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    FUEL CELL
    1.
    发明专利
    FUEL CELL 审中-公开

    公开(公告)号：JP2003086188A

    公开(公告)日：2003-03-20

    申请号：JP2002187424

    申请日：2002-06-27

    Applicant: BASF AG

    Inventor： WESSEL HELGE ,  BENDER MICHAEL ,  HARTH KLAUS ,  FISCHER ANDREAS ,  HOELZLE MARKUS

    IPC: H01M4/86 ,  H01M4/90 ,  H01M8/0662 ,  H01M8/1004 ,  H01M8/1007 ,  H01M8/10

    Abstract: PROBLEM TO BE SOLVED: To eliminate the adverse effects of peroxides generated at the cathode of a fuel cell. SOLUTION: The fuel cell 1 has two electrodes 2 and an ion-exchange membrane 6, with each of the electrodes 2 having an electrode catalyst layer 4 and at least one gas passage for a reaction gas 7. The fuel cell contains at least one kind of additive that works to prevent formation of peroxides and/or decompose peroxides. A method is disclosed for using at least one kind of additive inside or over the electrode 2 of the fuel cell 1 having the ion- exchange membrane 6, the electrode catalyst layer 4, and the electrode 2 having at least one gas flow passage for the reaction gas 7. The at least one kind of additive works to prevent formation of and/or decompose peroxides inside or over the electrode 2.

    METHOD OF PRODUCING GLYOXAL DIACETAL
    2.
    发明专利
    METHOD OF PRODUCING GLYOXAL DIACETAL 审中-公开

    公开(公告)号：JP2003176248A

    公开(公告)日：2003-06-24

    申请号：JP2002290014

    申请日：2002-10-02

    Applicant: BASF AG

    Inventor： HEYDRICH GUNNAR ,  AUST NICOLA CHRISTIANE ,  PUTTER HERMANN ,  FISCHER ANDREAS ,  BOTZEM JOERG

    IPC: C07B61/00 ,  C07C41/50 ,  C07C43/303 ,  C07C47/198

    Abstract: PROBLEM TO BE SOLVED: To provide a method of producing glyoxal diacetal that uses a water- miscible alcohol and permits the continuous operation in high yield. SOLUTION: The reaction of 40-75 wt.% of glyoxal aqueous solution with a monohydric alcohol is carried out in the presence of an acid catalyst to produce a glyoxal diacetal. In this case, a liquid mixture including the alcohol and glyoxal in at least 15:1 molar ratio and water in an amount of ≤8 wt.% at the start of the reaction is brought into contact with an acid catalyst so that the alcohol used may not be distilled off over 5 wt.% until the concentration of the diacetal formed in the reaction mixture attains at least 70% of the equilibrium concentration. COPYRIGHT: (C)2003,JPO

    FUEL CELL
    4.
    发明专利
    FUEL CELL 失效

    公开(公告)号：JP2001143724A

    公开(公告)日：2001-05-25

    申请号：JP2000313809

    申请日：2000-10-13

    Applicant: BASF AG

    Inventor： PUETTER HERMANN DR ,  FISCHER ANDREAS

    IPC: H01M4/86 ,  H01M8/04089 ,  H01M8/04276 ,  H01M8/08 ,  H01M8/083 ,  H01M8/02

    Abstract: PROBLEM TO BE SOLVED: To substantially promote cost performance and efficiency of a current fuel cell by providing a proper transportation means and separator means of gas. SOLUTION: In the case where a fuel cell comprises at least following elements; a) each of two electrode comprising at least one gas flow channels for reaction gas and b) a liquid electrolyte, each of the gas flow channel of each electrode has at least one inlet and is vertically extended for a movement direction of ion under specified electric charge according to the arrangement of electrode.

