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公开(公告)号:DE3062542D1
公开(公告)日:1983-05-05
申请号:DE3062542
申请日:1980-09-27
Applicant: BASF AG
Inventor: HICKMANN ECKHARD DR , OESER HEINZ-GUENTER DR , MOEBIUS LEANDER DR
IPC: C07D401/06 , A61K31/47 , C07D209/38 , C07D211/22 , C07D215/14 , C07D215/50
Abstract: The present invention relates to a simplified process, which avoids organo-lithium intermediates, for the preparation of erythro- alpha -piperid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl-methanol, wherein 2,8-bis-(trifluoromethyl)-quinoline-4-carboxylic acid or a salt thereof is reacted with a pyrid-2-yl-magnesium halide to give pyrid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl ketone in the manner of a Grignard reaction, and this product is hydrogenated, in a conventional manner, to give erythro- alpha -piperid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl-methanol.
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公开(公告)号:DE3171591D1
公开(公告)日:1985-09-05
申请号:DE3171591
申请日:1981-09-17
Applicant: BASF AG
Inventor: HICKMANN ECKHARD DR , OESER HEINZ-GUENTER DR
IPC: A61K31/47 , A61P33/02 , C07D213/57 , C07D215/12 , C07D215/18 , C07D401/06 , C07D401/14 , C07F9/58 , C07F9/60 , C07F9/62 , C07F9/6558
Abstract: Quinol-4-ylmethane derivatives of the formula I I where R1 is hydrogen or chlorine, R2 is trifluoromethyl or chlorine, R3 is a nitrogen-containing, cyclic-unsaturated or acyclic-saturated radical of not more than 6 carbon atoms, R4 is hydrogen or an anion-stabilizing group and R5 is hydrogen, an anion center or an acetal radical of not more than 8 carbon atoms, their preparation and their use for the preparation of quinol-4-ylmethane derivatives.
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公开(公告)号:DE2963211D1
公开(公告)日:1982-08-19
申请号:DE2963211
申请日:1979-02-15
Applicant: BASF AG
Inventor: ROHR WOLFGANG DR , HANSEN HANSPETER DR , WUERZER BRUNO DR , OESER HEINZ-GUENTER DR
IPC: A01N43/58 , C07D237/14
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公开(公告)号:DE3264948D1
公开(公告)日:1985-08-29
申请号:DE3264948
申请日:1982-12-08
Applicant: BASF AG
Inventor: BECKER RAINER DR , OESER HEINZ-GUENTER DR , ACKER ROLF-DIETER DR
IPC: C07C67/31 , C07C69/712
Abstract: 2-(Hydroxyphenoxy)-carboxylates are prepared by a process wherein a dihydroxybenzene (A) is reacted with a 2-halo-fatty acid ester (B) of an alcohol, phenol or oxime of no more than 10 carbon atoms, in a molar ratio of A:B>/=1.5, in the presence of calcium hydroxide in dimethylsulfoxide, at from 0 DEG to 100 DEG C.
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公开(公告)号:DE3061002D1
公开(公告)日:1982-12-02
申请号:DE3061002
申请日:1980-09-03
Applicant: BASF AG
IPC: C07C265/06 , A01N47/40 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/04 , C07C265/04 , C07C118/00 , C07C119/042
Abstract: 1-Monohalogenated isocyanates, and a process for the preparation of mixtures of 1-monohalogenated isocyanates and 1,2-unsaturated isocyanates by reacting 1-monohalogenated carbamic acid halides or isocyanates with a halogen-free isocyanate or diisocyanate or by reacting 1,2-unsaturated isocyanates with a carbamic acid halide or a bis-carbamic acid halide. The 1,2-unsaturated isocyanates and 1-monohalogenated isocyanates prepared according to the invention are valuable starting materials for the preparation of pest control agents, dyes, drugs, water-repellent textile finishes, detergents, plastics, bleaches and adhesives.
