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31.
公开(公告)号:CA2210529A1
公开(公告)日:1996-08-15
申请号:CA2210529
申请日:1996-01-26
Applicant: BASF AG
Inventor: RITTINGER STEFAN , RIEBER NORBERT , DRESSEL JUERGEN , GOLD RANDALL EVAN
IPC: C05G3/90 , C07D231/12 , C07D231/16 , C09K17/14 , C09K101/00 , C05G3/08
Abstract: Pyrazol derivatives having general formula (I) are disclosed, as well as their use as nitrification inhibitors. In said formula (I): residues R1, R2, R3 and R4 may be substituted once or twice by halogen and/or hydroxyl; the residues R1, R2 and R3 stand for halogen, nitro, hydrogen, C1-C20-alkyl, C3-C8-cycloalkyl, C5-C20-aryl or alkyl aryl; and R4 may stand for (a) a residue R4a of the formula (II), in which R5 and R6 stand for hydrogen, C1-C20-alkyl optionally substituted once or twice by halogen and/or hydroxyl, a carboxyl group, a carboxymethyl group or a functional derivative of both latter groups, and R7 stands for a carboxyl residue or a carboxy-(C1-C3-alkyl) residue or for a functional derivative of said groups, or R4 may stand for (b) a residue R4b having the formula (III), in which R8 and R9 stand for hydrogen, C1-C20-alkyl, C2-C8-cycloalkyl, C5-C20-aryl or alkyl aryl, these residues being optionally substituted once or twice by halogen, and R10 stands for hydrogen or a poly (C2-C4-alkylene oxide) residue whose terminal hydroxyl group may be etherified with an aliphatic C1-C10 alcohol or esterified with a C1-C10 carboxylic acid.
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公开(公告)号:CA2208529A1
公开(公告)日:1996-07-04
申请号:CA2208529
申请日:1995-12-14
Applicant: BASF AG
Inventor: RITTINGER STEFAN , GOLD RANDALL EVAN , DRESSEL JUERGEN , RIEBER NORBERT
IPC: C05G3/90 , C07D231/12 , C07D231/16 , C07D521/00 , C08J3/24 , C05G3/08
Abstract: Disclosed is the use as nitrification inhibitors of pyrazole derivatives of formula (I), or salts thereof, in which the groups R1-R4 have the following meanings: R1, R2 and R3 represent C1-C20 alkyl, C3-C8 cycloalkyl, C5-C20 aryl or alkyl aryl (these four groups can be singly or doubly substituted by a halogen and/or hydroxyl), and halogen, nitro or hydrogen; and R4 represents either (a) C6-C20 alkyl, one or two hydrogen atoms being optionally substituted by a halogen; or (b) C1-C20 alkyl. In the latter case, 1-4 hydrogen atoms can be substituted by a group of formula (II), in which R5, R6, and R7 represent C1-C20 alkyl, C3-C8 cycloalkyl, C5-C20 aryl or alkyl aryl (these four groups can be singly or doubly substituted by a halogen and/or hydroxyl), as well as halogen, nitro or hydrogen; and 1 or two hydrogen atoms are optionally substituted by a halogen.
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公开(公告)号:CA2532151C
公开(公告)日:2008-02-12
申请号:CA2532151
申请日:1997-08-06
Applicant: BASF AG
Inventor: RITTINGER STEFAN , LEIBOLD EDGAR , BARTH THOMAS , DRESSEL JUERGEN , ERHARDT KLAUS , HORCHLER VON LOCQUENGH KLAUS , GOLD RANDALL EVAN , RIEBER NORBERT
IPC: C05F3/00 , C05G3/00 , C05G3/90 , C05G5/00 , C07D231/12 , C07D231/16 , C07D321/12 , C07D521/00
Abstract: The use of inorganic or organic polyacids to treat mineral fertilizers, in particular the use of polyacids as a mixture with at least one nitrification inhibitor to treat mineral fertilizers. The invention also concerns the use of selected pyrazol e derivatives as inhibitors in mineral fertilizers and as stabilizers for liqu id manure or liquid fertilizer formulations, and the treated mineral fertilizers themselves, as well as new pyrazole derivatives that can be used as nitrification inhibitor s in mineral fertilizers and as stabilizers in liquid manure or liquid fertilizer formulations.
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公开(公告)号:PL195428B1
公开(公告)日:2007-09-28
申请号:PL36133397
申请日:1997-08-06
Applicant: BASF AG
Inventor: BARTH THOMAS , RIEBER NORBERT , GOLD RANDALL EVAN , DRESSEL JUERGEN , ERHARDT KLAUS , HORCHLER VON LOCQUENGH KLAUS , LEIBOLD EDGAR , RITTINGER STEFAN
IPC: C05F3/00 , C05G3/00 , C05G3/90 , C05G5/00 , C07D231/12 , C07D231/16 , C07D321/12 , C07D521/00
Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.
