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公开(公告)号：KR1020120076273A
公开(公告)日：2012-07-09
申请号：KR1020100138353
申请日：2010-12-29
Applicant: 제일모직주식회사
Abstract: PURPOSE: An environment-friendly crosslinkable polyphosphonate is provided to improve flame retardance by only small amount, and to impart excellent physical properties balance of flame retardance, thermal resistance, impact strength, appearance, etc. CONSTITUTION: An environment-friendly crosslinkable polyphosphonate contains a repeating unit in chemical formula 1. In chemical formula 1, Z is C1-C5 linear or branched alkyl, C5-C6 cycloalkyl, or C6-C20 aryl, Y is hydrogen, C1-C5 linear or branched alkyl, C5-C6 cycloalkyl, or C6-C20 aryl, X is C1-C5 linear or branched alkylene, C5-C6 cycloalkylene, or C6-C20 arylene, Q is a functional group in chemical formula 1-a. In chemical formula 1-a, A is a single bond, C1-C5 alkylene, C1-C5 alkylidene, C5-C6 cycloalkylidene, -S-, or -SO2-, R is a C1-C10 alkyl group, a C6-C20 aryl group, or a C6-C20 aryloxy group, and n is an integer from 5-2000, and m is an integer from 3-10.
Abstract translation: 目的：提供环保的交联性聚膦酸盐，以提高阻燃性，少量，并且具有优异的物理性能平衡阻燃性，耐热性，冲击强度，外观等。构成：环境友好型交联聚膦酸盐含有 化学式1中的Z为C1-C5直链或支链烷基，C5-C6环烷基或C6-C20芳基，Y为氢，C1-C5直链或支链烷基，C5-C6环烷基， 或C6-C20芳基，X是C1-C5直链或支链亚烷基，C5-C6亚环烷基或C6-C20亚芳基，Q是化学式1-a中的官能团。 在化学式1-a中，A是单键，C1-C5亚烷基，C1-C5亚烷基，C5-C6亚环烷基，-S-或-SO2-，R是C1-C10烷基，C6-C20 芳基或C 6 -C 20芳氧基，n为5〜2000的整数，m为3-10的整数。
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公开(公告)号：KR1020120071282A
公开(公告)日：2012-07-02
申请号：KR1020110028418
申请日：2011-03-29
Applicant: 제일모직주식회사
CPC classification number: C07F9/12 , C08K5/523 , C08L2201/02 , C08L2666/84 , C09K21/12
Abstract: PURPOSE: A novel phosphorus compound and a flame retardant thermoplastic resin composition containing the same are provided to enhance anti-hydrolysis property and thermal resistance. CONSTITUTION: A phosphorus compound is denoted by chemical formula 1. A method for preparing the phosphorus compound of chemical formula 1 comprises: a step of reacting phosphorus oxychloride and a compound of chemical formula 2; and a step of reacting a reactant with hydroquinone. A flame retardant thermoplastic resin composition contains 0.1-50 weight parts of the phosphorus compound and 100 weight part of thermoplastic resin. The thermoplastic resin is polycarbonate resin.
Abstract translation: 目的：提供一种新的磷化合物和含有它的阻燃热塑性树脂组合物，以提高抗水解性能和耐热性。 构成：化学式1表示磷化合物。化学式1的磷化合物的制备方法包括：使磷酰氯与化学式2化合物反应的工序; 以及使反应物与氢醌反应的步骤。 阻燃热塑性树脂组合物含有0.1-50重量份的磷化合物和100重量份的热塑性树脂。 热塑性树脂是聚碳酸酯树脂。
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33.发明公开중합형 인계 화합물을 포함하는 열가소성 수지 조성물, 상기 조성물로부터 성형된 플라스틱 성형품 및 중합형 인계 화합물의 제조방법 有权包含聚磷酸酯化合物的热塑性树脂组合物，其制造的塑料制品及其制备方法
公开(公告)号：KR1020110079480A
公开(公告)日：2011-07-07
申请号：KR1020100082354
申请日：2010-08-25
Applicant: 제일모직주식회사
CPC classification number: C08G79/04 , C08L51/04 , C08L55/02 , C08L69/00 , C08L85/02 , C08L2201/02 , C09K21/14 , C08L2666/02
Abstract: PURPOSE: A thermoplastic resin composition, a plastic molded article produced therefrom, and a method for preparing a polymerizable phosphorus-based compound are provided to ensure excellent flame retardancy, impact resistance, heat resistance, and fluidity. CONSTITUTION: A thermoplastic resin composition comprises: 100 wt % of a base resin including 30 to 100 wt % of a polycarbonate-based resin; and 0.1 to 40 wt % of a polymerizable phosphorus-based compound represented by chemical formula 1. In chemical formula 1, A is a single bond, C1-C5 alkylene, C1-C5 alkylidene, C5-C6 cycloalkylidene, -S- or -SO2-; R is C1-C20 aryl; and n is an integer of 4 - 500. The base resin comprises 30~100 weight% of a polycarbonate resin and 0~70 weight% of a rubber-modified aromatic vinyl polymer.
