33.
    发明专利
    未知

    公开(公告)号:ES2158507T3

    公开(公告)日:2001-09-01

    申请号:ES97909234

    申请日:1997-09-19

    Applicant: BASF AG

    Abstract: In a process for the hydroformylation of olefins having from 12 to 100 carbon atoms in the presence of a cobalt carbonyl catalyst at pressures of from 100 to 400 bar and at from 100 to 200° C., depressurization and recovery of the cobalt catalyst by extraction with an aqueous acid solution in the presence of atmospheric oxygen,(a) the extraction is carried out in the presence of a polymeric emulsion breaker selected from the group consisting of alkoxylated compounds containing amino, imino or OH groups, and(b) to achieve complete phase separation in the organic phase still containing small amounts of aqueous phase, the formation of relatively large droplets of the dispersed aqueous phase is effected in a coalescence stage.

    36.
    发明专利
    未知

    公开(公告)号:DE59703815D1

    公开(公告)日:2001-07-26

    申请号:DE59703815

    申请日:1997-09-19

    Applicant: BASF AG

    Abstract: In a process for the hydroformylation of olefins having from 12 to 100 carbon atoms in the presence of a cobalt carbonyl catalyst at pressures of from 100 to 400 bar and at from 100 to 200° C., depressurization and recovery of the cobalt catalyst by extraction with an aqueous acid solution in the presence of atmospheric oxygen,(a) the extraction is carried out in the presence of a polymeric emulsion breaker selected from the group consisting of alkoxylated compounds containing amino, imino or OH groups, and(b) to achieve complete phase separation in the organic phase still containing small amounts of aqueous phase, the formation of relatively large droplets of the dispersed aqueous phase is effected in a coalescence stage.

    38.
    发明专利
    未知

    公开(公告)号:NO327827B1

    公开(公告)日:2009-10-05

    申请号:NO20023514

    申请日:2002-07-23

    Applicant: BASF AG

    Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that-before the hydrolysis of the methyl formate-the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.

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