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公开(公告)号:DE2960787D1
公开(公告)日:1981-11-26
申请号:DE2960787
申请日:1979-10-15
Applicant: BASF AG
IPC: C07C265/02 , A01M20060101 , A61K20060101 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/16 , C07C265/04 , C09B20060101 , C07C119/042
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公开(公告)号:DE3063695D1
公开(公告)日:1983-07-14
申请号:DE3063695
申请日:1980-10-17
Applicant: BASF AG
Inventor: PARG ADOLF DR , HAMPRECHT GERHARD DR , OESER HEINZ-GUENTER DR
IPC: A01N43/58 , A01N47/30 , A01N47/32 , A01N47/38 , C07C273/18 , C07C275/36 , C07C275/64 , C07D207/06 , C07D213/62 , C07D213/64 , C07D213/643 , C07D213/65 , C07D237/14 , C07D237/16 , C07D237/22 , C07D265/30 , C07D295/215 , C07C93/14 , C07C121/75 , C07C149/42
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公开(公告)号:CH633519A5
公开(公告)日:1982-12-15
申请号:CH578978
申请日:1978-05-26
Applicant: BASF AG
Inventor: OESER HEINZ-GUENTER DR , KOENIG KARL-HEINZ DR , MANGOLD DIETRICH DR
IPC: C07B61/00 , B01J23/00 , C07C67/00 , C07C201/00 , C07C201/12 , C07C205/12 , C07C253/00 , C07C255/50 , C07C79/12 , C07C121/52
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公开(公告)号:DE3060496D1
公开(公告)日:1982-07-22
申请号:DE3060496
申请日:1980-05-21
Applicant: BASF AG
Inventor: THEOBALD HANS DR , ADOLPHI HEINRICH DR , EICKEN KARL DR , OESER HEINZ-GUENTER DR
IPC: A01N57/16 , C07D213/64 , C07F9/58
Abstract: 6-Fluoropyridyl-(di)(thio)phosphoric acid esters, and their use for combating pests, especially from the classes of insects and Nemathelminthes. The 6-fluoropyridyl-(di)(thio)phosphoric acid esters have the formula where X is oxygen or sulfur, R1 is linear or branched alkyl of a maximum of 3 carbon atoms and R2 is linear or branched alkylthio of a maximum of 6 carbon atoms.
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公开(公告)号:DE3267839D1
公开(公告)日:1986-01-16
申请号:DE3267839
申请日:1982-12-11
Applicant: BASF AG
Inventor: BECKER RAINER DR , HOFFMANN WERNER DR , OESER HEINZ-GUENTER DR , ROHR WOLFGANG DR , VARWIG JUERGEN DR
IPC: C07C69/66 , B01J23/00 , B01J27/00 , C07B61/00 , C07C41/00 , C07C41/01 , C07C41/16 , C07C41/26 , C07C43/205 , C07C43/225 , C07C43/23 , C07C43/29 , C07C43/295 , C07C51/00 , C07C59/125 , C07C59/64 , C07C67/00 , C07C201/00 , C07C205/38 , C07C253/00 , C07C255/54 , C07D213/64 , C07D241/44 , C07D277/68
Abstract: 1. A process for the preparation of a diether of m- or p-hydroxyphenol, of the formula see diagramm : EP0083010,P13,F4 or a monoether of m- or p-hydroxyphenol, of the formula see diagramm : EP0083010,P13,F5 where the two hydroxyl groups are in the m- or p-position relative to one another and R**1 is an aliphatic radical or see diagramm : EP0083010,P13,F6 see diagramm : EP0083010,P13,F7 see diagramm : EP0083010,P14,F1 see diagramm : EP0083010,P14,F2 see diagramm : EP0083010,P14,F3 the individual radicals R**2 and R**3 can be identical or different and each is hydrogen or an aliphatic, araliphatic or aromatic radical, and R**3 can also in each case be halogen, nitro, cyano or alkoxy, by reacting a monoether of a dihydroxy compound with a halogen compound to form a diether and splitting off the original monoether group, wherein a) m- or p-tert.-butoxyphenol of the formula see diagramm : EP0083010,P14,F4 is reacted with a halogen compound of the formula R**1 -X where R**1 has the above meanings and X is halogen, in the presence of a hydroxide, carbonate and/or bicarbonate of an alkali metal or alkaline earth metal and an organic solvent which is inert under the reaction conditions, at from 20 to 150 degrees C, to give the end product la, and, if desired, b) the resulting end product la is reacted with a mixture of water, a water-miscible alkanol and an inorganic acid at from 30 to 100 degrees C to give the end product Ib.
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