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    Zpusob kontinuální výroby hydroxylamonných solí
    31.
    发明专利
    Zpusob kontinuální výroby hydroxylamonných solí 未知

    公开(公告)号：CZ303428B6

    公开(公告)日：2012-09-12

    申请号：CZ20031626

    申请日：2001-12-12

    Applicant: BASF AG

    Inventor： BENDER MICHAEL ,  WILFINGER HANS JOERG ,  SCHENKEL ALBERT

    IPC: C01B21/00 ,  C01B21/14

    Abstract: Zpusob kontinuální výroby hydroxylamonných solí katalytickou redukcí oxidu dusnatého s vodíkem ve zredeném vodnatém roztoku minerální soli ve více za sebou zarazených reakcních stupních spocívá v tom, že prítok zredeného vodnatého roztoku minerální kyseliny se pred prívodem do více za sebou zarazených reakcních stupnu rozdelí na alespon dva dílcí proudy, první z uvedených dílcích proudu se zavede do prvního reakcního stupne, druhý z uvedených dílcích proudu se zavede do jiného než prvního reakcního stupne, pricemž se prítok zredeného vodného roztoku minerální kyseliny do více za sebou zarazených reakcních stupnu rídí pomocí hodnoty pH tohoto jiného než prvního reakcního stupne.

    PROCEDIMIENTO PARA LA OBTENCION CONTINUA DE SALES DE HIDROXILAMONIO.
    34.
    发明专利
    PROCEDIMIENTO PARA LA OBTENCION CONTINUA DE SALES DE HIDROXILAMONIO. 未知

    公开(公告)号：ES2225630T3

    公开(公告)日：2005-03-16

    申请号：ES01985870

    申请日：2001-12-12

    Applicant: BASF AG

    Inventor： BENDER MICHAEL ,  WILFINGER HANS JORG ,  SCHENKEL ALBERT

    IPC: C01B21/00 ,  C01B21/14

    Abstract: Procedimiento para la obtención continua de sales de hidroxilamonio mediante reducción catalítica de monóxido de nitrógeno con hidrógeno en disolución acuosa diluida de ácido mineral, en varias etapas de reacción conectadas en serie, caracterizado porque se divide el flujo de disolución acuosa diluida de ácido mineral en al menos dos corrientes parciales antes de la alimentación en las diversas etapas de reacción conectadas en serie, se alimenta a una primera de las citadas corrientes parciales a la primera etapa de reacción, se alimenta a una segunda de las citadas corrientes parciales a una etapa de reacción diferente a la primera, controlándose el flujo de disolución acuosa diluida de ácido mineral en las diversas etapas de reacción conectadas entre sí por medio del valor de pH de esta etapa de reacción diferente a la primera.

    INTEGRATED METHOD FOR SYNTHESISING PROPYLENE OXIDE
    36.
    发明专利
    INTEGRATED METHOD FOR SYNTHESISING PROPYLENE OXIDE 未知

    公开(公告)号：AU2003266329A1

    公开(公告)日：2004-03-19

    申请号：AU2003266329

    申请日：2003-08-29

    Applicant: BASF AG

    Inventor： MULLER ULRICH ,  HARTH KLAUS ,  SCHINDLER GOTZ-PETER ,  JUNICKE HENRIK ,  BENDER MICHAEL ,  ZEHNER PETER ,  MACHHAMMER OTTO

    IPC: C07D301/12

    Abstract: The present invention relates to an integrated process for the synthesis of propylene oxide, which comprises at least the following steps: (i) dehydrogenation of propane to give a substream T( 0 ) comprising at least propane, propene and hydrogen; (ii) fractionation of the substream T( 0 ) to give at least one gaseous hydrogen-rich substream T( 2 ) and a substream T( 1 ) comprising at least propene and propane; (iii) synthesis of hydrogen peroxide using the substream T( 2 ), giving a substream T ( 4 ) which is rich in hydrogen peroxide and a gaseous substream T( 6 ); (iv) fractionation of the substream T( 1 ) to give at least one propane-rich substream T( 5 ) and at least one propene-rich substream T( 3 ); (v) reaction of the at least one substream T( 3 ) with substream T( 4 ) to give propylene oxide.

