公开(公告)号：WO1991013052A1

公开(公告)日：1991-09-05

申请号：PCT/US1991000639

申请日：1991-01-30

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  LIU, Kou-Chang ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A. ,  NARAYANAN, Kolazi, S. ,  PLOTKIN, Jeffrey, S. ,  TAYLOR, Paul, D.

IPC: C07C69/96

CPC classification number: C07C43/23 ,  C07C69/96

Abstract: Alkenyl ether carbonates having formula (A) wherein A is RHC=CHO(B)n-, lower alkyl or a mixture thereof; B is (a) divalent radical having from 2 to 12 carbon atoms and is selected from the group of alkylene, mono or polyalkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R is hydrogen or lower alkyl and n is from 1 to 10. These are provided alkenyl ether polycarbonate, a polymerizable compound formed from reaction of a dialkenyl ether monocarbonate and a polyhydroxy alcohol having at least three hydroxy groups, a polymerizable compound formed from the reaction of a hydroxylated polymeric polyether, polyurethane, polycarbonate, polyester of an alkanedioic acid or polybutadiene and a dialkenyloxy carbonate co-reactant, and polyaryloxypolyvinyl ethers. The polymerized compounds are intermediates for hard abrasion resistant films and coatings. The monomers and oligomers are intermediates for hydrogels or photoresist materials.

Abstract translation: 式（A）的烯基醚碳酸酯，其中A为RHC = CHO（B）n-，低级烷基或其混合物; B是（a）具有2至12个碳原子的二价基团，并且选自亚烷基，单或多烷氧基化的亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，其基团任选被卤素，烷基，氰基 ，硝基或烷氧基; R为氢或低级烷基，n为1〜10。这些为烯基醚聚碳酸酯，由二烯基醚单碳酸酯与至少具有三个羟基的多羟基醇反应形成的可聚合化合物，由反应形成的可聚合化合物 的羟基化聚合物聚醚，聚氨酯，聚碳酸酯，链烷二酸或聚丁二烯的聚酯和二链烯基氧基碳酸酯共反应物，以及聚芳氧基聚乙烯醚。 聚合的化合物是用于硬质耐磨膜和涂层的中间体。 单体和低聚物是水凝胶或光致抗蚀剂材料的中间体。

公开(公告)号：WO1998019980A1

公开(公告)日：1998-05-14

申请号：PCT/US1997018349

申请日：1997-10-06

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  COHEN, Jeffrey, M. ,  WOLF, Philip, F. ,  YOUNG, William, D.

IPC: C07C07/20

CPC classification number: C10L3/00 ,  C09K8/52 ,  C10L1/143 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/2368 ,  C10L3/06

Abstract: A composition for preventing or retarding the formation of gas hydrates or for reducing the tendency of gas hydrates to agglomerate, during the transport of a fluid comprising water and a hydrocarbon, through a conduit, comprising, (a) a polymer or copolymer selected from a terpolymer of vinyl pyrrolidone, vinyl caprolactam and an ammonium derivative monomer having from 6 to 12 carbon atoms, selected from the group consisting of dialkyl aminoalkyl methacrylamide, dialkyl dialkenyl ammonium halide and a dialkylamino alkyl acrylate or methacrylate, a copolymer of vinyl pyrrolidone and vinyl caprolactam, and a homopolymer of vinyl caprolactam, and (b) an alcohol containing three to five carbon atoms and one hydroxy group, or a low molecular weight glycol ether containing an alkoxy group having at least 3 carbon atoms.

