A PROCESS FOR PREPARING A ZEOLITIC MATERIAL COMPRISING A METAL M AND HAVING FRAMEWORK TYPE AEI

    公开(公告)号:WO2018210815A1

    公开(公告)日:2018-11-22

    申请号:PCT/EP2018/062531

    申请日:2018-05-15

    Abstract: A process for preparing a zeolitic material comprising a metal M, having framework type AEI, and having a framework structure which comprises a tetravalent element Y, a trivalent element X, and oxygen, said process comprising (i) providing a zeolitic material comprising the metal M, having a framework type other than AEI, and having a framework structure comprising the trivalent element X, and oxygen; (ii) preparing a synthesis mixture comprising the zeolitic material provided in (i), water, a source of the tetravalent element Y, and an AEI framework structure directing agent; (iii) subjecting the synthesis mixture prepared in (ii) to hydrothermal synthesis conditions comprising heating the synthesis mixture to a temperature in the range of from 100 to 200 °C and keeping the synthesis mixture at a temperature in this range under autogenous pressure, obtaining the zeolitic material having framework type AEI; wherein Y is one or more of Si, Ge, Sn, Ti, Zr; wherein X is one or more of Al, B, Ga, In; wherein M is a transition metal of groups 7 to 12 of the periodic table of elements.

    STORAGE VESSEL COMPRISING AT LEAST ONE SHAPED BODY OF A POROUS SOLID WITH SPACERS
    26.
    发明申请
    STORAGE VESSEL COMPRISING AT LEAST ONE SHAPED BODY OF A POROUS SOLID WITH SPACERS 审中-公开
    至少有一个多孔固体的形状的存储容器与间隔物

    公开(公告)号:WO2016075129A1

    公开(公告)日:2016-05-19

    申请号:PCT/EP2015/076190

    申请日:2015-11-10

    Applicant: BASF SE

    Abstract: The invention is related to a storage vessel (1) comprising at least one shaped body (3) of a porous solid, wherein the storage vessel (1) comprises a wall (5) with at least one inlet (7), the storage vessel (1) having a central axis (9), the central axis (9) being a longitudinal axis of the storage vessel (1) and/or perpendicular to a cross-sectional area of the inlet (7), wherein at least 80% of a radial cross-sectional area (19) of the storage vessel (1) is covered by the at least one shaped body (3), wherein a ratio between a longest first extension (11) of the at least one shaped body (3) in a radial direction (13) and a longest second extension (15) of the at least one shaped body (3) in an axial direction (17) is equal to or greater than 5, axial and radial referring to the central axis (9) of the storage vessel (1), wherein an opening (21) in the axial direction (17) is provided in the at least one shaped body (3) and wherein at least one first spacer (25) is provided next to or on a lateral surface (23) of the at least one shaped body (3), the lateral surface (23) facing in the axial direction (17). The invention is further related to a shaped body and use of the shaped body.

    Abstract translation: 本发明涉及一种包括多孔固体的至少一个成形体(3)的储存容器(1),其中所述储存容器(1)包括具有至少一个入口(7)的壁(5),所述储存容器 (1)具有中心轴线(9),所述中心轴线(9)是所述储存容器(1)的纵向轴线和/或垂直于所述入口(7)的横截面积,其中至少80% 所述储存容器(1)的径向横截面面积(19)被所述至少一个成形体(3)覆盖,其中所述至少一个成形体(3)的最长第一延伸部(11) )沿着轴向方向(17)的所述至少一个成形体(3)的径向方向(13)和最长的第二延伸部(15)等于或大于5,轴向和径向指中心轴线 9),其中在所述至少一个成形体(3)中设置有沿所述轴向方向(17)的开口(21),并且其中至少一个第一间隔件(25)设置在所述至少一个成形体 r在所述至少一个成形体(3)的侧表面(23)上,所述侧表面(23)面向轴向方向(17)。 本发明还涉及成形体和成形体的用途。

    METAL IMPREGNATED AMORPHOUS SILICATES FOR THE SELECTIVE CONVERSION OF ETHANOL TO BUTADIENE
    30.
    发明申请
    METAL IMPREGNATED AMORPHOUS SILICATES FOR THE SELECTIVE CONVERSION OF ETHANOL TO BUTADIENE 审中-公开
    用于乙醇选择性转化为丁二烯的金属浸渍的无定形硅酸盐

    公开(公告)号:WO2014199349A2

    公开(公告)日:2014-12-18

    申请号:PCT/IB2014/062203

    申请日:2014-06-13

    Abstract: The present invention relates to a catalyst for the preparation of butadiene comprising Hf and two or more further catalytically active metals M1 and M2, wherein the two or more fur- ther catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2; as well as to a process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 provided in (i) with theinventive catalyst, thereby obtaining a gas stream G-2 comprising butadiene; wherein the catalyst comprises Hf and two or more further catalytically active metals M and M2, wherein the twoor morefurther catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2, as well as to the use of the catalyst comprises Hf and two or more further catalytically active 1 metals M1 and M2, wherein the twoor morefurther catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2.

    Abstract translation: 本发明涉及一种用于制备丁二烯的催化剂,其包含Hf和两种或更多种其它催化活性金属M1和M2,其中两种或多种其它催化活性金属M1和M2选自Zr,Zn ,Cu及其两种或更多种的组合,并且其中M1不同于M2; 以及制备丁二烯的方法,包括(i)提供包含乙醇的气流G-1; (ii)使(i)中提供的气流G-1与所述催化剂接触,从而获得包含丁二烯的气流G-2; 其中所述催化剂包含Hf和两种或更多种其它催化活性金属M和M2,其中所述更多的另外的催化活性金属M1和M2选自Zr,Zn,Cu及其两种或更多种的组合,并且其中M1 与M2不同,以及催化剂的使用包括Hf和两种或更多种其它催化活性的金属M1和M2,其中所述更多的另外的催化活性金属M1和M2选自Zr,Zn, Cu及其两种或更多种的组合,并且其中M1不同于M2。

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