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公开(公告)号:ES2256464T3
公开(公告)日:2006-07-16
申请号:ES02724288
申请日:2002-04-17
Applicant: BASF AG
Inventor: STAMM ARMIN , KNEUPER HEINZ-JOSEF , RITTINGER STEFAN , DRANSFELD PETER , SCHILDBERG HANS-PETER , HEILIG MANFRED
Abstract: Un procedimiento para la manipulación intrínsecamente segura del 3-cloropropino en presencia de un diluyente con un punto de ebullición que oscila entre los -50 °C (223 K) y los 200 °C (473 K) bajo presión atmosférica, caracterizado porque el diluyente, que hierve a la misma temperatura que el 3-cloropropino o a una temperatura superior, se utiliza en una cantidad de entre le 50 y el 2000% del peso en la fase líquida, basado en la cantidad de 3-cloropropino en la fase líquida, y porque la concentración de 3-cloropropino en la fase líquida y en la fase gaseosa se mantiene por debajo de las concentraciones susceptibles a la deflagración gracias al tipo y la cantidad de diluyente, la temperatura y la presión total del sistema.
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公开(公告)号:DE102004023529A1
公开(公告)日:2005-12-08
申请号:DE102004023529
申请日:2004-05-13
Applicant: BASF AG
Inventor: HAESE FRANK , BOETTCHER ARND , STEIN BERND , REIF WOLFGANG , MELDER JOHANN-PETER , ROS KARL-HEINZ , RUETTER HEINZ , LIANG SHELUE , RITTINGER STEFAN
IPC: C07C209/16 , C07C209/26 , C07C211/06 , C07C211/08 , C07C211/35 , C07C213/02 , C07C217/08 , C07D295/02 , C07D295/027 , C07D295/03 , C07D295/088 , C07C217/42 , C07C215/08
Abstract: Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C. in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al 2 O 3 ), zirconium dioxide (ZrO 2 ), titanium dioxide (TiO 2 ) and/or silicon dioxide (SiO 2 ), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr 2 O 3 , oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
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公开(公告)号:ES2217046T3
公开(公告)日:2004-11-01
申请号:ES01105436
申请日:1997-08-06
Applicant: BASF AG
Inventor: BARTH THOMAS , RIEBER NORBERT , GOLD RANDALL EVAN , DRESSEL JUERGEN , ERHARDT KLAUS , RITTINGER STEFAN
IPC: C05F3/00 , C05G3/00 , C05G3/90 , C05G5/00 , C07D231/12 , C07D231/16 , C07D321/12 , C07D521/00 , C05G3/08
Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.
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公开(公告)号:AT261919T
公开(公告)日:2004-04-15
申请号:AT01105436
申请日:1997-08-06
Applicant: BASF AG
Inventor: BARTH THOMAS , RIEBER NORBERT , GOLD RANDALL EVAN , DRESSEL JUERGEN , ERHARDT KLAUS , RITTINGER STEFAN , HORCHLER LOCQUENGHIEN KLAUS VON , LEIBOLD EDGAR
IPC: C05F3/00 , C05G3/00 , C05G3/90 , C05G5/00 , C07D231/12 , C07D231/16 , C07D321/12 , C07D521/00 , C05G3/08
Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.
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公开(公告)号:DK0917526T3
公开(公告)日:2002-03-25
申请号:DK97941915
申请日:1997-08-06
Applicant: BASF AG
Inventor: BARTH THOMAS , RIEBER NORBERT , GOLD RANDALL EVAN , DRESSEL JUERGEN , ERHARDT KLAUS , HORCHLER VON LOCQUENGH KLAUS , LEIBOLD EDGAR , RITTINGER STEFAN
IPC: C05F3/00 , C05G3/00 , C05G3/90 , C05G5/00 , C07D231/12 , C07D231/16 , C07D321/12 , C07D521/00 , C05G3/08
Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.
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公开(公告)号:AU716545B2
公开(公告)日:2000-02-24
申请号:AU4378797
申请日:1997-08-06
Applicant: BASF AG
Inventor: BARTH THOMAS , RIEBER NORBERT , GOLD RANDALL EVAN , DRESSEL JUERGEN , ERHARDT KLAUS , LOCQUENGH KLAUS HORCHLER VON , LEIBOLD EDGAR , RITTINGER STEFAN
IPC: C05F3/00 , C05G3/00 , C05G3/90 , C05G5/00 , C07D231/12 , C07D231/16 , C07D321/12 , C07D521/00 , C05G3/08
Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.
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