Abstract translation: 一种用于在包含水和烃的流体输送通过导管的过程中，预防或延缓气体水合物的形成或降低气体水合物凝聚的倾向，该组合物包括：（a）选自以下的聚合物或共聚物： 乙烯基吡咯烷酮，乙烯基己内酰胺和具有6至12个碳原子的铵衍生物单体的三元共聚物，选自二烷基氨基烷基甲基丙烯酰胺，二烷基二链烷基卤化铵和二烷基氨基烷基丙烯酸酯或甲基丙烯酸酯，乙烯基吡咯烷酮和乙烯基己内酰胺的共聚物 和乙烯基己内酰胺的均聚物，和（b）含有3-5个碳原子和一个羟基的醇或含有至少3个碳原子的烷氧基的低分子量二醇醚。

公开(公告)号：WO1998008878A1

公开(公告)日：1998-03-05

申请号：PCT/US1997011892

申请日：1997-06-19

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  DOUGHERTY, James, A. ,  MCKITTRICK, John, G. ,  CLARK, Raymond, Bret

IPC: C08F04/18

CPC classification number: C08F16/16

Abstract: A process for polymerizing a vinyl ether monomer which comprises contacting the vinyl ether with an initiator system of silicon dioxide and one or more metallic oxides.

Abstract translation: 一种聚合乙烯基醚单体的方法，其包括使乙烯基醚与二氧化硅和一种或多种金属氧化物的引发剂体系接触。

公开(公告)号：WO1998006780A1

公开(公告)日：1998-02-19

申请号：PCT/US1997010897

申请日：1997-06-24

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  NARAYANAN, Kolazi, S. ,  CURRY, James, F. ,  GOEHNER, Ronald, H., Jr.

IPC: C08K05/3415

CPC classification number: A01N25/22

Abstract: A stabilizer additive composition for a diluted tank mix of an agricultural chemical which will inhibit crystal formation therein when present in an amount of about 0.05-1 % by volume of the mix, comprising by weight: (a) about 5-50 % of a water insoluble polymer of vinyl pyrrolidone which is > 30 % alkylated with a C4-C24 alkyl group, and has an HLB

Abstract translation: 一种用于农药的稀释罐混合物的稳定剂添加剂组合物，其以约0.05-1体积％的混合物的量存在时将抑制其中的晶体形成，所述组合物包含：（a）约5-50％的 乙烯基吡咯烷酮的水不溶性聚合物，其用C 4 -C 24烷基烷基化并且具有HLB <18; （b）约10-90％的十二烷基或辛基吡咯烷或其混合物，其在R.T.具有<0.01％的CMC，约2-8的HLB; 和（c）约5-40％的阴离子表面活性剂。

公开(公告)号：WO1997028197A1

公开(公告)日：1997-08-07

申请号：PCT/US1997000110

申请日：1997-01-13

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  KWAK, Yoon, Tae ,  NARAYANAN, Kolazi, S. ,  KOPOLOW, Stephen, L.

IPC: C08F222/06

CPC classification number: C08F216/12

Abstract: This invention relates to a 1-8 % cross-linked terpolymer of a C1-C4 alkyl vinyl ether, maleic anhydride and a hydrophobic C6 to C18 alkyl vinyl ether in a critical molar ratio of from 1-3:1:0.01-0.20, which polymer has a pH of from about 4 to about 11, a Brookfield viscosity of from about 10,000 to about 150,000 cps and is characterized as having desirable salt tolerance enhanced viscosity, stability, low residual monomers and enhanced use characteristics. The invention also relates to liquid or aqueous gel compositions of the cross-linked terpolymer containing a salt and a method for the preparation of said cross-linked terpolymer gel.

Abstract translation: 本发明涉及C1-C4烷基乙烯基醚，马来酸酐和疏水性C6至C18烷基乙烯基醚的1-8％交联三元共聚物，其临界摩尔比为1-3:1至0.01-0.20， 该聚合物的pH为约4至约11，布鲁克菲尔德粘度为约10,000至约150,000cps，并且其特征在于具有所需的盐耐受性增强的粘度，稳定性，低残留单体和增强的使用特性。 本发明还涉及含有盐的交联三元共聚物的液体或水性凝胶组合物以及制备所述交联三元共聚物凝胶的方法。

公开(公告)号：WO1997021427A1

公开(公告)日：1997-06-19

申请号：PCT/US1996014928

申请日：1996-09-10

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  ULMER, Herbert ,  ROCAFORT, Colleen, M.

