公开(公告)号：DE3934205A1

公开(公告)日：1991-04-18

申请号：DE3934205

申请日：1989-10-13

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  SCHUBERT JUERGEN DR ,  KACZMAREK REINHARD DR

IPC: C07C327/24 ,  C07C327/28 ,  C07C327/58

Abstract: Preparation of cyclohexanetrionecarboxylic acid thiol esters of the formula I in which R and R represent optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, benzyl or phenyl, and R additionally denotes hydrogen, by reacting a cyclohexanetrione compound II with hydroxylamine or hydroxylamine O-sulphonic acid in an inert solvent at temperatures from 0 to 150 DEG C to give cyclohexanetrione compounds III subsequently reacting the compounds III with a mercaptan IV R -SH IV in the presence of an anhydrous acid HX to give cyclohexanetrione imidothioester salts V where X represents the acid radical, and hydrolysing the compounds V to give the cyclohexanetrione carboxylic acid thiol esters I.

公开(公告)号：DE3718899A1

公开(公告)日：1988-12-22

申请号：DE3718899

申请日：1987-06-05

Applicant: BASF AG

Inventor： KEIL MICHAEL DR ,  SCHIRMER ULRICH DR ,  KAST JUERGEN DR ,  KOLASSA DIETER DR ,  WUERZER BRUNO DR ,  MEYER NORBERT DR ,  RADEMACHER WILHELM DR ,  JUNG JOHANN PROF DR ,  CARLSON DALE R DR

IPC: A01N37/08 ,  A01N37/42 ,  A01N37/44 ,  A01N37/50 ,  C07C67/00 ,  C07C325/00 ,  C07C327/14 ,  C07C327/22 ,  C07C327/24 ,  C07C153/07 ,  C07C149/26

Abstract: 1. A cyclohexenone compound of the formula I see diagramm : EP0293817,P16,F3 where R**1 is hydrogen ; C1 -C6 -alkyl which is unsubstituted or substituted by C1 -C4 -alkoxy, C1 -C4 -alkylthio, C1 -C4 dialkylamino, hydroxyl or halogen ; C2 -C6 -alkenyl ; C3 -C6 -cycloalkyl ; or phenyl or benzyl which is unsubstituted or substituted by halogen, C1 -C4 -alkyl, C1 -C4 -alkoxy or nitro, R**2 is C1 -C4 -alkyl or cyclopropyl, A is oxygen ; a radical NOR**3 , where R**3 is C1 -C4 -alkyl, C3 or C4 -alkenyl, C3 - or C4 -alkynyl, C2 -C4 -haloalkyl, C3 - or C4 -haloalkenyl or C2 -C4 -alkoxyalkyl ; or a radical NR4 , where R4 is hydrogen, C1 -C6 -alkyl, C1 -C4 -hydroxyalkyl, C1 -C4 -alkoxyalkyl, benzyl or phenyl, and X is hydroxyl ; chlorine ; C1 -C6 -alkylthio which is unsubstituted or substituted by C1 -C4 -alkoxy, C1 -C4 -alkylthio, C1 -C4 dialkylamino, hydroxyl or halogen ; C2 -C6 -alkenylthio ; C3 -C6 -cycloalkylthio ; or phenylthio or benzylthio which is unsubstituted or substituted by halogen, C1 -C4 -alkoxy or nitro, or an agriculturally usable salt thereof.

公开(公告)号：DE3701298A1

公开(公告)日：1988-07-28

申请号：DE3701298

申请日：1987-01-17

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  KEIL MICHAEL DR ,  KOLASSA DIETER DR ,  SCHIRMER ULRICH DR ,  WUERZER BRUNO DR ,  MEYER NORBERT DR ,  RADEMACHER WILHELM DR ,  JUNG JOHANN PROF DR

IPC: A01N43/14 ,  C07D309/32 ,  C07D409/04 ,  C07D407/04 ,  A01N43/00 ,  A01N43/16 ,  A01N43/18 ,  C07D335/02 ,  C07D409/14 ,  C07D521/00

Abstract: The invention relates to tetrahydro(thio)pyran-2,4-diones of the formula in which R represents hydrogen, a cation, alkylcarbonyl, C2-C10-alkenylcarbonyl or benzoyl which is optionally substituted by alkyl, R represents alkyl, R represents a non-aromatic heterocycle which has 5 to 7 ring members and not more than one double bond in the heterocyclic ring and which is optionally substituted by alkyl, X represents oxygen or sulphur, Z represents oxygen or the radical NO-R , where R represents alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, alkoxyalkyl or the radical CH2-R in which R represents a 5-membered heterocycle having up to 3 hetero atoms, and, if appropriate, not more than 2 double bonds and up to 2 substituents selected from the group comprising alkyl, alkoxy, halogen, trifluoromethyl, alkoxymethyl, alkylthiomethyl and vinyl, or represents phenyl which is optionally substituted by up to 3 substituents selected from the group comprising alkyl, alkoxy, halogen, trifluoromethyl, nitro and dialkylamino, to processes for their preparation and to their use for controlling undesired plant growth for regulating the growth of plants.

