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公开(公告)号:JP2001278943A
公开(公告)日:2001-10-10
申请号:JP2001028625
申请日:2001-02-05
Applicant: BASF AG , BASF COATINGS AG
Inventor: BRUCHMANN BERND , RENZ HANS , MOHRHARDT GUENTHER , BAUMGART HUBERT , BITTER SIMONE
Abstract: PROBLEM TO BE SOLVED: To obtain a coating film having excellent mechanical characteristics, especially high strength, flexibility and chemical resistance by using a two-pack coating material containing a polyisocyanate having no defects of the conven tional techniques. SOLUTION: A compound represented by formula (1): OCN-R1-[-NX-CO-O-R2- O-CO-NX-R1-]n-NCO is used as a polyisocyanate [in formula, R1, X and R2, and n are shown the claim 1].
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公开(公告)号:JPH0912971A
公开(公告)日:1997-01-14
申请号:JP17138996
申请日:1996-07-01
Applicant: BASF AG
Inventor: BRUCHMANN BERND , RENZ HANS , MOHRHARDT GUENTER
IPC: C09D175/04 , C08G18/28 , C08G18/32 , C08G18/38 , C08G18/80 , C09D175/00
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公开(公告)号:JP2001323041A
公开(公告)日:2001-11-20
申请号:JP2001079024
申请日:2001-03-19
Applicant: BASF AG
Inventor: BRUCHMANN BERND DR , RENZ HANS , KOENIGER RAINER , EHE ULRIKE , TREULING ULRICH DR , MUELLER-MALL RUDOLF
IPC: C08G18/10 , C08G18/09 , C08G18/80 , C09D175/04 , C09J175/04
Abstract: PROBLEM TO BE SOLVED: To obtain a polyisocyanate useful as a building block made of polyurethane and combining high functionality, high reactivity, low consistency and good properties. SOLUTION: (i) An addition product A is produced by reacting a diisocyanate or a polyisocyanate I with a compound having three or more groups reactive to the isocyanate, a compound having two groups reactive thereto or the mixture of the compounds. A reaction ratio is selected so that the product A containing an average of one group having reactivity to the isocyanate. (ii) A polyaddition product P containing an average of one group having reactivity to the isocyanate and an average of more than two isocyanate groups is formed by an intermolecular addition product. (iii) The high functional polyisocyanate is obtained by reacting the product A and/or the product P with a diisocyanate or a polyisocyanate II.
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公开(公告)号:JP2001213936A
公开(公告)日:2001-08-07
申请号:JP2001028091
申请日:2001-02-05
Applicant: BASF AG
Inventor: BRUCHMANN BERND , MOHRHARDT GUNTER , RENZ HANS , JAHME JOACHIM
IPC: C08G18/79 , C08G18/72 , C08G18/78 , C08G18/80 , C09D175/04
Abstract: PROBLEM TO BE SOLVED: To provide a polyisocyanate storable for a longer time without undergoing substantial changes in its characteristics. SOLUTION: A polyisocyanate-containing mixture comprises (a) a polyisocyanate (polyisocyanate A) obtained from an aliphatic or alicyclic diisocyanate (diisocyanate C) and having a structural unit selected from an isocyanurate group and a biuret group, and (b) a polyisocyanate (polyisocyanate B) other than A having a structural unit selected from an allophanate group and a urethane group obtained from (b1) an aliphatic or alicclic diisocyanate (diisocyanate C) and (b2) a polyvalent aliphatic or alicyclic alcohol (alcohol A). At this time, the molar ratio of the polyisocyanarte A to the polyisocyanate B is caused to be 200:1 to 5:1.
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公开(公告)号:JP2001261770A
公开(公告)日:2001-09-26
申请号:JP2001068523
申请日:2001-03-12
Applicant: BASF AG
Inventor: BRUCHMANN BERND DR , RENZ HANS , KONIGER RAINER , EHE ULRIKE
Abstract: PROBLEM TO BE SOLVED: To provide a polyisocyanate which has good characteristics and can easily by produced. SOLUTION: This method for producing the polyisocyanate, comprising (i) a step for reacting (a) a diisocyanate I (cf. the specification) with (b) a compound having two groups capable of reacting with the isocyanate (wherein, at least one of the components (a) and (b) has a function group exhibiting a reacting property different from the functional groups of the other component) to produce (A) the addition product with having one isocyanate group and a group capable of reacting with one isocyanate, (ii), if necessary, a step for producing (P) a polyaddition reaction product having one isocyanate group and a group capable of reacting with one isocyanate, and (iii) a step for reacting (A) the addition product and/or (P) the polyaddition reacting product with a diisocyanate or polyisocyanate II different from the diisocyanate I.
