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公开(公告)号:CA2376345C
公开(公告)日:2010-06-01
申请号:CA2376345
申请日:2002-03-12
Applicant: BASF AG
Inventor: LUTTER HEINZ-DIETER , BRUCHMANN BERND , WAGNER KLAUS , MULLER JENS
Abstract: The present invention relates to a process for the production of flexible polyurethane foams by reaction of a) at least one compound having at least two isocyanate-reactive hydrogen atoms, with b) polyisocyanates, wherein the compund used as said Compound having at least two isocyanate-reactive hydrogen atoms a) comprises at least one block polyoxypropylene/polyoxyethylene/polyol having a hydroxyl value of from 25 to 45 mg KOH/g and a content of terminally bound ethylene oxide units of from 15 to 17 wt-%, based on the total amount of the alkylene oxide, obtained by attachment of ethylene oxide and propylene oxide to an initiator having an average functionality of 3.
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公开(公告)号:CA2370340C
公开(公告)日:2008-12-23
申请号:CA2370340
申请日:2002-02-04
Applicant: BASF AG
Inventor: FALKE PETER , LUTTER HEINZ-DIETER , PCOLINSKI MICHAEL
Abstract: Low-density hydrophilic flexible polyurethane foams are prepared by reacting organic and/or modified organic polyisocyanates (a) with a polyetherol mixture,(b) and, if required, further compounds (c) having hydrogen atoms reactive toward isocyanates, in the presence of water and/or other blowing agents (d), catalysts (e) and, if required, further assistants and additives (f), by a process in which the polyetherol mixture (b) consists of b1) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and ethylene oxide, having an ethylene oxide content of more than 40% by weight, based on the total amount of alkylene oxide used, an OH number of from 20 to 120 mg KOH/g and a proportion of primary OH groups of more than 20% and b2) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and, if required, ethylene oxide, the ethylene oxide content being not more than 40% by weight, and having an OH number of more than 25 mg KOH/g, water in amounts of up to 15% by weight, based on the total weight of the components (b) to (f), and a mixture of gel catalysts and blowing catalysts are used and the foaming is effected in an index range of from 20 to 120. Furthermore, the flexible polyurethane foams themselves produced in this manner are used as upholstery material, as energy-absorbing material and in the cosmetics and hygiene sectors.
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33.
公开(公告)号:ES2285502T3
公开(公告)日:2007-11-16
申请号:ES04765051
申请日:2004-09-10
Applicant: BASF AG
Inventor: BAUER STEPHAN , WAGNER KLAUS , LUTTER HEINZ-DIETER , MEYER STEFAN
Abstract: Alfombrilla para automóvil, que comprende una espuma blanda, termomoldeada, de poliuretano, obtenible mediante reacción de al menos i) poliisocianatos con ii) polioles con un contenido en polímeros termoplásticos desde un 2 hasta un 50 % en peso, obtenible mediante polimerización por medio de radicales de monómeros olefínicos, adecuados, en un poliéterol que sirve como base para el injerto, para dar una espuma blanda de poliuretano, con una densidad de 10 hasta 150 g/l según DIN EN ISO 845 y, a continuación, moldeo térmico irreversible de la espuma blanda obtenida, a temperaturas por encima de la temperatura de transición vítrea de los polímeros termoplásticos.
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公开(公告)号:DE502004003711D1
公开(公告)日:2007-06-14
申请号:DE502004003711
申请日:2004-09-10
Applicant: BASF AG
Inventor: BAUER STEPHAN , WAGNER KLAUS , LUTTER HEINZ-DIETER , MEYER STEFAN
Abstract: The invention relates to a thermoformed soft foam, made from polyurethane, obtained by reaction of polyisocyanates with polymeric polyols to give a polyurethane soft foam with subsequent irreversible thermoforming of the soft foam obtained thus, at temperatures above the glass temperature of the thermoplastic polymers and the use of polymeric polyols to produce a polyurethane soft foam which may be irreversibly formed in moulds at temperatures of 120 DEG C to 250 DEG C.
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公开(公告)号:CA2307082C
公开(公告)日:2006-03-21
申请号:CA2307082
申请日:2000-04-28
Applicant: BASF AG
Inventor: BRUCHMANN BERND , LUTTER HEINZ-DIETER , RENZ HANS
Abstract: In-a compound of the formula I (see formula) (reactive polymer), L is polymer, XY is a reactive radical which is inert toward NCO groups and splits off one or more protective groups Y under acidic, neutral or basic conditions and the radical X bears, after Y has been split off, at least two groups which are reactive toward isocyanates. Also provided are processes for preparing such a polymer and for preparing a polymer polyol which is obtainable by reacting a polymer of the formula I with an acid or base. A polymer polyol as is obtainable by treatment of a reactive polymer according to the present, invention produce a polyaddition product or polycondensation product.
