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公开(公告)号：AU8772901A
公开(公告)日：2002-03-26
申请号：AU8772901
申请日：2001-09-11
Applicant: BASF AG
Inventor： ROPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , GRENACHER ARMIN VOLKER , KROKOSZINSKI ROLAND , SCHONMANN WILLI
Abstract: Essentially monounsaturated polyalkylenes having from 30 to 700 carbon atoms are continuously hydroformylated by a process in which i) a hydroformylation-active cobalt carbonyl catalyst is prepared from a catalyst precursor dissolved in an aqueous phase in the absence of the polyalkylenes, ii) the polyalkylenes are hydroformylated by means of synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, iii) the cobalt carbonyl catalyst is separated from the output from the reaction zone with at least partial reformation of the catalyst precursor and the catalyst precursor is recirculated to step i).
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公开(公告)号：DE10045056A1
公开(公告)日：2002-03-21
申请号：DE10045056
申请日：2000-09-12
Applicant: BASF AG
Inventor： ROEPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , GRENACHER ARMIN VOLKER , KROKOSZINSKI ROLAND , SCHOENMANN WILLI
Abstract: The invention relates to a method for the continuous hydroformylation of polyalkenes having 30 to 700 carbon atoms and being unsaturated essentially once. The inventive method involves i) producing a cobalt carbonyl catalyst which is active for hydroformylation from a catalyst precursor which is dissolved in an aqueous phase, in the absence of the polyalkenes, ii) hydroformylating the polyalkenes with synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, and iii) separating the cobalt carbonyl catalyst from the discharge from the reaction zone while at least partially regenerating the catalyst precursor, and returning the catalyst precursor to step i).
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公开(公告)号：AT283869T
公开(公告)日：2004-12-15
申请号：AT01967331
申请日：2001-09-11
Applicant: BASF AG
Inventor： ROEPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , GRENACHER ARMIN VOLKER , KROKOSZINSKI ROLAND , SCHOENMANN WILLI
Abstract: Essentially monounsaturated polyalkylenes having from 30 to 700 carbon atoms are continuously hydroformylated by a process in which i) a hydroformylation-active cobalt carbonyl catalyst is prepared from a catalyst precursor dissolved in an aqueous phase in the absence of the polyalkylenes, ii) the polyalkylenes are hydroformylated by means of synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, iii) the cobalt carbonyl catalyst is separated from the output from the reaction zone with at least partial reformation of the catalyst precursor and the catalyst precursor is recirculated to step i).
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公开(公告)号：DE10126363A1
公开(公告)日：2001-12-06
申请号：DE10126363
申请日：2001-05-30
Applicant: BASF AG
Inventor： GRENACHER ARMIN VOLKER , HEIN HANS-GEORG , STEPP HANS , FROEHLICH HANS-JUERGEN , SCHOENMANN WILLI , BORCHERT GERHARD
IPC: B01J3/04 , B01J8/00 , B01J19/26 , C07C29/141 , C07C45/50 , C07C27/20 , C07C47/02 , C07C31/125
Abstract: In the production of 6-30C aldehydes and/or alcohols (A) by hydroformylation, the reaction mixture (olefins, synthesis gas and catalysts, or their precursors) is introduced into the reactor through a nozzle with adjustable transmission cross-section. Reaction is at 120-210 deg C and 100-400 bar and the reaction mixture is introduced at high speed into a high-pressure reactor. An Independent claim is also included for a reactor for production of (A) by the new process.
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公开(公告)号：ES2003829B3
公开(公告)日：1989-12-16
申请号：ES86116461
申请日：1986-11-27
Applicant: BASF AG
Inventor： GRENACHER ARMIN VOLKER , HOFFMANN HERWIG , STROHMEYER MAX , ELLIEHAUSEN HEINRICH
IPC: C07B61/00 , B01J23/00 , B01J23/88 , C07C27/00 , C07C29/14 , C07C29/141 , C07C31/02 , C07C31/125 , C07C67/00
Abstract: LA OBTENCION DE C3 CION CATALITICA DE LOS CORRESPONDIENTES ALCANALES EN BRUTO, COMO SE PRODUCEN POR LA HIDROFORMILIZACION CATALIZADA CON COBALTO DE C2 C4 % A 150-230 (GRADOS) C Y A 10-350 BARES, CON UN CATALIZADOR SOPORTE DE SIO2, CONTENIENDO UN 5-15 % DE SU PESO DE NIQUEL, ASI COMO 2-20 % DE SU PESO DE MOLIBDENO, EN FORMA DE OXIDO DE MOLIBDENO, REFERIDO RESPECTIVAMENTE A SU CONTENIDO TOTAL, Y QUE B) SE CONTINUA HASTA SU FIN LA HIDRATACION EN UN SEGUNDO PASO, A 150-230 (GRADOS) C Y 10-350 BARES CON AYUDA DE UN CATALIZADOR DE COBALTO, CUYA MASA ESTA COMPUESTA DE 55-65 % DE SU PESO DE COBALTO, 15-20 % DE SU PESO DE COBRE, 4-10 % DE SU PESO DE MANGANESO, 2 LIBDENO, 0-10 % DE SU PESO DE SUSTANCIAS ADITIVAS ACTIVADORAS HABITUALES.