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公开(公告)号:JPH11193319A
公开(公告)日:1999-07-21
申请号:JP28757298
申请日:1998-10-09
Applicant: BASF AG
Inventor: BRUCHMANN BERND DR , LUTTER HEINZ-DIETER , RENZ HANS , SCHERZER DIETRICH , MOHRHARDT GUENTER
IPC: C08G18/48 , C08G18/28 , C08G18/56 , C09D175/04
Abstract: PROBLEM TO BE SOLVED: To provide a two-component polyurethane contg. a reactive diluent which is easy to manufacture and incorporated into a polyurethane without difficulty, and has no side-reaction with the structural component of the polyurethane. SOLUTION: This polyurethane comprises at least two-functional polyisocyanate component and polyol component, and the polyol component contains at least a cyclic acetal contg. a hydroxyl and/or a ketal. This method of manufacturing the polyurethane comprises a reaction of at least two- functional polyisocyanate with a compd. contg. an active hydrogen, and the compd. contg. an active hydrogen contains the cyclic acetal and/or the ketal as a reactive diluent.
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公开(公告)号:AT366763T
公开(公告)日:2007-08-15
申请号:AT01101920
申请日:2001-01-27
Applicant: BASF AG
Inventor: BRUCHMANN BERND , RENZ HANS , MOHRHARDT GUENTER , BAUMGART HUBERT , BITTER SIMONE
Abstract: A polyisocyanate of formula (I)in which the units R1, X and R2 have the meanings:R1 is a unit of the formula (II):X is hydrogen or a unit of the formula (III):with the proviso that at least one of the units X in the polyisocyanates is a unit of formula (III); andR2 . is a 4-, 5- or 6-membered cycloalkylene group containing radical.
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公开(公告)号:DE10057603A1
公开(公告)日:2002-05-23
申请号:DE10057603
申请日:2000-11-21
Applicant: BASF AG
Inventor: BRUCHMANN BERND , MOHRHARDT GUENTER , RENZ HANS , JAEHME JOACHIM
Abstract: Mixtures containing (a) polyisocyanates (A) with isocyanurate and/or biuret units, derived from aliphatic or cycloaliphatic di-isocyanates (C) and (b) other polyisocyanates (B) with allophanate and/or urethane units, derived from (b1) di-isocyanates (C) as above and (b2) polyhydric aliphatic or cycloaliphatic alcohols (alcohols A'), with a mol ratio of (A):(B) = (200:1)-(5:1). Independent claims are also included for (i) a method for the production of these mixtures by reacting (C) with (A') in a mol ratio of (200:1)-(5:1), optionally in presence of catalysts for the formation of allophanates and urethanes, optionally deactivating the catalyst, optionally removing unreacted (C) and then mixing the resulting (B) with (A) in the above ratio; (ii) an alternative method in which (A) contains mainly isocyanurate units, involving the reaction of (C) with (A') as above, optionally in presence of catalysts for the formation of isocyanurates, allophanates and urethanes; (iii) an alternative method in which (A) contains mainly biuret unit, involving the reaction of (C), (A') and a biuretising agent (D) in mol ratios of (C):(A') = (200:1)-(5:1) and (C):(D) = (200:1)-(5:1), optionally in presence of catalysts for the formation of biurets, allophanates and urethanes; (iv) two-component coating materials containing a polyisocyanate mixture as above and an isocyanate-reactive component; (v) a method for coating objects by mixing the two components (see iv above) and coating the resulting mixture onto the substrate within 12 hours; (vi) coated objects obtained by this method.
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公开(公告)号:DE59705295D1
公开(公告)日:2001-12-13
申请号:DE59705295
申请日:1997-08-18
Applicant: BASF AG
Inventor: BRUCHMANN BERND , REIF MARTIN , HOFSCHEUER WERNER , JAEHME JOACHIM , LANGER WERNER , RENZ HANS , MOHRHARDT GUENTER , SCHIESSL MICHAEL
IPC: C07C273/18 , C07C275/62 , C08G18/08 , C08G18/30 , C08G18/32 , C08G18/78
Abstract: A process for preparing biuret-functional polyisocyanates from at least one aliphatic or cycloaliphatic diisocyanate and from at least one amine or water or a mixture thereof as reactants involves mixing the reactants with one another in a mixing unit having a high shear action.
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公开(公告)号:DE19828935A1
公开(公告)日:1999-12-30
申请号:DE19828935
申请日:1998-06-29
Applicant: BASF AG
Inventor: BRUCHMANN BERND , MOHRHARDT GUENTER , RENZ HANS , POTH ULRICH , BAUMGART HUBERT , BITTER SIMONE
IPC: C08G18/42 , C08G18/62 , C08G18/79 , C09D175/04 , C09D175/00 , C08L75/00
Abstract: A composition (I) comprises (A) at least a substantially allophanate group free polyisocyanatoisocyanurate having an average NCO functionality of more than 3.5 and a viscosity of 4000-50,000 mPas at 20-50 deg C (DIN53019) and (B) at least a compound having an average more than 5 isocyanate reactive groups consisting of urea, urethane, thiourethane or amide forming functional groups. An Independent claim is included for a process for the production of a surface coating agent by mixing (A) and (B).
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