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公开(公告)号:CA2112021A1
公开(公告)日:1994-06-23
申请号:CA2112021
申请日:1993-12-21
Applicant: MITSUI PETROCHEMICAL IND
Inventor: YAMAGUCHI MASAYOSHI , ISHIMOTO AKIO , WAKUMOTO HIROSHI , SUGI MASAHIRO
Abstract: Disclosed are a polypropylene composition comprising 95 - 55 parts by weight of polypropylene (A) and 5 - 95 parts by weight of an ethylene/1-butene random copolymer (B-1) which contains constituent units derived from 1-butene in an amount of 15 to 25 % by mol; and a polypropylene composition comprising 95 - 55 parts by weight of polypropylene (A) and 5 - 45 parts by weight of an ethylene/1-octene random copolymer (B-2) which contains constituent units derived from 1-octene in an amount of 8 to 20 % by mol. Each of the random copolymers (B-1) and (B-2) has an intrinsic viscosity ¢~! of 1.5 to 3.5 dl/g as measured in decalin, a glass transition temperature (Tg) of not higher than -50.degree.C, a crystallinity of less than 20 % as measured by X-ray diffractometry, a randomness parameter (B value) of 1.0 to 1.4 as measured by 13C-NMR spectroscopy. With respect to a melting point as measured by a differential scanning calorimeter (DSC) as the main peak, the copolymer (B-1) has a value of not higher than 60 .degree.C, while the copolymer (B-2) has a value of not higher than 80 .degree.C .
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公开(公告)号:HK112293A
公开(公告)日:1993-10-29
申请号:HK112293
申请日:1993-10-21
Applicant: MITSUI PETROCHEMICAL IND
Inventor: SUGI MASAHIRO , NAKAGAWA TAKASI
IPC: B32B27/32 , B65D17/40 , B65D65/40 , B65D77/38 , C08L23/06 , C08L23/08 , C08L23/12 , C09J123/02 , C09J123/08
Abstract: A heat seal material having a plurality of resin surfaces which are positioned face to face and can be heat-fused together, at least one of the resin surfaces being formed of a resin composition comprising (A) 30 to 85% by weight of low-density polyethylene having a density of 0.91 to 0.94 g/cm and a crystallinity of more than 40%, (B) 5 to 40% by weight of polypropylene, and (C) 10 to 40% by weight of a low-crystalline or substantially amorphous ethylene/alpha-olefin copolymer. f
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公开(公告)号:AT82732T
公开(公告)日:1992-12-15
申请号:AT88311841
申请日:1988-12-14
Applicant: MITSUI PETROCHEMICAL IND
Inventor: SUGI MASAHIRO , NAKAGAWA TAKASI
IPC: B32B27/32 , B65D17/40 , B65D65/40 , B65D77/38 , C08L23/06 , C08L23/08 , C08L23/12 , C09J123/02 , C09J123/08
Abstract: A heat seal material having a plurality of resin surfaces which are positioned face to face and can be heat-fused together, at least one of the resin surfaces being formed of a resin composition comprising (A) 30 to 85% by weight of low-density polyethylene having a density of 0.91 to 0.94 g/cm and a crystallinity of more than 40%, (B) 5 to 40% by weight of polypropylene, and (C) 10 to 40% by weight of a low-crystalline or substantially amorphous ethylene/alpha-olefin copolymer. f
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公开(公告)号:DE3376572D1
公开(公告)日:1988-06-16
申请号:DE3376572
申请日:1983-09-28
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TOKUNAGA TERUO , SUGI MASAHIRO
Abstract: Polyethylene synthetic pulp giving synthetic paper which may be heat-treated with a heating apparatus attached to a conventional papermaking machine. The polyethylene synthetic pulp comprises fibers of polyethylene which has an MFR (Melt Flow Ratio) of 0.1 to 3,000 g/10 min., and the portion with a low melting point thereof, which melts at a temperature of 95 DEG C or lower when measured with a DSC (Differential Scanning Calorimeter), is at least 20% by weight, preferably, 40% to 70%.
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公开(公告)号:CA2155016C
公开(公告)日:2005-10-25
申请号:CA2155016
申请日:1994-11-29
Applicant: MITSUI PETROCHEMICAL IND
Inventor: UEDA TAKASHI , MIZUNO AKIRA , KAWASAKI MASAAKI , FUKUOKA DAISUKE , KISO YOSHIHISA , TANIZAKI TATSUYA , HASHIMOTO MIKIO , SUGI MASAHIRO , TSUTSUI TOSHIYUKI
IPC: C08F210/06 , C08F210/08
Abstract: The novel propylene elastomer according to the invention contains (1) units derived from propylene in amounts of 50 to 95 % by mol and units derived from 1-butene in amounts of 5 to 50 % by mol, and has (2) triad tacticity (mm fraction), determined by the 13C-NMR spectrum (hexachlorobutadiene solution, based on tetramethylsilane), of not less than 90 %, (3) an intrinsic viscosity (in decalin at 135 .degree.C) of 0.1 to 12 dl/g, (4) a molecular weight distribution (Mw/Mn) of not more than 3 and (5) a randomness parameter B value of 1.0 to 1.5, preferably 1.0 to 1.3. In addition, the elastomer desirably has properties that (6) the elastomer has a melting point Tm of 60 to 140 .degree.C, and the melting point Tm and a 1-butene constituent unit content M (% by mol) in the elastomer satisfy the relation -2.6M + 130 .ltoreq. Tm .ltoreq. -2.3M + 155, and (7) a crystallinity C of the elastomer measured by X-ray diffractometry and the 1-butene constituent unit content M (a by mol) satisfy the relation C .gtoreq. -1.5M + 75. Such propylene elastomer is excellent in rigidity, heat resistance, scratch resistance, transparency, heat sealing properties and blocking resistance. The propylene elastomer can be prepared using a specific transition metal compound catalyst.