公开(公告)号：DE59505617D1

公开(公告)日：1999-05-20

申请号：DE59505617

申请日：1995-01-27

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  VON DEYN WOLFGANG DR ,  NUEBLING CHRISTOPH DR ,  WALTER HELMUT DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR

IPC: C07D239/80 ,  A01N35/06 ,  A01N41/10 ,  A01N43/00 ,  C07C321/22 ,  C07C323/22 ,  C07C323/48 ,  C07C323/64 ,  C07C323/66 ,  C07D207/00 ,  C07D235/26 ,  C07D239/96 ,  C07D261/06 ,  C07D263/54 ,  C07D265/14 ,  C07D275/02 ,  C07D275/06 ,  C07D277/62 ,  C07D279/16 ,  C07D285/16 ,  C07D307/00 ,  C07D317/26 ,  C07D317/34 ,  C07D333/52 ,  C07D335/06

Abstract: 2-Aroyl-cyclohexane dione derivs. of formula (I) and the agriculturally acceptable salts of (I) with 1-10C carboxylic acids or inorganic acids are new. A = 1-6C alkylene; R = phenyl or 5-6 membered heteroaryl (each ring being opt. mono to tetra-substd. with halogen, CN, NO2, N = N-Ph, S(O)mR , (1-4C alkoxy)carbonyl, SO2NR R , NR COR , NR SO2R , 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy (these last 4 gps. themselves opt. mono or di substd. with 1-4C alkoxy, 1-4C alkylthio and/or CN) and 2 neighbouring C atoms on each ring being opt. linked by one of these chains: CR =CR CR =CR , XCR =N, XN=CR , CR =NCR R -X, XCR =NCR R , XCR =CR , XCR =CR -CR R , XCR R -CR R , CR R -X-CR R , X-CR R -Y, X-CR R -CR R -Y, X-CR R -CR R -CR R , CR R -X-CR R -CR R , XNR X, SNR X, CR R -NR X, XNR YNR , or NR XN=CR ); X and Y = each, S, O, SO, SO2, CO, CR R or NR ; R - R = each H, halogen, OH, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C alkylamino, di(1-4C alkyl)amino or phenyl; R , R = H, 1-4C alkyl, 1-4C alkoxy, (1-4C alkyl)carbonyl, phenyl or benzoyl; Ph = phenyl opt. mono to tri-substd. with halogen, CN, NO2 S(O)nR , (1-4C alkoxy)carbonyl, SO2NR R , NR COR , NR SO2R , 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, or 1-4C haloalkoxy (these last 4 gps.themselves opt. mono or di substd.with 1-4C alkoxy, 1-4C alkylthio and/or CN); m and n = 0-2; R and R = 1-4C alkyl or 1-4C halo-alkyl (each opt. mono- or di-substd. with 1-4C alkoxy, 1-4C alkylthio and/or CN); R ,R ,R and R = H, 1-4C alkyl, 1-4C haloalkyl, or phenyl (this last opt. mono to tri-substd. with halogen, 1-4C alkyl or 1-4C alkoxy); R and R = each 1-4C alkyl or 1-4C halo-alkyl (each opt. mono or di-substd. with CN, phenyl and/or benzyl); R -R = H or 1-4C alkyl; R = H, 1-4C alkyl or (1-4C alkoxy)carbonyl; R = 1-4C alkyl; provided that R is not mono or di-halo-phenyl.