Abstract translation: 目的：提供一种热塑性树脂组合物，由其制造的塑料模塑制品和可聚合的磷基化合物的制备方法，以确保优异的阻燃性，耐冲击性，耐热性和流动性。 构成：热塑性树脂组合物包含：100重量％的基础树脂，其包含30至100重量％的聚碳酸酯基树脂; 在化学式1中，A为单键，C1-C5亚烷基，C1-C5亚烷基，C5-C6亚环烷基，-S-或 - SO2-; R是C 1 -C 20芳基; n为4〜500的整数。该基础树脂包含30〜100重量％的聚碳酸酯树脂和0〜70重量％的橡胶改性芳族乙烯基聚合物。
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公开(公告)号：KR1020100078561A
公开(公告)日：2010-07-08
申请号：KR1020080136857
申请日：2008-12-30
Applicant: 제일모직주식회사
Abstract: PURPOSE: A non-halogen flame-retarding polycarbonate resin composition is provided to secure the stability to the fire, and to prevent the environmental contamination by avoid using a halogen based flame retardant. CONSTITUTION: A non-halogen flame-retarding polycarbonate resin composition contains the following: 100 parts of base resin by weight formed with 50~100wt% of polycarbonate resin, and 0~50wt% of rubber-modified styrenic resin; 0.5~20 parts of cyclic benzyl phosphonate compound by weight marked with chemical formula 1; and 0~20 parts of aromatic phosphate ester compound by weight. In the chemical formula 1, R1, R1`, R2, and R2` are hydrogen, a C1~C8 alkyl group, a C6~C20 aryl group, or a C1~C8 alkyl-substituted C6~C20 aryl group.
Abstract translation: 目的：提供无卤阻燃聚碳酸酯树脂组合物以确保火灾的稳定性，并且通过避免使用卤素类阻燃剂来防止环境污染。 构成：无卤阻燃聚碳酸酯树脂组合物含有：由50〜100重量％的聚碳酸酯树脂形成的100重量份的基础树脂和0〜50重量％的橡胶改性苯乙烯树脂; 0.5〜20份以化学式1表示的重量的环状苄基膦酸酯化合物; 和0〜20份重量的芳族磷酸酯化合物。 在化学式1中，R 1，R 1，R 2和R 2'是氢，C 1〜C 8烷基，C 6〜C 20芳基或C 1〜C 8烷基取代的C 6〜C 20芳基。
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公开(公告)号：KR1020100075184A
公开(公告)日：2010-07-02
申请号：KR1020080133816
申请日：2008-12-24
Applicant: 제일모직주식회사
IPC: C08K3/10 , C08L101/00
CPC classification number: C08K3/10 , C08K3/30 , C08K5/0066 , C08L55/02 , C08L69/00 , C08L71/00 , C08L101/00 , C08L2201/02
Abstract: PURPOSE: A flameproof thermoplastic resin composition is provided to secure the environment-friendly property of the composition by using an environment-friendly compound instead of a halogen based flame retardant, or a phosphate flame retardant. CONSTITUTION: A flameproof thermoplastic resin composition contains 100 parts of thermoplastic resin by weight, and 0.1~40 parts of selenium based flame retardant by weight. A thermoplastic resin is selected from the group consisting of an aromatic vinyl resin, a rubber modified aromatic vinyl resin, a polyphenylene resin, a polycarbonate resin, a polyester resin, a methacrylate resin, a polyarylene sulfide resin, a polyamide resin, a polyvinylchloride resin, a polyolefin resin, and their compound.