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公开(公告)号:DE3876223D1
公开(公告)日:1993-01-07
申请号:DE3876223
申请日:1988-12-14
Applicant: MITSUI PETROCHEMICAL IND
Inventor: SUGI MASAHIRO , NAKAGAWA TAKASI
IPC: B32B27/32 , B65D17/40 , B65D65/40 , B65D77/38 , C08L23/06 , C08L23/08 , C08L23/12 , C09J123/02 , C09J123/08
Abstract: A heat seal material having a plurality of resin surfaces which are positioned face to face and can be heat-fused together, at least one of the resin surfaces being formed of a resin composition comprising (A) 30 to 85% by weight of low-density polyethylene having a density of 0.91 to 0.94 g/cm and a crystallinity of more than 40%, (B) 5 to 40% by weight of polypropylene, and (C) 10 to 40% by weight of a low-crystalline or substantially amorphous ethylene/alpha-olefin copolymer. f
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公开(公告)号:AU628361B2
公开(公告)日:1992-09-17
申请号:AU3902589
申请日:1989-07-28
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TANAKA MUTSUHIRO , SUGI MASAHIRO
IPC: C08L23/08 , C08J5/18 , C08L23/00 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L23/18 , C08L53/00
Abstract: A propylene resin composition contains: (A) 50 to 99% by weight of a polypropylene resin, and (B) 1 to 50% by weight of a rubber component, and the rubber component (B) contains a random copolymer composition containing: (i) an ethylenic random copolymer selected from random copolymers of ethylene with an alpha -olefin having 3 to 20 carbon atoms having an ethylene content of 60 to 95 mol% and a MFR230 DEG C of 0.1 to 50 g/10 min. and (ii) a propylenic random copolymer selected from random copolymers of propylene with an -olefin having 2 to 20 carbon atoms except for propylene having a propylene content of 60 to 95 mol% and a MFR230 DEG C of 0.1 to 50 g/10 min., at a weight ratio of (i):(ii) of from 95:5 to 20:80.
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公开(公告)号:DE3778475D1
公开(公告)日:1992-05-27
申请号:DE3778475
申请日:1987-10-09
Applicant: MITSUI PETROCHEMICAL IND
Inventor: KIOKA MAMORU , KASHIWA NORIO , SUGI MASAHIRO , TOYOTA AKINORI
IPC: B32B27/32 , C08F210/06 , C08F210/16 , C08F2/00 , C08L23/14 , C08L23/16
Abstract: A novel low-crystalline propylene random copolymer composition comprising [I] 60 to 95 % by weight of a propylene random copolymer and [II] 5 to 40 % by weight of a low-crystalline propylene random copolymer which has excellent heat-sealability, heat-seal imparting property, transparency and antiblocking property and containing a reduced amount of a hydrocarbon-soluble component, a process for production thereof, and polypropylene composite laminated structure having improved heat-sealability and heat seal strength at low temperatures.
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公开(公告)号:CA2033053A1
公开(公告)日:1991-02-08
申请号:CA2033053
申请日:1990-08-07
Applicant: MITSUI PETROCHEMICAL IND
Inventor: SUGI MASAHIRO , TANAKA MUTSUHIRO
Abstract: A releasable protective film consists of (A) 85-20 wt.% of a random propylene-butene copolymer iwth a MFI of 0.1-100 g/10 minutes (ASTM D 1238-65T, 230 deg.C), a propylene content of 60-85 mol.% and a heat of crystal fusion of 20-80 Joule/g determined using a differential scanning calorimeter (B) 15-8 w.% of an ethylene-alpha olefin copolymer with a MFI of 0.1-100 g/10 minutes, an ethylene content of 75-95 mol.%, a crystallinity of 0-30%, and the alpha-olefin contains 3-10C atoms, and (C) 0-10 wt.% of a tackifier.
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公开(公告)号:CA1225802A
公开(公告)日:1987-08-25
申请号:CA437204
申请日:1983-09-21
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TOKUNAGA TERUO , SUGI MASAHIRO
Abstract: Disclosed is a novel polyethylene synthetic pulp giving synthetic paper which may be heat-treated with a heating apparatus attached to a conventional papermaking machine. The polyethylene synthetic pulp comprises fibers of polyethylene which has an MFR (Melt Flow Ratio) of 0.1 to 3,000 g/10 min., and the portion with a low melting point thereof, which melts at a temperture of 95.degree.C or lower when measured with a DSC (Differential Scanning Calorimeter), is at least 20% by weight, preferably, 40% to 70%.
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