公开(公告)号：DE3062542D1

公开(公告)日：1983-05-05

申请号：DE3062542

申请日：1980-09-27

Applicant: BASF AG

Inventor： HICKMANN ECKHARD DR ,  OESER HEINZ-GUENTER DR ,  MOEBIUS LEANDER DR

IPC: C07D401/06 ,  A61K31/47 ,  C07D209/38 ,  C07D211/22 ,  C07D215/14 ,  C07D215/50

Abstract: The present invention relates to a simplified process, which avoids organo-lithium intermediates, for the preparation of erythro- alpha -piperid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl-methanol, wherein 2,8-bis-(trifluoromethyl)-quinoline-4-carboxylic acid or a salt thereof is reacted with a pyrid-2-yl-magnesium halide to give pyrid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl ketone in the manner of a Grignard reaction, and this product is hydrogenated, in a conventional manner, to give erythro- alpha -piperid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl-methanol.

公开(公告)号：DE2422183A1

公开(公告)日：1975-11-27

申请号：DE2422183

申请日：1974-05-08

Applicant: BASF AG

Inventor： KUESTERS WERNER DR ,  HICKMANN ECKHARD DR ,  VELIC MILAN DR ,  LENZ WILHELM DR ,  ZUERGER MANFRED

IPC: C08F2/00 ,  C07C45/00 ,  C07C49/84 ,  C07C67/00 ,  C07D309/12 ,  C08F2/46 ,  C08F2/50 ,  G03F7/031

公开(公告)号：CZ19097A3

公开(公告)日：1998-04-15

申请号：CZ19097

申请日：1995-07-18

Applicant: BASF AG

Inventor： KROPP RUDOLF ,  HICKMANN ECKHARD DR ,  EBEL KLAUS DR ,  GUNTHER WOLFGANG DR ,  RATH HANS PETER DR ,  SCHWAHN HARALD DR

IPC: C10L1/234 ,  C07C205/02 ,  C07C205/15 ,  C07C211/09 ,  C07C211/13 ,  C07C215/08 ,  C07C215/18 ,  C08F8/30 ,  C08F10/10 ,  C10L1/14 ,  C10L1/18 ,  C10L1/22 ,  C10L1/222 ,  C10L1/23 ,  C10L1/236 ,  C10L1/238 ,  C10L10/00 ,  C10L10/08 ,  C10M133/02 ,  C10M133/52 ,  C10M133/54 ,  C10M149/14 ,  C10M159/12 ,  C10N40/25

Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.

公开(公告)号：DE59010296D1

公开(公告)日：1996-05-30

申请号：DE59010296

申请日：1990-07-21

Applicant: BASF AG

Inventor： HICKMANN ECKHARD DR

IPC: C07C69/708 ,  C08G65/20 ,  C08G65/32 ,  C08G65/332

Abstract: Polyethercarboxylic esters of the formula I where Alk is alkyl of 1 to 8 carbon atoms, R is hydrogen or methyl and n is from 3 to 70.

公开(公告)号：DE59201251D1

公开(公告)日：1995-03-09

申请号：DE59201251

申请日：1992-03-24

Applicant: BASF AG

Inventor： FRANK JUERGEN DR ,  RHEUDE UDO DR ,  SCHULZ BERNHARD DR ,  PAUST JOACHIM DR ,  HICKMANN ECKHARD DR

IPC: B01J27/128 ,  B01J27/138 ,  C07B61/00 ,  C07C47/21 ,  C07C403/24 ,  C07D307/28

公开(公告)号：DK0409049T3

公开(公告)日：1993-04-13

申请号：DK90113144

申请日：1990-07-10

Applicant: BASF AG

Inventor： HICKMANN ECKHARD DR ,  GOETZ NORBERT DR ,  KOBER REINER DR ,  SEELE RAINER DR ,  ZIERKE THOMAS DR ,  ISAK HEINZ DR

IPC: C07B53/00 ,  C07C17/00 ,  C07C17/35 ,  C07C17/357 ,  C07C22/04 ,  C07C25/24 ,  C07C41/18 ,  C07C41/48 ,  C07C43/225 ,  C07C43/29 ,  C07D233/56 ,  C07D233/58 ,  C07D249/08 ,  C07D301/16 ,  C07D303/08 ,  C07D405/06 ,  C07D521/00

Abstract: Preparation of Z-1,2-diarylallyl chlorides of the general formula I in which the radicals R and R independently of one another are hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or a substituted aromatic radical, and n and m represent 1, 2 or 3, by dehydrating chlorohydrins of the formula II in which the radicals have the abovementioned meanings, at temperatures of up to 50 DEG C in the presence of a carboxylic anhydride and of an organic or inorganic acid, in an inert ether or carboxylate as the solvent, the reaction of these products to give azolylmethyloxiranes, and novel intermediates.