Abstract translation: 目的：提供一种防火热塑性树脂组合物，以通过使用环境友好的化合物代替卤素阻燃剂或磷酸酯阻燃剂来确保组合物的环境友好性。 构成：防火热塑性树脂组合物含有100重量份的热塑性树脂，和0.1-40重量份的基于硒的阻燃剂。 热塑性树脂选自芳族乙烯基树脂，橡胶改性芳族乙烯基树脂，聚苯醚树脂，聚碳酸酯树脂，聚酯树脂，甲基丙烯酸酯树脂，聚芳硫醚树脂，聚酰胺树脂，聚氯乙烯树脂 ，聚烯烃树脂及其化合物。
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Patent Agency Ranking
公开(公告)号：KR1020100075172A
公开(公告)日：2010-07-02
申请号：KR1020080133801
申请日：2008-12-24
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided for molding electrical/electronic material with improved heat resistance, and to secure the environment-friendly property of the composition. CONSTITUTION: A thermoplastic resin composition with improved fire retardant property contains the following: 30~100 parts of polycarbonate resin by weight; 0~70 parts of rubber-modified aromatic vinyl polymer by weight; and 0.1~40 parts of boron-based compound by weight marked as chemical formula 2, for 100 parts of base resin by weight including the polycarbonate resin and the rubber-modified aromatic vinyl polymer. In the chemical formula 2, R1, R2, and R3 are an amine group, a sulfone group, a hydroxyl group, a phenol group, a phenyl group, an alkyl group of C1~C10, and others, respectively.
Abstract translation: 目的：提供热塑性树脂组合物，用于模塑具有改善的耐热性的电气/电子材料，并确保组合物的环境友好性。 构成：具有改善阻燃性能的热塑性树脂组合物包含以下物质：30〜100重量份的聚碳酸酯树脂; 橡胶改性芳族乙烯基聚合物重量为0〜70份; 和0.1〜40份以化学式2表示的重量的硼基化合物，对于100重量份的包含聚碳酸酯树脂和橡胶改性的芳族乙烯基聚合物的基础树脂。 在化学式2中，R1，R2和R3分别是胺基，砜基，羟基，苯酚基，苯基，C1〜C10的烷基等。
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公开(公告)号：KR100890901B1
公开(公告)日：2009-04-03
申请号：KR1020070138422
申请日：2007-12-27
Applicant: 제일모직주식회사
Abstract: A flameproof styrene-based resin composition having phosphorus-based compounds as a flame retardant is provided to ensure excellent chemical resistance and flame retardancy by applying the phosphorus-based compounds to a blend of styrene-based copolymer, polyphenylene ether resin and polyethylene terephthalate resin. A flameproof styrene-based resin composition having phosphorus-based compounds as a flame retardant comprises a 100 part of base resin and 1~30 part of one or more phosphorus-based compounds selected from the group consisting of alkyl phosphinic acid metal salt compounds and aromatic phosphoric acid ester compounds by weight. The base resin contains 40~98wt% of styrene-based resin, 1~30wt% of polyphenylene ether resin, and 1~30wt% of polyethylene terephthalate resin.
Abstract translation: 提供具有磷系化合物作为阻燃剂的防火苯乙烯类树脂组合物，以通过将苯基类共聚物，聚苯醚树脂和聚对苯二甲酸乙二醇酯树脂的共混物施用于磷系化合物来确保优异的耐化学性和阻燃性。 具有磷基化合物作为阻燃剂的防火苯乙烯类树脂组合物包括100份基础树脂和1〜30份选自烷基次膦酸金属盐化合物和芳族化合物的一种或多种磷基化合物 磷酸酯化合物。 基础树脂含有苯乙烯系树脂40〜98重量％，聚苯醚树脂1〜30重量％，聚对苯二甲酸乙二醇酯树脂1〜30重量％。
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公开(公告)号：KR100829446B1
公开(公告)日：2008-05-15
申请号：KR1020060135995
申请日：2006-12-28
Applicant: 제일모직주식회사
IPC: C08F230/02 , C08F212/04 , C08F212/08 , C08J3/22
CPC classification number: C08F230/02 , C08F212/10 , C08J3/22 , C08L25/12
Abstract: A phosphorus-aromatic vinyl compound copolymer is provided to avoid the use of a char-forming agent in imparting flame resistance to a resin composition, to prevent a drop in heat resistance of a thermoplastic resin, and to impart excellent flame resistance to a thermoplastic resin composition. A phosphorus-aromatic vinyl compound copolymer is obtained by polymerizing: elemental phosphorus; an aromatic vinyl monomer; and a monomer selected from the group consisting of a crosslinking agent selected from divinyl benzene, multi-functional aromatic vinyl compounds, triallyl isocyanurate, multifunctional mercaptan, multifunctional peroxide and a mixture thereof, a unsaturated nitrile monomer and a mixture thereof.
