公开(公告)号：CA1333826C

公开(公告)日：1995-01-03

申请号：CA551584

申请日：1987-11-06

Applicant: BASF AG

Inventor： HASENBEIN NORBERT ,  BAUER PETER ,  SCHLEMMER LOTHAR ,  HAUSS ALFRED F ,  GROPPER HANS ,  OHLINGER RAINER

IPC: C08F2/02 ,  C08F8/44 ,  C08F255/02 ,  C09J4/00 ,  C09J151/06

Abstract: In a process for the peroxide-free grafting of ethylenically unsaturated carboxylic acids, carboxylic anhydrides and/or their derivatives to a homopolymer or copolymer of ethylene having a density equal to or greater than 0.930 g/cm3, the monomers to be grafted are used in a concentration of from 0.01 to 0.5% by weight and the grafting reaction is carried out at from 210 to 300.degree.C in a conventional extruder or mixer in the absence of a free radical initiator. The graft copolymers are used for the preparation of ionomers and adhesion promoters.

公开(公告)号：NO173588C

公开(公告)日：1994-01-05

申请号：NO871512

申请日：1987-04-10

Applicant: BASF AG

Inventor： KLIMESCH ROGER GUENTHER ,  BLECKMANN GERHARD ,  FARWERCK KARL-PETER ,  SCHLEMMER LOTHAR ,  GOERTZ HANS-HELMUT

IPC: A61H39/00 ,  A61J3/10 ,  A61K9/20 ,  A61K9/22 ,  A61K9/26 ,  B29B9/06 ,  B30B11/16 ,  B30B11/24

Abstract: Extrudable pharmaceutical mixtures are tableted by a continuous method in which the mixture is extruded and the still deformable extrudate is pressed between two rollers which are driven in opposite directions and possess depressions opposite one another in the roller shell, the form of these depressions determining the tablet shape.

公开(公告)号：DE3786884D1

公开(公告)日：1993-09-09

申请号：DE3786884

申请日：1987-11-19

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  BAUER PETER ,  SCHLEMMER LOTHAR ,  HAUSS ALFRED FRIEDRICH DR ,  GROPPER HANS DR ,  OHLINGER RAINER DR

IPC: C08F2/02 ,  C08F8/44 ,  C08F255/02 ,  C09J4/00 ,  C09J151/06

Abstract: Grafting of ethylenically unsatd. acids or anhydrides (or their derivs.) onto ethylene homo- or co-polymers of density 0.930 g/cc or higher is carried out in a conventional extruder or mixer at 1-500 bar in the absence of a catalyst which decomposes to give radicals. This is achieved by mixing 0.01-0.5 wt. pts. of the grafting monomer with 100 wt. pts. of molten ethylene polymer at 140 deg.C or above and then carrying out grafting at 210-300 deg.C..