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公开(公告)号:DE10343122A1
公开(公告)日:2005-04-07
申请号:DE10343122
申请日:2003-09-16
Applicant: BASF AG
Inventor: BAUER STEPHAN , WAGNER KLAUS , LUTTER HEINZ-DIETER , MEYER STEFAN
Abstract: The invention relates to a thermoformed soft foam, made from polyurethane, obtained by reaction of polyisocyanates with polymeric polyols to give a polyurethane soft foam with subsequent irreversible thermoforming of the soft foam obtained thus, at temperatures above the glass temperature of the thermoplastic polymers and the use of polymeric polyols to produce a polyurethane soft foam which may be irreversibly formed in moulds at temperatures of 120 DEG C to 250 DEG C.
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公开(公告)号:AT260309T
公开(公告)日:2004-03-15
申请号:AT97111491
申请日:1997-07-08
Applicant: BASF AG
Inventor: GUETTES BERND , DINSCH STEFAN , STEINCHEN KARL-HEINZ , HOEPPNER GERD , WAGNER KLAUS , LARBIG HARALD , LUTTER HEINZ-DIETER
Abstract: A process for the production of flexible polyurethane foam comprises reacting: (a) optionally modified polyisocyanates with: (b) compounds with reactive hydrogens, and (c) optionally chain extenders and/or crosslinkers, in presence of: (d) blowing agents, (e) catalysts, (f) fire retardants, and optionally: (g) other additives etc. At least 10 wt% of the compounds used in this process comprises polyether-polyols obtained by base-catalysed reaction of lower alkylene oxides with hydroxy-functional starters and subjected, during or after alkylene oxides-addition and with a water content of not more than 0.1 wt.%, to distillation at temperatures above 49 degrees C.
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公开(公告)号:DE10110553A1
公开(公告)日:2002-09-12
申请号:DE10110553
申请日:2001-03-05
Applicant: BASF AG
Inventor: BRUCHMANN BERND , BINDER HORST , LUTTER HEINZ-DIETER , HIRN MICHAEL , SANDER PAMELA
Abstract: The invention relates to a method of producing flexible polyurethane foams that have a density of not more than 100 g/l, by reacting: a) polyisocyanates with b) compounds with at least two hydrogen atoms that are reactive with isocyanate groups. The inventive method is characterized in that the polyisocyanates (a) are aromatic di- or polysiocyanates and the compounds with at least two hydrogen atoms (b) that are reactive with isocyanate groups contain at least one acrylate polyol.
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公开(公告)号:DE10105559A1
公开(公告)日:2002-08-08
申请号:DE10105559
申请日:2001-02-06
Applicant: BASF AG
Inventor: FALKE PETER , LUTTER HEINZ-DIETER , PCOLINSKI MICHAEL
Abstract: Low-density hydrophilic flexible polyurethane foams are prepared by reacting organic and/or modified organic polyisocyanates (a) with a polyetherol mixture (b) and, if required, further compounds (c) having hydrogen atoms reactive toward isocyanates, in the presence of water and/or other blowing agents (d), catalysts (e) and, if required, further assistants and additives (f), by a process in which the polyetherol mixture (b) consists ofb1) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and ethylene oxide, having an ethylene oxide content of more than 40% by weight, based on the total amount of alkylene oxide used, an OH number of from 20 to 120 mg KOH/g and a proportion of primary OH groups of more than 20% andb2) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and, if required, ethylene oxide, the ethylene oxide content being not more than 40% by weight, and having an OH number of more than 25 mg KOH/g,water in amounts of up to 15% by weight, based on the total weight of the components (b) to (f), and a mixture of gel catalysts and blowing catalysts are used and the foaming is effected in an index range of from 20 to 120. Furthermore, the flexible polyurethane foams themselves produced in this manner are used as upholstery material, as energy-absorbing material and in the cosmetics and hygiene sectors.
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公开(公告)号:CA2370340A1
公开(公告)日:2002-08-06
申请号:CA2370340
申请日:2002-02-04
Applicant: BASF AG
Inventor: FALKE PETER , LUTTER HEINZ-DIETER , PCOLINSKI MICHAEL
Abstract: Low-density hydrophilic flexible polyurethane foams are prepared by reacting organic and/or modified organic polyisocyanates (a) with a polyetherol mixture,(b) and, if required, further compounds (c) having hydrogen atoms reactive toward isocyanates, in the presence of water and/or other blowing agents (d), catalysts (e) and, if required, further assistants and additives (f), by a process in which the polyetherol mixture (b) consists of b1) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and ethylene oxide, having an ethylene oxide content of more than 40% by weight, based on the total amount of alkylene oxide used, an OH number of from 20 to 120 mg KOH/g and a proportion of primary OH groups of more than 20% and b2) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and, if required, ethylene oxide, the ethylene oxide content being not more than 40% by weight, and having an OH number of more than 25 mg KOH/g, water in amounts of up to 15% by weight, based on the total weight of the components (b) to (f), and a mixture of gel catalysts and blowing catalysts are used and the foaming is effected in an index range of from 20 to 120. Furthermore, the flexible polyurethane foams themselvesproduced in this manner are used as upholstery material, as energy-absorbing material and in the cosmetics and hygiene sectors.
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