IPC: A61K09/12

CPC classification number: A61Q5/06 ,  A61K8/046 ,  A61K8/8164 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S514/957

Abstract: A hair spray composition of 80 % or less VOC includes a fixative which is the half-ester of a copolymer of maleic anhydride and methyl vinyl ether having advantageous physical and performance properties even at low fixative levels. The copolymer is made by polymerizing the monomers at a selected temperature in the presence of a predetermined amount of a polymerization initiator whose decomposition fragments are soluble in hydroalcoholic solutions containing high levels of water. The composition is clear and without precipitate formation, has a low weight average molecular weight and a narrow molecular weight distribution, or polydispersity, affording a low solution viscosity. The composition also forms a spray pattern of small particle size, providing clear, hard fixative films with superior adhesion to the hair of the user, an advantageous high humidity curl retention (hold), and low tack and dry times, in both pump and aerosol products.

Abstract translation: 80％或更低VOC的喷发组合物包括固定剂，其即使在低固定水平下也具有有利的物理和性能特性的马来酸酐和甲基乙烯基醚的共聚物的半酯。 共聚物是通过在预定量的聚合引发剂存在下在选定温度下聚合单体制备的，其分解片段可溶于含有高含量水的水醇溶液。 该组合物是透明的且没有沉淀物形成，具有低重均分子量和窄分子量分布或多分散性，提供低溶液粘度。 该组合物还形成小粒径的喷雾图案，提供清晰，硬的固定膜，具有优于使用者头发的粘附性，在泵和气溶胶中有利的高湿度卷曲保持（保持）和低粘性和干燥时间 产品。

公开(公告)号：WO1997002809A1

公开(公告)日：1997-01-30

申请号：PCT/US1996004796

申请日：1996-04-08

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  MC GILL, Elayne ,  WALLS, Edward, W., Jr. ,  DALLAL, Joseph, A.

IPC: A61K09/12

CPC classification number: A61K8/046 ,  A61K8/922 ,  A61Q5/06

Abstract: Anhydrous and low VOC hydroalcoholic hair spray compositions including 80 % or less VOC components, and a hair fixative polymer, and, optionally, water, ethanol and/or a propellant, contains gum rosin as a performance enhancing additive in an amount up to about 1 % by weight of the composition. The presence of gum rosin improves use performance characteristics particularly reduced tack period, decreased drying time, and increased stiffness.

Abstract translation: 包含80％或更少VOC组分的无水和低VOC水醇发胶组合物，以及头发固定剂聚合物，以及任选的水，乙醇和/或推进剂，含有作为性能增强添加剂的松香作为高达约1 重量％的组合物。 橡胶松香的存在提高了使用性能特征，特别是降低粘着时间，减少干燥时间和增加刚度。

公开(公告)号：WO1996020691A1

公开(公告)日：1996-07-11

申请号：PCT/US1995016803

申请日：1995-12-22

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  SHIH, Jenn, S. ,  ROCAFORT, Colleen, M. ,  LOGIN, Robert, B.

IPC: A61K07/11

CPC classification number: A61K8/046 ,  A61K8/8182 ,  A61Q5/06 ,  Y10S424/02

Abstract: A low VOC (volatile organic compounds) hair spray composition having a combination of desirable user performance characteristics is described herein. The hair fixative resin in the composition is a terpolymer of 40-75 % by weight of a vinyl lactam, preferably vinyl pyrrolidone, 15-40 % of a polymerizable carboxylic acid, preferably acrylic acid or methacrylic acid, and 5-25 % of a hydrophobic monomer, preferably a long chain alkyl (C8-C24) acrylate, methacrylate, acrylamide or methacrylamide. The terpolymer has a K-value of 30-55, preferably 40-50, which provides compositions having good sprayability in both pump and aerosol form, and small, fine spray particles.

