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    METHOD FOR THE PRODUCTION OF DEFINED MIXTURES OF THF, BDO AND GBL BY GAS PHASE HYDROGENATION
    1.
    发明申请
    METHOD FOR THE PRODUCTION OF DEFINED MIXTURES OF THF, BDO AND GBL BY GAS PHASE HYDROGENATION 审中-公开
    PROCESS FOR通过气相氢化PRODUCING DEFINED MIXTURES FROM THF，BDO和GBL

    公开(公告)号：WO2005058853A3

    公开(公告)日：2005-08-04

    申请号：PCT/EP2004013811

    申请日：2004-12-04

    Applicant: BASF AG ,  ROESCH MARKUS ,  PINKOS ROLF ,  HESSE MICHAEL ,  SCHLITTER STEPHAN ,  JUNICKE HENRIK ,  SCHUBERT OLGA ,  WECK ALEXANDER ,  WINDECKER GUNTHER

    Inventor： ROESCH MARKUS ,  PINKOS ROLF ,  HESSE MICHAEL ,  SCHLITTER STEPHAN ,  JUNICKE HENRIK ,  SCHUBERT OLGA ,  WECK ALEXANDER ,  WINDECKER GUNTHER

    IPC: C07D307/08 ,  C07D307/33 ,  C07D307/32

    CPC classification number: C07D307/33 ,  C07D307/08

    Abstract: The invention relates to a method for variable production of mixtures of optionally alkyl-substituted BDO, GBL and THF by two-stage hydrogenation in the gaseous phase of C4-dicarboxylic acids and/or the derivatives thereof, characterized in that a) a gas flow of C4-dicarboxylic acids and/or the derivatives thereof is hydrogenated in a first stage in the gaseous phase on a catalyst at a pressure of 2-100 bars and at a temperature of 200 DEG C to 300 DEG C in a first reactor in the presence of a catalyst in the form of catalyst moulded bodies with a volume of less than 20 mm3, consisting of 5 - 95 wt. % Cu-oxide and 5 - 95 wt. % of an oxide with acid centres in order to form a flow maintly consisting of optionally aryl-substituted GBL and THF, b) succinic anhydride optionally arising therefrom is separated by partial condensation, c) the products THF, water and GBL which remain predominantly in the gaseous phase during said partial condensation are reacted at the same pressure or at a pressure which is reduced in order to reduce flow losses in the hydrogenation circuit at a temperature of 150 to 240 DEG C in a second reactor on a catalyst of > 95 wt. % CuO and 5 to 95 wt. % of one or several oxides selected from the group consisting of ZnO, Al2O3, SiO2, TiO2, ZrO2, CeO2, MgO, CaO, SrO, BaO, La2O3, and Mn2O3 in order to form a mixture consisting of a flow containing BDO, GBL and THF, d) the hydrogen is separated from the products and returned to the hydrogenation, e) the products THF, BDO, GBL and Wasser are separated in a distillatory manner, a flow rich in GBL is optionally returned to the second reactor or is optionally removed therefrom and BDO, THF and GBL are processed in a distillatory manner, and the ratio of the products THF, GBL and BDO is adjusted in relation to each other in the region of 10 to 100 wt. % THF, 0 to 90 wt. % GBL and 0 to 90 wt. % BDO exclusively by varying the temperatures in the two hydrogenation areas, in addition to that of the GBL return flow.

    Abstract translation: 本发明是一种用于在C4二羧酸和/或其衍生物的气相中的可变生产任选烷基取代的BDO，GBL的混合物，和THF通过两步氢化的方法中，在气相中的第一步骤a），其特征在于 以2至100巴的压力下的C4二羧酸和/或它们的衍生物的气体流过催化剂和200℃，在催化剂中的催化剂成型体的小的体积为一体的形式存在的温度〜300℃在第一反应器 20立方毫米，所述重量％Cu氧化物和氢化5至95重量具有酸性位点的主要来自任选烷基取代的GBL和THF电流含，b）可以通过琥珀酸酐得到的5至95，C的部分冷凝分离的氧化物％ ）在等于OD在气相产物THF，水和GBL通过部分冷凝保留了大部分 它超过= 95重量％的CuO的催化剂和5内流动损失在氢化电路减压和150至240℃的温度下在第二反应器至95重量选自氧化锌的一种或多种氧化物的％ 氧化铝，二氧化硅，二氧化钛，氧化锆，氧化铈，氧化镁，氧化钙，SRO，BaO的，镧，并流至BDO，GBL的混合物，以及含有的Mn2O3 THF反应。 d）分离从产物中的氢和再循环到氢化，E）产品THF，BDO，GBL和通过蒸馏分离水，GBL富流至第二反应器返回任选或任选ausschleust和BDO，THF和GBL后处理通过蒸馏 ，并在10〜彼此只通过在两个氢化区不同的温度THF，GBL和BDO的产物比例为100重量％THF，0至90重量GBL的％，和0至90重量％BDO 和任选的再循环流GBL被设置。

