSWELL EASTON , SHUM SAI PING , PFAENDNER RUDOLF
IPC: C08G79/02 , C07F9/59 , C08G79/025 , C08G79/04 , C08K5/529 , C08K5/5373 , C08L85/02
Abstract: Un compuesto polimérico de la fórmula I **(Ver fórmula)** en donde L es -X-R4-Y-, R0 es hidrógeno, alquilo C1 -C25 o **(Ver fórmula)** R1 es hidrógeno o alquilo C1 -C4, R2 es hidrógeno o metilo, R3 es alquilo C1 -C25, alquenilo C2 -C25; con oxígeno, azufre o **(Ver fórmula)** alquilo C2 -C25 interrumpido; o cicloalquilo C5 -C12, R4 es alquileno C1 -C24, alquenileno C2 -C24; con oxígeno, azufre o **(Ver fórmula)** alquileno C2 -C24 interrumpido: R5 es hidrógeno o alquilo C1 -C8, X es -O-, -S-o Y es -O-, -S-o **(Ver fórmula)** 20 **(Ver fórmula)** m es 0 ó 1, y n es un entero de 2 a 100.
-
-
-
-
-
-
-
-
-