公开(公告)号：CS200228B2

公开(公告)日：1980-08-29

申请号：CS671077

申请日：1977-10-14

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRID G ,  APPLEQUIST MICHAEL D

IPC: B01J23/28 ,  B01J23/54 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/19 ,  C07C51/25 ,  C07C57/055 ,  C07C57/04

公开(公告)号：CS199688B2

公开(公告)日：1980-07-31

申请号：CS671177

申请日：1977-10-14

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRID G

IPC: C07C57/04 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.

公开(公告)号：ATA466877A

公开(公告)日：1979-06-15

申请号：AT466877

申请日：1977-06-30

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  APPLEQUIST MICHAEL D

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/89 ,  B01J27/00 ,  B01J27/057 ,  B01J27/192 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04 ,  C07C51/26

公开(公告)号：DD133432A5

公开(公告)日：1979-01-03

申请号：DD20157677

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRID G

IPC: C07C57/04 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C51/26 ,  B01J21/00 ,  B01J23/00 ,  B01J27/16

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.

公开(公告)号：DD132490A5

公开(公告)日：1978-10-04

申请号：DD19974677

申请日：1977-06-28

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  APPLEQUIST MICHAEL D

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/89 ,  B01J27/00 ,  B01J27/057 ,  B01J27/192 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04 ,  B01J23/16 ,  B01J23/64 ,  B01J23/84 ,  C07C51/32

公开(公告)号：CA1144696A

公开(公告)日：1983-04-12

申请号：CA366032

申请日：1980-12-03

Applicant: STANDARD OIL CO OHIO

Inventor： BENTON KENNETH C ,  UEBELE CURTIS E ,  WHITE JAMES F ,  WEINERT RAYMOND J JR

IPC: C08F4/00 ,  C08F2/14 ,  C08F4/60 ,  C08F10/00 ,  C08F10/06 ,  C08F2/00

Abstract: This invention relates to a process for polymerizing alpha-olefins in the presence of a Ziegler-type catalyst wherein at least one of dichloroethane, dichloropropane and chlorine gas is added to the process after the polymerization has been initiated. This invention is especially useful when the olefin is propylene and the catalyst is a titanium trichloride complex.

公开(公告)号：RO73304A

公开(公告)日：1981-09-24

申请号：RO9187177

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WHITE JAMES F ,  MILBERGER ERNEST C

IPC: B01J27/192 ,  C07C51/215 ,  C07C51/25 ,  B01J23/28 ,  C07C57/14

Abstract: Maleic anhydride is produced by the oxidation of n-butane, n-butenes, 1,3-butadiene with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, bismuth, copper, oxygen, and a halogen selected from the group consisting of chlorine, bromine or iodine.

公开(公告)号：RO69967A

公开(公告)日：1981-05-15

申请号：RO8721576

申请日：1976-08-05

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J27/18 ,  B01J21/16 ,  B01J23/16 ,  B01J23/88 ,  B01J27/00 ,  B01J27/186 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00

Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.

公开(公告)号：AT359982B

公开(公告)日：1980-12-10

申请号：AT582976

申请日：1976-08-05

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J23/24 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J27/18

公开(公告)号：CS200531B2

公开(公告)日：1980-09-15

申请号：CS639978

申请日：1978-10-03

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WHITE JAMES F ,  MILBERGER ERNEST C

IPC: C07D307/60