    Continuous preparation process of hydroxyl ammonium salts
    37.
    发明专利
    Continuous preparation process of hydroxyl ammonium salts 未知

    公开(公告)号：CZ20031626A3

    公开(公告)日：2003-10-15

    申请号：CZ20031626

    申请日：2001-12-12

    Applicant: BASF AG

    Inventor： BENDER MICHAEL ,  WILFINGER HANS JORG ,  SCHENKEL ALBERT

    IPC: C01B21/00 ,  C01B21/14

    Abstract: A process for the continuous preparation of hydroxylammonium salts by catalytic reduction of nitrogen monoxide by means of hydrogen in a dilute aqueous solution of mineral acid in a plurality of reaction stages connected in series comprises dividing the incoming stream of dilute aqueous solution of mineral acid into at least two substreams before it is fed into the plurality of reaction stages connected in series, feeding a first of these substreams to the first reaction stage, feeding a second of these substreams to a reaction stage other than the first, where the inflow of dilute aqueous solution of mineral acid into the plurality of reaction stages connected in series is controlled by means of the pH in this reaction stage other than the first.

    38.
    发明专利
    未知

    公开(公告)号：BR0116095A

    公开(公告)日：2003-10-14

    申请号：BR0116095

    申请日：2001-12-12

    Applicant: BASF AG

    Inventor： BENDER MICHAEL ,  WILFINGER HANS J RG ,  SCHENKEL ALBERT

    IPC: C01B21/00 ,  C01B21/14

    Abstract: A process for the continuous preparation of hydroxylammonium salts by catalytic reduction of nitrogen monoxide by means of hydrogen in a dilute aqueous solution of mineral acid in a plurality of reaction stages connected in series comprises dividing the incoming stream of dilute aqueous solution of mineral acid into at least two substreams before it is fed into the plurality of reaction stages connected in series, feeding a first of these substreams to the first reaction stage, feeding a second of these substreams to a reaction stage other than the first, where the inflow of dilute aqueous solution of mineral acid into the plurality of reaction stages connected in series is controlled by means of the pH in this reaction stage other than the first.

    39.
    发明专利
    未知

    公开(公告)号：DE10157916A1

    公开(公告)日：2003-06-05

    申请号：DE10157916

    申请日：2001-11-26

    Applicant: BASF AG

    Inventor： BENDER MICHAEL ,  WESSEL HELGE

    IPC: B22F9/00 ,  B01J13/00 ,  B01J23/40 ,  B01J31/06 ,  B01J35/00 ,  C01B15/023 ,  C01B15/029 ,  H01M4/86 ,  H01M4/88 ,  H01M4/92 ,  H01M4/96 ,  H01M8/1007 ,  C01B15/01

    Abstract: Colloid with precious metal particles having surface oxidation-insensitive sulfonic or phosphonic acid groups derived from a coordinate polymer selected from sulfonated (partially) fluorinated polystyrene or alkylene/styrene copolymer, perfluorinated alkylene/alkylene oxide, polystyrene, polyarylene oxide, polyarylene ether sulfone, polyarylene ether ketone, polyphenylene or polyphenylene sulfide; or phosphonated arylene oxide or polybenzimidazole. Independent claims are also included for the following: (1) a solution containing the colloid; (2) a method of preparing the colloid solution in which precious metals salt(s) are reacted with reducing agent(s) in the presence of the oxidation-insensitive stabilizing polymer(s); (3) a precious metal heterogeneous catalyst containing the precious metal colloid and a support.

    40.
    发明专利
    未知

    公开(公告)号：DE10130828A1

    公开(公告)日：2003-01-16

    申请号：DE10130828

    申请日：2001-06-27

    Applicant: BASF AG

    Inventor： WESSEL HELGE ,  BENDER MICHAEL ,  HARTH KLAUS ,  FISCHER ANDREAS ,  HOELZLE MARKUS

    IPC: H01M4/86 ,  H01M4/90 ,  H01M8/0662 ,  H01M8/1004 ,  H01M8/1007

    Abstract: Fuel cell (1) comprises two electrodes (2) and an ion exchange membrane (6). The electrodes each have an electro-catalytic layer (4) and a gas feed for a reaction gas (7). The electro-catalytic layers each contain a standard catalyst. The fuel cell further contains an additive that prevents the formation of peroxides and/or decomposes peroxides. Preferred Features: The additive is an element or compound of a metallic transition element or group IVa element, preferably cobalt (Co), iron (Fe), chromium (Cr), manganese (Mn), copper (Cu), vanadium (V), ruthenium (Ru), palladium (Pd), nickel (Ni), molybdenum (Mo), tin (Sn) or tungsten (W). The element or compound is supported on a carrier material selected from carbon, silica (SiO2), alumina (Al2O3), zeolite or hetero-poly acids.

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