    METHOD FOR PRODUCING ALCOXYLATED CARBONYL COMPOUNDS BY AN ANODIC OXIDATION METHOD USING A CATHODIC COUPLED REACTION FOR ORGANIC SYNTHESIS
    7.
    发明申请
    METHOD FOR PRODUCING ALCOXYLATED CARBONYL COMPOUNDS BY AN ANODIC OXIDATION METHOD USING A CATHODIC COUPLED REACTION FOR ORGANIC SYNTHESIS 审中-公开
    PROCESS FOR烷氧基化由阳极氧化法UNDER阴极KOPPEL反应在有机合成中使用的制备羰基

    公开(公告)号：WO0242524A2

    公开(公告)日：2002-05-30

    申请号：PCT/EP0113587

    申请日：2001-11-22

    Applicant: BASF AG ,  PUETTER HERMANN ,  FISCHER ANDREAS

    Inventor： PUETTER HERMANN ,  FISCHER ANDREAS

    IPC: C25B3/02 ,  C25B3/00

    CPC classification number: C25B3/00

    Abstract: A method for producing alcoxylated carbonyl compounds of general formula (I) (compounds I): R aR C(OR )b wherein R , R represent hydrogen or C1- C6-alkyl, R independently means C1- C6-alkyl, a is 0 or 1, b 2 or 3 with the proviso that the sum of a and b is 3, by means of anodic oxidation of germinal dialcoxy compounds of general formula (II) (compounds II) wherein R , R , R , R represent hydrogen or C1- C6-alkyl, R , R represent C1- C6-alkyl or C1- C6-alcoxy, in the presence of a C1-C6-alkyl alcohol (compounds III).A usual compound (compound IV) is used as a cathodic depolarizer suitable for electrochemical oxidation. The anodic oxidation and cathodic reduction is carried out in an undivided electrolyte cell in the presence of C1-C6-alkyl alcohols.

    Abstract translation: 一种生产通式（I）的烷氧基​​化的羰基化合物的方法（I化合物）：R <1> AR <2> C（OR <3>）b式中[R <1>，R <2>是氢或C 1 -C -C 6 - 烷基，R <3>彼此独立地C1-C6烷基，a是0或1，b 2或3，条件是a和b的总和为3，由通式的偕二烷氧基化合物的阳极氧化 （II）（化合物II），其中R <4>，R <5> - [R <6> - [R <7>是氢或C1-C6烷基，R <5> - [R <6>的C1至C6 在C1的存在下C6烷基醇或烷基C1至C6烷氧基（化合物III），被用作消偏振镜一个常规有机化合物（化合物IV）阴极，其适合用于电化学氧化和得到 阳极氧化和在未分割的电解槽的阴极还原在C1-C6烷基醇执行的存在。

    METHOD FOR PRODUCING ORTHOCARBONIC ACID TRIALKYL ESTERS
    8.
    发明申请
    METHOD FOR PRODUCING ORTHOCARBONIC ACID TRIALKYL ESTERS 审中-公开
    用于生产ORTHOCARBONSÄURETRIALKYLESTERN

    公开(公告)号：WO0220446A8

    公开(公告)日：2003-04-24

    申请号：PCT/EP0110216

    申请日：2001-09-05

    Applicant: BASF AG ,  FISCHER ANDREAS ,  PUETTER HERMANN

    Inventor： FISCHER ANDREAS ,  PUETTER HERMANN

    IPC: C07C43/32 ,  C25B3/02

    CPC classification number: C25B3/02

    Abstract: The invention relates to a method for producing orthocarbonic acid trialkyl esters by electrochemical oxidation of alpha-beta-diketones or alpha-beta-hydroxy ketones in the presence of C1-to C4-alcohols (alcohol A), the keto function being present in the form of a ketal function derived from C1- to C4-alykl alcohols and the hydroxyl function being optionally in the form of an ether function derived from C1- to C4-alykl alcohols (ketal K). The molar ratio of the ketal K to the alcohols A in the electrolytes is 0.2:1 to 10:1.

    Abstract translation: 一种通过α-β-二酮或α-β-羟基酮，在的形式从C1-缩酮官能和羟基官能团任选地在C1至C4的形式衍生C4烷基醇酮官能的电化学氧化制备Orthocarbonsäuretrialkylestern过程 烷基醇的醚官能团的情况下（缩酮K），在C1至C4醇（醇A）的存在下，在电解质中，缩酮K的摩尔比醇甲0.2：1：1至10度。

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