公开(公告)号：AT169624T

公开(公告)日：1998-08-15

申请号：AT91107140

申请日：1991-05-02

Applicant: BASF AG

Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  KUEKENHOEHNER THOMAS DR ,  WUERZER BRUNO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: C07D213/30 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/36 ,  A01N43/40 ,  A01P13/00 ,  C07D207/32 ,  C07D207/333 ,  C07D307/38 ,  C07D307/42 ,  C07D333/16 ,  C07D333/28 ,  C07D405/08 ,  C07D405/12 ,  C07D407/08 ,  C07D407/12 ,  C07D409/08 ,  C07D409/12

Abstract: Cyclohexenone oxime ethers of the formula I (I) (R1=C1-C6-alkyl; A=substituted or unsubstituted alkylene or alkenylene; Z=a 5-membered or 6-membered heteroaromatic structure; X=substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, carboxyl, C1-C4-alkoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl and phenyl; n=0 to 3, or 1 to 4 where Z is halogen-substituted pyridyl; and R2=alkoxyalkyl or alkylthioalkyl; substituted or unsubstituted cycloalkyl or cycloalkenyl; a substituted or unsubstituted 5-membered saturated heterocyclic structure which contains one or two hetero atoms; a substituted or unsubstituted 6-membered or 7-membered saturated or mono- or diunsaturated heterocyclic structure containing one or two hereto atoms; a substituted or unsubstituted 5-membered heteroaromatic structure containing one to three hereto atoms; substituted or unsubstituted phenyl or pyridyl) and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids. The compounds are suitable as herbicides.

公开(公告)号：DE59108291D1

公开(公告)日：1996-11-28

申请号：DE59108291

申请日：1991-04-27

Applicant: BASF AG

Inventor： MEYER NORBERT DR ,  KAST JUERGEN DR ,  MISSLITZ ULF DR ,  HARREUS ALBRECHT DR ,  GOETZ NORBERT DR ,  WUERZER BRUNO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/18 ,  A01N43/30 ,  A01N43/32 ,  A01N43/36 ,  A01N43/80 ,  A01P13/00 ,  C07C239/08 ,  C07C239/20 ,  C07C251/34 ,  C07C251/36 ,  C07C251/42 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07C251/60 ,  C07C255/62 ,  C07C323/47 ,  C07D207/32 ,  C07D207/335 ,  C07D257/02 ,  C07D261/02 ,  C07D261/04 ,  C07D261/08 ,  C07D275/02 ,  C07D307/14 ,  C07D309/04 ,  C07D309/06 ,  C07D309/20 ,  C07D317/26 ,  C07D317/28 ,  C07D319/06 ,  C07D333/04 ,  C07D333/16 ,  C07D333/22 ,  C07D333/58 ,  C07D335/02 ,  C07D339/06

Abstract: Cyclohexenone oxime ethers of the general formula I in which the substituents have the following meanings: R is alkyl; A is optionally substituted C3-, C5- or C6-alkylene or C3-, C5- or C6-alkenylene, X is NO2, CM, halogen, alkyl, alkoxy, phenoxy, alkylthio, haloalkyl, haloalkoxy, carboxyl, alkoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted phenyl, n is 0 - 3 or 1 - 5 if X is halogen; R is alkoxyalkyl or alkylthioalkyl; optionally substituted cycloalkyl or cycloalkenyl, an optionally substituted 5-membered saturated heterocycle having one or two oxygen and/or sulphur atoms as hetero atoms, an optionally substituted 6- or 7-membered heterocycle having up to two oxygen and/or sulphur atoms and up to two double bonds, an optionally substituted 5-membered hetaryl having up to two nitrogen atoms and one oxygen atom or one sulphur atom, optionally substituted phenyl or pyridyl, and their agriculturally utilisable salts and esters of C1-C10-carboxylic acids and inorganic acids, methods and intermediates for their preparation, and their use as herbicides.

公开(公告)号：DE4427995A1

公开(公告)日：1996-02-15

申请号：DE4427995

申请日：1994-08-08

Applicant: BASF AG

Inventor： PLATH PETER DR ,  KARDORFF UWE DR ,  DEYN WOLFGANG VON DR ,  ENGEL STEFAN DR ,  KAST JUERGEN DR ,  RANG HARALD DR ,  KOENIG HARTMANN DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR

IPC: C07D275/04 ,  A01N43/80 ,  A01P13/00 ,  C07D275/00 ,  C07D275/06 ,  C07D417/10 ,  C07D417/06

Abstract: Saccharin derivatives of formula (I) are disclosed, wherein the substituents have the following meanings: L, M stand for hydrogen, alkyl, alkoxy, alkylthio, chlorine, cyano, methylsulphonyl, nitro or trifluoromethyl; Z stands for hydrogen, alkyl, cycloalkyl, alkenyl, alkinyl, acyl, benzyl (optionally substituted by halogen, alkyl), or phenyl; J stands for an optionally substituted cyclohexane-1,3-dione ring linked at position 2.