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Patent Agency Ranking6.发明专利
公开(公告)号：ES2233678T3
公开(公告)日：2005-06-16
申请号：ES01967331
申请日：2001-09-11
Applicant: BASF AG
Inventor： ROPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , GRENACHER ARMIN VOLKER , KROKOSZINSKI ROLAND , SCHONMANN WILLI
Abstract: Procedimiento para el hidroformilado continuo de polialquilenos, esencialmente monoinsaturados, con 30 a 700 átomos de carbono, en el que i) se obtiene un catalizador de carbonilo de cobalto con actividad de hidroformilado en ausencia de polialquilenos, a partir de un precursor de catalizador disuelto en una fase acuosa, ii) se hidroformilan los polialquilenos en una zona de reacción en presencia del catalizador de carbonilo de cobalto con gas de síntesis, iii) a partir de la descarga de la zona de reacción se separa el catalizador de carbonilo de cobalto bajo recuperación, al menos parcial, del precursor de catalizador, y se devuelve al precursor de catalizador en el paso i).
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公开(公告)号：DE10003871A1
公开(公告)日：2001-08-02
申请号：DE10003871
申请日：2000-01-28
Applicant: BASF AG
Inventor： SCHWAHN HARALD , BORCHERT GERHARD , DIEHL KLAUS , GRENACHER ARMIN VOLKER , SAUER FRIEDRICH
Abstract: The invention relates to a method for hydroformylating olefins having between 20 and 400 carbon atoms by reacting the olefins with synthesis gas in the presence of a cobalt carbonyl catalyst, by recovering the cobalt catalyst by extracting the discarded substances resulting from the reaction using an aqueous acidic solution in the presence of oxygen, and by separating the organic and aqueous phases. The inventive method is characterized in that: (a) the aqueous phase is separated away from the organic phase to the greatest possible extent by using mass forces such that the proportion of the aqueous phase dispersed in the organic phase is equal to 2 wt. % or less with regard to the organic phase, and; (b) the organic phase involved in step (a) is subjected to an electric field while effecting the coalescence of the dispersed aqueous phase. This enables the residual cobalt content in the hydroformylation product to be reduced to less than 1 ppm.
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公开(公告)号：ES2158507T3
公开(公告)日：2001-09-01
申请号：ES97909234
申请日：1997-09-19
Applicant: BASF AG
Inventor： BLANKERTZ HEINRICH-JOSEF , GRENACHER ARMIN VOLKER , SAUER FRIEDRICH , SCHWAHN HARALD , SCHONMANN WILLI , ROEPER MICHAEL
Abstract: In a process for the hydroformylation of olefins having from 12 to 100 carbon atoms in the presence of a cobalt carbonyl catalyst at pressures of from 100 to 400 bar and at from 100 to 200° C., depressurization and recovery of the cobalt catalyst by extraction with an aqueous acid solution in the presence of atmospheric oxygen,(a) the extraction is carried out in the presence of a polymeric emulsion breaker selected from the group consisting of alkoxylated compounds containing amino, imino or OH groups, and(b) to achieve complete phase separation in the organic phase still containing small amounts of aqueous phase, the formation of relatively large droplets of the dispersed aqueous phase is effected in a coalescence stage.
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公开(公告)号：DE19939491A1
公开(公告)日：2001-02-22
申请号：DE19939491
申请日：1999-08-20
Applicant: BASF AG
Inventor： GRENACHER ARMIN VOLKER , STEPP HANS
Abstract: The continuous hydroformylation of 6-20C olefins with hydrogen and carbon monoxide, with regeneration and recycling of the cobalt catalyst, is carried out with aqueous cobalt(II) salt solution. A continuous process for the hydroformylation of 6-20C olefins (I) by: (a) contacting an aqueous cobalt(II) salt solution with hydrogen and carbon monoxide to form a hydroformylation catalyst and then bringing the aqueous catalyst phase into intimate contact with (I), optional organic solvent and H2 plus CO so that the catalyst is extracted into the organic phase and (I) is hydroformylated; (b) treating the product from the reaction zone with oxygen in presence of acid aqueous Co salt solution so that the catalyst is decomposed to form Co(II) salts which are back-extracted into the aqueous phase, and then separating the phases; and (c) returning the aqueous Co(II) salt solution unchanged to stage (a). The Co(II) salt solution has a concentration of 1.1-1.7 wt% (as cobalt) and is always kept under conditions such that the solubility limit of Co(II) formate in water is not exceeded.
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公开(公告)号：CA2421940C
公开(公告)日：2009-11-24
申请号：CA2421940
申请日：2001-09-11
Applicant: BASF AG
Inventor： ROPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , SCHONMANN WILLI , KROKOSZINSKI ROLAND , GRENACHER ARMIN VOLKER
Abstract: The invention relates to a method for the continuous hydroformylation of polyalkenes having 30 to 700 carbon atoms and being unsaturated essentially once. The inventive method involves i) producing a cobalt carbonyl catalyst which is active for hydroformylation from a catalyst precursor which is dissolved in an aqueous phase, in the absence of the polyalkenes, ii) hydroformylating the polyalkenes with synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, and iii) separating the cobalt carbonyl catalyst from the discharge from the reaction zone while at least partially regenerating the catalyst precursor, and returning the catalyst precursor to step i).
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