    4.
    发明专利
    未知

    公开(公告)号：AT328876T

    公开(公告)日：2006-06-15

    申请号：AT03790944

    申请日：2003-08-29

    Applicant: BASF AG

    Inventor： BENDER MICHAEL ,  ZEHNER PETER ,  MACHHAMMER OTTO ,  MUELLER ULRICH ,  HARTH KLAUS ,  SCHINDLER GOETZ-PETER ,  JUNICKE HENRIK

    IPC: C07D301/12

    Abstract: The present invention relates to an integrated process for the synthesis of propylene oxide, which comprises at least the following steps: (i) dehydrogenation of propane to give a substream T( 0 ) comprising at least propane, propene and hydrogen; (ii) fractionation of the substream T( 0 ) to give at least one gaseous hydrogen-rich substream T( 2 ) and a substream T( 1 ) comprising at least propene and propane; (iii) synthesis of hydrogen peroxide using the substream T( 2 ), giving a substream T ( 4 ) which is rich in hydrogen peroxide and a gaseous substream T( 6 ); (iv) fractionation of the substream T( 1 ) to give at least one propane-rich substream T( 5 ) and at least one propene-rich substream T( 3 ); (v) reaction of the at least one substream T( 3 ) with substream T( 4 ) to give propylene oxide.

    INTEGRATED PROCESS FOR THE SYNTHESIS OF PROPYLENE OXIDE
    6.
    发明专利
    INTEGRATED PROCESS FOR THE SYNTHESIS OF PROPYLENE OXIDE 未知

    公开(公告)号：CA2496954A1

    公开(公告)日：2004-03-11

    申请号：CA2496954

    申请日：2003-08-29

    Applicant: BASF AG

    Inventor： JUNICKE HENRIK ,  SCHINDLER GOTZ-PETER ,  HARTH KLAUS ,  MULLER ULRICH ,  MACHHAMMER OTTO ,  ZEHNER PETER ,  BENDER MICHAEL

    IPC: C07D301/12

    Abstract: The invention relates to an integrated method for synthesising propylene oxide, said method comprising at least the following steps: (i) dehydrogenation of propane to obtain a partial stream T (0), which contains at least propane, propene and hydrogen; (ii) separation of the partial stream T (0) to obtain at least one gaseous partial stream T (2) with a high hydrogen content and a partial stream T (1), which contains at least propene and propane; iii) hydrogen peroxide synthesis using the partial stream T (2), to produce a partial stream T (4) with a high hydrogen peroxide content and a gaseous partial stream T (6); (iv) separation of the partial stream T (1) to obtain at least one partial stream T (5) with a high propane content and at least one partial stream T (3) with a high propene content; (v) reaction of the partial stream(s) T (3) with partial stream T (4) to obtain propylene oxide.

    9.
    发明专利
    未知

    公开(公告)号：DE102005032726A1

    公开(公告)日：2007-01-18

    申请号：DE102005032726

    申请日：2005-07-13

    Applicant: BASF AG

    Inventor： HOUSSIN CHRISTOPHE ,  JUNICKE HENRIK ,  MUELLER ULRICH

    IPC: B01J23/72 ,  C07B31/00 ,  C07B41/02 ,  C07B41/08 ,  C07C27/22 ,  C07C29/132 ,  C07C29/17 ,  C07C51/09

    Abstract: The invention relates to a method for hydrogenating an organic compound, which has at least one carbonyl group, during which the organic compound is, in the presence of hydrogen, brought into contact with a shaped body that can be produced according to a method in which: (i) an oxidic material comprising copper oxide and aluminum oxide and at least one of the oxides of iron, lanthanum, tungsten, molybdenum, titanium, zirconium, tin or manganese, as well as, optionally, tin oxide and/or manganese oxide; (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material; (iii) the mixture resulting from (ii) is shaped into a shaped body, and; (iv) the shaped body is treated with water or steam.

    10.
    发明专利
    未知

    公开(公告)号：BRPI0408384A

    公开(公告)日：2006-03-21

    申请号：BRPI0408384

    申请日：2004-03-20

    Applicant: BASF AG

    Inventor： HUBER-DIRR SYLVIA ,  HESSE MICHAEL ,  HAUNERT ANDREA ,  JUNICKE HENRIK

    IPC: B01J23/83 ,  C07C29/149 ,  B01J23/72 ,  B01J21/04

    Abstract: A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.

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