公开(公告)号：AT130602T

公开(公告)日：1995-12-15

申请号：AT92916831

申请日：1992-08-05

Applicant: BASF AG

Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  BRATZ MATTHIAS DR ,  HARREUS ALBRECHT DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: A01N31/06 ,  A01N35/10 ,  A01N39/00 ,  A01N41/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/80 ,  A01P13/00 ,  C07C317/30 ,  C07C323/47 ,  C07D261/08 ,  C07D333/16 ,  C07D333/28

公开(公告)号：ES2075258T3

公开(公告)日：1995-10-01

申请号：ES91106892

申请日：1991-04-27

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  MEYER NORBERT DR ,  MISSLITZ ULF DR ,  HARREUS ALBRECHT DR ,  KUEKENHOEHNER THOMAS DR ,  RANG HARALD DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: A01N35/10 ,  A01N37/22 ,  A01N37/34 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/28 ,  A01N43/80 ,  A01P13/00 ,  C07C239/08 ,  C07C239/20 ,  C07C249/08 ,  C07C251/34 ,  C07C251/42 ,  C07C251/52 ,  C07C251/54 ,  C07C251/58 ,  C07C251/60 ,  C07C255/62 ,  C07C323/47 ,  C07D213/30 ,  C07D257/02 ,  C07D261/08 ,  C07D275/02 ,  C07D307/10 ,  C07D307/14 ,  C07D309/04 ,  C07D309/06 ,  C07D309/08 ,  C07D309/20 ,  C07D317/14 ,  C07D317/28 ,  C07D333/04 ,  C07D333/06 ,  C07D335/02 ,  C07D339/06

Abstract: Cyclohexenone oxime ethers I (I) where R1 is C1-C6-alkyl, A is unsubstituted or substituted C3-C6-alkynylene, Z is unsubstituted or substituted phenyl or a 5-membered or 6-membered heteroaromatic and R2 is C1-C4-alkoxy-C1-C6-alkyl, C1-C4-alkylthio-C1-C6-alkyl, unsubstituted or substituted C3-C7-cycloalkyl or C5-C7-cycloalkenyl, an unsubstituted or substituted 5-membered saturated heterocyclic structure having one or two hetero atoms, an unsubstituted or substituted 6-membered or 7-membered saturated or monounsaturated or diunsaturated heterocyclic structure having one or two hetero atoms, an unsubstituted or substituted 5-membered heteroaromatic having one to three hetero atoms or unsubstituted or substituted phenyl or pyridyl, and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids, are suitable as herbicides.

公开(公告)号：DE59106110D1

公开(公告)日：1995-09-07

申请号：DE59106110

申请日：1991-04-27

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  MEYER NORBERT DR ,  MISSLITZ ULF DR ,  HARREUS ALBRECHT DR ,  KUEKENHOEHNER THOMAS DR ,  RANG HARALD DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: A01N35/10 ,  A01N37/22 ,  A01N37/34 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/28 ,  A01N43/80 ,  A01P13/00 ,  C07C239/08 ,  C07C239/20 ,  C07C249/08 ,  C07C251/34 ,  C07C251/42 ,  C07C251/52 ,  C07C251/54 ,  C07C251/58 ,  C07C251/60 ,  C07C255/62 ,  C07C323/47 ,  C07D213/30 ,  C07D257/02 ,  C07D261/08 ,  C07D275/02 ,  C07D307/10 ,  C07D307/14 ,  C07D309/04 ,  C07D309/06 ,  C07D309/08 ,  C07D309/20 ,  C07D317/14 ,  C07D317/28 ,  C07D333/04 ,  C07D333/06 ,  C07D335/02 ,  C07D339/06

Abstract: Cyclohexenone oxime ethers I (I) where R1 is C1-C6-alkyl, A is unsubstituted or substituted C3-C6-alkynylene, Z is unsubstituted or substituted phenyl or a 5-membered or 6-membered heteroaromatic and R2 is C1-C4-alkoxy-C1-C6-alkyl, C1-C4-alkylthio-C1-C6-alkyl, unsubstituted or substituted C3-C7-cycloalkyl or C5-C7-cycloalkenyl, an unsubstituted or substituted 5-membered saturated heterocyclic structure having one or two hetero atoms, an unsubstituted or substituted 6-membered or 7-membered saturated or monounsaturated or diunsaturated heterocyclic structure having one or two hetero atoms, an unsubstituted or substituted 5-membered heteroaromatic having one to three hetero atoms or unsubstituted or substituted phenyl or pyridyl, and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids, are suitable as herbicides.