Abstract translation: 提供了一种磷 - 芳族乙烯基化合物共聚物，以避免使用成炭剂赋予树脂组合物阻燃性，防止热塑性树脂的耐热性降低，并赋予热塑性树脂优异的阻燃性 组成。 通过聚合形成磷 - 芳族乙烯基化合物共聚物：元素磷; 芳族乙烯基单体; 和选自二乙烯基苯，多官能芳族乙烯基化合物，三烯丙基异氰脲酸酯，多官能硫醇，多官能过氧化物及其混合物的交联剂，不饱和腈单体及其混合物的单体。
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公开(公告)号：KR100778008B1
公开(公告)日：2007-11-28
申请号：KR1020060134617
申请日：2006-12-27
Applicant: 제일모직주식회사
Abstract: A flame retardant styrene-based resin composition, a pellet obtained by extruding the composition, and an exterior material of an electronic device molded from the composition are provided to improve the balance of physical properties such as heat resistance and workability and to obtain excellent flame retardancy even by using a small amount of a flame retardant. A flame retardant styrene-based resin composition comprises 100 parts by weight of a base resin which comprises 50-99 wt% of a styrene-based resin and 1-50 wt% of a polyphenylene ether resin; and 0.1-30 parts by weight of a phosphonium-based compound represented by the formula 1, wherein R1 is a C1-C6 alkyl group, an aryl group, or a C1-C6 alkyl group having a carboxyl group at terminal; and X is a halogen atom.
Abstract translation: 提供阻燃苯乙烯基树脂组合物，通过挤出组合物获得的颗粒和由组合物模制的电子器件的外部材料，以改善诸如耐热性和加工性的物理性能的平衡，并获得优异的阻燃性 即使使用少量的阻燃剂。 阻燃苯乙烯类树脂组合物包含100重量份的基础树脂，其包含50-99重量％的苯乙烯基树脂和1-50重量％的聚苯醚树脂; 和0.1-30重量份由式1表示的鏻基化合物，其中R 1是C 1 -C 6烷基，芳基或在末端具有羧基的C 1 -C 6烷基; X为卤素原子。
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公开(公告)号：KR101489956B1
公开(公告)日：2015-02-06
申请号：KR1020110147917
申请日：2011-12-30
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 방향족 비닐계 수지 및 폴리페닐렌 옥사이드 수지를 포함하는 기초수지 100 중량부; 및 하기 화학식 1로 표시되는 폴리포스포네이트 공중합체 0.1 내지 30 중량부를 포함한다:
[화학식 1]
(상기 식에서, A 및 B는 각각 독립적으로 단일 결합, C
1 -C
5 의 알킬렌, C
1 -C
5 의 알킬리덴, C
5 -C
6 의 시클로알킬리덴, -S- 또는 -SO2-이고, 단, A 및 B는 서로 동일하지 않으며, R5 및 R6은 각각 독립적으로 치환 또는 비치환된 C
1 -C
6 알킬기, 치환 또는 비치환된 C
6 -C
20 인 아릴기 또는 C
6 -C
20 인 치환 또는 비치환된 아릴옥시기이고, R1, R2, R3 및 R4는 각각 독립적으로 치환 또는 비치환된 C
1 -C
6 알킬기, 치환 또는 비치환된 C
3 -C
6 사이클로알킬기, 치환 또는 비치환된 C
6 -C
12 아릴기 또는 할로겐 원자이며, a 및 b는 각각 독립적으로 0 내지 4의 정수, n 및 m은 1 내지 500의 정수임).
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