Abstract:
The invention includes methods of making lithography photomask blanks. The invention also includes lithography photomask blanks and preforms for producing lithography photomask. The method of making a lithography photomask blank includes providing a soot deposition surface, producing SiO2 soot particles and projecting the SiO2 soot particles toward the soot deposition surface. The method includes successively depositing layers of the SiO2 soot particle on the deposition surface to form a coherent SiO2 porous glass preform body comprised of successive layers of the SiO2 soot particles and dehydrating the coherent SiO2 glass preform body to remove OH from the preform body. The SiO2 is exposed to and reacted with a fluorine containing compound and consolidated into a nonporous silicon oxyfluoride glass body with parallel layers of striae. The method further includes forming the consolidated silicon oxyfluoride glass body into a photomask blank having a planar surface with the orientation of the striae layer parallel to the photomask blank planar surface.
Abstract:
The present invention is a method of making a lithography photomask and photomask blank. The method of making the lithography photomask and photomask blank includes providing a silicon oxyfluoride glass tube having an OH content less than 50 ppm. The method further includes cutting the silicon oxyfluoride glass tube, flattening the silicon oxyfluoride glass tube, and forming the flattened cut silicon oxyfluoride glass tube into a photomask blank having a planar surface. The present invention includes a glass lithography mask preform. The glass lithography mask preform is a longitudinal silicon oxyfluoride glass tube that has an OH content ≤ 10 ppm, an F wt. % concentration ≥ 0.5 wt. %.
Abstract:
A synthetic quartz glass to be used for light with a wavelength of from 150 to 200 nm, wherein the OH group concentration is at most 100 ppm, the hydrogen molecule concentration is at most 1×10 17 molecules/cm 3 , reduction type defects are at most 1×10 15 defects/cm 3 , and the relation between Δk 163 and Δk 190 , as between before and after irradiation of ultraviolet rays, satisfies 0 163 190 , and a process for its production.
Abstract:
The invention relates to fluorine-containing silica glasses, and methods of their production. The silica glass may be used for an ultraviolet light optical system in which light in a wavelength region of 200 nm or less, such as an ArF (193nm) excimer laser, is used. The invention also relates to a projection exposure apparatus containing fluorine-containing glass of the invention.
Abstract:
A synthetic quartz glass optical member for an ultraviolet laser, suitably applicable as a stepper lens of a lithographer using an excimer laser beam and other optical members, wherein the quartz glass has a hydroxyl content of 10 to 100 ppm, a chlorine content of 200 ppm or less, a hydrogen content of 1 x 1016 molecules/cm3 or less, a homogeneity of refractive index of 5 x 10-6 or less in terms of Δn, and a birefringence of 5 nm/cm or less. The optical member can be produced by subjecting a volatile silicon compound to flame hydrolysis with oxyhydrogen flame, depositing the formed particulate silica on a heat-resistant support to prepare a porous silica matrix, heating the matrix in a vacuum as high as 1 x 10-2 Torr or above to a temperature of 1,400 °C or above to effect dehydration and degassing, homogenizing the resultant transparent quartz glass into highly homogeneous quartz glass free from striae in at least one direction, molding the highly homogeneous quartz glass, and annealing the molded glass.
Abstract:
Es wird ein Bauteil für die Übertragung von Licht hoher Energiedichte mit einer Wellenlänge zwischen 250 nm und 400 nm aus synthetischem, hochreinem Quarzglas beschrieben, bei dem zur Erzielung einer möglichst geringen Transmissionsänderung bei der Übertragung des Lichtes, das Quarzglas einen Hydroxylionengehalt im Bereich zwischen 50 ppm und 1200 ppm und einen unterstöchiometrischen Gehalt an Sauerstoff aufweist.
Abstract:
This invention relates to an optical member made of synthetic silica glass of high-purity and transparency, and a method for manufacture a blank thereof or the optical member, and more especially to optical members assembled in assembled in various apparatus employing such high-power laser beams as an excimer laser. The optical member comprising: having absolute refractive index, n d , of 1.460 or more, and having hydrogen molecule concentration of about 5 x 10¹⁶ molecules/cm³ or more.
Abstract:
The invention relates to a method for producing a silica glass article, involving method steps i.) providing a silica granulate, ii.) forming a glass melt from the silica granulate, and iii.) forming a silica glass article from at least some of the glass melt, step i.) consisting of steps I. producing a silica powder using at least two particles made from a silicon-chlorine compound, II. bringing the silica powder into contact with ammonia so as to obtain a treated silica powder, and III. granulating the treated silica powder so as to obtain a silica granulate, the chlorine content of the silica powder being higher than the chlorine content of the silica granulate. The invention further relates to a silica glass article that can be obtained by said method. The invention also relates to a method for producing a silica granulate. The invention finally relates to an optical waveguide, an illuminant and a molded article, each of which can be obtained by further processing the silica glass article.