公开(公告)号：AT86597T

公开(公告)日：1993-03-15

申请号：AT90113144

申请日：1990-07-10

Applicant: BASF AG

Inventor： KOBER REINER DR ,  SEELE RAINER DR ,  ISAK HEINZ DR ,  HICKMANN ECKHARD DR ,  GOETZ NORBERT DR ,  ZIERKE THOMAS DR

IPC: C07B53/00 ,  C07C17/00 ,  C07C17/35 ,  C07C17/357 ,  C07C22/04 ,  C07C25/24 ,  C07C41/18 ,  C07C41/48 ,  C07C43/225 ,  C07C43/29 ,  C07D233/56 ,  C07D233/58 ,  C07D249/08 ,  C07D301/16 ,  C07D303/08 ,  C07D405/06 ,  C07D521/00

公开(公告)号：DE4112271A1

公开(公告)日：1992-10-22

申请号：DE4112271

申请日：1991-04-15

Applicant: BASF AG

Inventor： KOEHLER ULRICH DR ,  HICKMANN ECKHARD DR ,  SIEGEL HARDO DR ,  BECKER JOHANNES DR

IPC: C08G18/50 ,  C08G18/61 ,  C08G65/32 ,  C08G65/336 ,  C08G77/42 ,  C08G77/60

公开(公告)号：DE4026788A1

公开(公告)日：1992-02-27

申请号：DE4026788

申请日：1990-08-24

Applicant: BASF AG

Inventor： WEGNER GUENTER DR ,  KARBACH STEFAN DR ,  SMUDA HUBERT DR ,  HICKMANN ECKHARD DR ,  KOBER REINER DR ,  SEELE RAINER DR ,  ZIERKE THOMAS DR

IPC: C07C45/68 ,  C07C45/71 ,  C07C49/175 ,  C07C49/255 ,  C07C49/517 ,  C07C49/84 ,  C07D307/46 ,  C07D333/22

Abstract: Process for the production of alpha , alpha -dialkoxyketones of the general formula I in which R and R independently of one another are hydrogen, C1- to C20-alkyl, C3- to C20-cycloalkyl, C4- to C30-cycloalkylalkyl, C9- to C30-alkylcycloalkyl, or optionally C1- to C8-alkyl-, C1- to C8-alkoxy-, halogen-, C1- to C4-haloalkyl-, C1- to C4-haloalkoxy-, phenyl-, phenoxy-, halophenyl-, halophenoxy- and/or cyano-substituted aryl, C7- to C20-aralkyl or heterocycle, R is additionally R and R independently of one another are C1- to C20-alkyl, C3- to C20-cycloalkyl, aryl, C7- to C20-arylalkyl, or together are a C2- to C7-alkylene chain which is optionally substituted by C1- to C4-alkyl, and R is R or together with R is a C2- to C7-alkylene chain which is optionally substituted by C1- to C4-alkyl, by reacting ketones or aldehydes of the general formula II with nitrites of the general formula III R -(NO2)n (III> in which n is 1 or 2, and n is 2 if R and R together represent a C2- to C7-alkylene chain which is optionally substituted by C1- to C4-alkyl, with the proviso that the nitrite groups are terminal, or with a mixture of alcohol of the general formula IV R -(OH)n IV in which n is 1 or 2, and n is 2 if R and R together represent a C2- to C7-alkylene chain which is optionally substituted by C1- to C4-alkyl, with the proviso that the hydroxyl group is terminal, and with dinitrogen trioxide in a molar ratio of 2:1 in the presence of an acid catalyst, at temperatures from 0 to 170 DEG C.

公开(公告)号：DE3936823A1

公开(公告)日：1991-05-08

申请号：DE3936823

申请日：1989-11-04

Applicant: BASF AG

Inventor： KOBER REINER DR ,  SEELE RAINER DR ,  ISAK HEINZ DR ,  HICKMANN ECKHARD DR ,  GOETZ NORBERT DR ,  ZIERKE THOMAS DR

IPC: C07C17/35 ,  C07C25/24 ,  C07C43/225 ,  C07C43/29 ,  C07D303/08 ,  C07D521/00

Abstract: Z-1,2-Diaryl-allyl chlorides of formula (I) and the corresponding epoxides (V) are new: where Ar1 = (R1)n-phenyl; Ar2 = (R2)m-phenyl; R1 and R2 are each H, halo, 1-7C alkyl, 1-6C haloalkyl, 1-5C alkoxy (opt. halo substd.), or aromatic gp. (opt. substd. by 1-3 of R1 and R2; n and m = 1-3.