Abstract translation: 本文描述了具有期望的用户性能特征的组合的低VOC（挥发性有机化合物）喷发组合物。 组合物中的头发固定树脂是40-75重量％的乙烯基内酰胺，优选乙烯基吡咯烷酮，15-40％的可聚合羧酸，优选丙烯酸或甲基丙烯酸，和5-25％ 疏水单体，优选长链烷基（C 8 -C 24）丙烯酸酯，甲基丙烯酸酯，丙烯酰胺或甲基丙烯酰胺。 三元共聚物的K值为30-55，优选为40-50，其提供在泵和气溶胶形式以及小的细小喷雾颗粒中具有良好喷雾性的组合物。

公开(公告)号：WO1996018673A1

公开(公告)日：1996-06-20

申请号：PCT/US1995015434

申请日：1995-11-29

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  ZHONG, Yuanzhen ,  WOLF, Philip, F.

IPC: C08K05/3412

CPC classification number: C08K5/0091 ,  C08F226/06

Abstract: This invention relates to a process for the production of substantially odorless, color stable N-vinyl heterocyclic copolymer which includes contacting alcohol solution of the copolymer, under reduced pressure, with water and a reducing agent selected from the group of a nitrogen containing borane complex, sulfurous acid and an alkali metal salt of sulfurous acid and recovering an aqueous, 10-80 wt.% solids solution of the copolymer having a substantially color free stability for a period of more than a year. The invention also relates to an N-vinyl heterocyclic copolymer in substantially pure deionized water or in aqueous alcoholic solution which exhibits significantly reduced color and odor and which is obtained by contacting an alcohol-copolymer mixture with water and a nitrogen containing, trivalent boron complex compound and stripping alcohol from the resulting mixture.

Abstract translation: 本发明涉及一种生产基本无臭，色泽稳定的N-乙烯基杂环共聚物的方法，该方法包括使该共聚物的乙醇溶液在减压下与水和选自含氮硼烷络合物， 亚硫酸和亚硫酸的碱金属盐，并回收具有基本上无色稳定性的共聚物的10-80重量％固含量的水溶液，持续一年以上的时间。 本发明还涉及在基本上纯的去离子水或含水醇溶液中的N-乙烯基杂环共聚物，其表现出显着降低的颜色和气味，并且其通过使醇共聚物混合物与水和含氮三价硼络合物 并从所得混合物中汽提醇。

公开(公告)号：WO1994010979A1

公开(公告)日：1994-05-26

申请号：PCT/US1993010881

申请日：1993-11-11

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  NARAYANAN, Kolazi, S.

IPC: A61K09/107

CPC classification number: A01N25/24 ,  A01N25/22 ,  A01N43/36 ,  A01N63/00 ,  A61K8/35 ,  A61K8/368 ,  A61K8/37 ,  A61K8/445 ,  A61K8/4913 ,  A61K8/8182 ,  A61Q17/04 ,  Y10S514/937 ,  Y10S514/938 ,  A01N2300/00 ,  A01N25/10 ,  A01N25/04

Abstract: A composition comprising a long-chain alkylpyrrolidone, a surfactant, and film-forming water-soluble polymer wherein the amounts of the components are such that on dilution with water, a clear liquid is formed. The composition may be used as a medium for agriculturally active ingredients as well as other active ingredients which are suitable for film formation, e.g., wood protectants, and the like. Also, emulsion concentrates of water-insoluble film-forming polymers are disclosed which can be utilized to form water-resistant films of active ingredients, such as, agriculturally active chemicals. Methods for preparation and use of the emulsion concentrates are disclosed.

Abstract translation: 包含长链烷基吡咯烷酮，表面活性剂和成膜水溶性聚合物的组合物，其中组分的量使得在用水稀释时形成透明液体。 该组合物可以用作农业活性成分的介质以及适用于成膜的其它活性成分，例如木材保护剂等。 此外，公开了可用于形成活性成分例如农业活性化学品的防水膜的水不溶性成膜聚合物的乳液浓缩物。 公开了制备和使用乳液浓缩物的方法。