公开(公告)号：DE3880514D1

公开(公告)日：1993-06-03

申请号：DE3880514

申请日：1988-01-22

Applicant: BASF AG

Inventor： TAUBITZ CHRISTOF DR ,  GAUSEPOHL HERMANN DR ,  SEILER ERHARD DR ,  BOEHLKE KLAUS DR ,  SCHLEMMER LOTHAR

IPC: C08J3/20 ,  C08F283/08 ,  C08G65/48 ,  C08L71/12 ,  C08L77/00

Abstract: Continuous prodn. of thermoplastic polyphenylene ether /polyamide moulding materials in an extruder comprises (1) reacting in a first zone at 240-350 deg.C (by wt. w.r.t. total components (a1)-(a5): (a1) 50-99.5% of a polyphenylene ether, (a2) 0-45% of a vinylaromatic polymer, (a3) 0.05-10% of (a31) an alpha-beta-unsatd. carboxylic acid of derivs. of this of formula R1-CO-C(R2)=C(R3)-CO-R4 (I) in which R1 and R4=OH, aryloxy, alkoxy, aralkoxy or cycloalkoxy gps. with up to 12C, or R1 and R4 together=-O- or -NR5-; R2 and R3=H, alkyl or cycloalkyl with up to 12C, aryl or Cl, or R2 and R3 may together form a 4-12C alkylene gp.; R5=alkyl, cycloalkyl, aralkyl or aryl gp. wit- up to 12C, which may be substd. with 1-4C alkyl or alkoxy gps., and/or (a32) a monomer contg. an amide gp. and a polymerisable double bond, and/or (a33) a monomer contg. a lactam gp. and a polymerisable double bond; and opt. (a4) 0-80% other monomers suitable for grafting and (a5) 0-20% radical initiators, for 0.1-15 mins. to give a modified polyphenylene ether A; and (2) subsequently introducing into a further zone of the extruder at 250-350 deg.C (by wt. w.r.t. total components A-F); (B) 5-95 wt.% of a polyamide, (C) 0-90 wt.% of an unmodified polyphenylene ether, (D) 0-45% of a vinyl aromatic polymer, (E) 0-40% of an impact-improving modifying rubber, (F) 0-60% additives and processing aids, and finally extruding the mixt..

公开(公告)号：DE4131872A1

公开(公告)日：1993-04-08

申请号：DE4131872

申请日：1991-09-25

Applicant: BASF AG

Inventor： FARWERCK KARL-PETER ,  LAUKE HARALD DR ,  MC KEE GRAHAM EDMUND DR ,  SEITZ FRIEDRICH DR ,  GUENTHERBERG NORBERT DR ,  OHLIG HILMAR ,  BESECKE SIEGMUND DR ,  KROEGER HARALD ,  LOTH WOLFGANG DR ,  NIESSNER NORBERT DR ,  SCHLEMMER LOTHAR ,  WAGNER DANIEL DR

IPC: B29B7/84 ,  B29C47/00 ,  B29C48/76 ,  C08J3/00

公开(公告)号：FI88577B

公开(公告)日：1993-02-26

申请号：FI871538

申请日：1987-04-08

Applicant: BASF AG

Inventor： KLIMESCH ROGER GUENTHER ,  BLECKMANN GERHARD ,  FARWERCK KARL-PETER ,  GOERTZ HANS-HELMUT ,  SCHLEMMER LOTHAR

IPC: A61H39/00 ,  A61J3/10 ,  A61K9/20 ,  A61K9/22 ,  A61K9/26 ,  B29B9/06 ,  B30B11/16 ,  B30B11/24

Abstract: Extrudable pharmaceutical mixtures are tableted by a continuous method in which the mixture is extruded and the still deformable extrudate is pressed between two rollers which are driven in opposite directions and possess depressions opposite one another in the roller shell, the form of these depressions determining the tablet shape.

公开(公告)号：AT82495T

公开(公告)日：1992-12-15

申请号：AT89105917

申请日：1989-04-05

Applicant: BASF AG

Inventor： KLIMESCH ROGER DR ,  BLECKMANN GERHARD ,  SCHLEMMER LOTHAR

IPC: A61J3/06 ,  A61J3/10 ,  A61K9/20 ,  B29C45/00

公开(公告)号：AT76648T

公开(公告)日：1992-06-15

申请号：AT89111193

申请日：1989-06-20

Applicant: BASF AG

Inventor： MUEHLENBERND THOMAS DR ,  HASENBEIN NORBERT DR ,  KOEHLER GERNOT DR ,  SCHLEMMER LOTHAR

IPC: C08F8/44 ,  C08F210/00 ,  C08F210/02 ,  C08F220/00 ,  C08F220/04

公开(公告)号：DE3485331D1

公开(公告)日：1992-01-23

申请号：DE3485331

申请日：1984-04-09

Applicant: BASF AG

Inventor： MC KEE GRAHAM EDMUND DR ,  OHLIG HILMAR ,  REIMANN HORST DR ,  SCHLEMMER LOTHAR ,  THEYSOHN RAINER DR ,  DORST HANS GEORG DR ,  ZAHRADNIK FRANZ DR

IPC: C08J3/00 ,  C08J3/20 ,  C08L9/00 ,  C08L51/04 ,  C08L77/00

Abstract: Compsns. (I) contains A) 60-95 pts.wt. at least one crystalline thermoplastic polyamide, B) 5-40 pts.wt. at least one rubber-elastic polymerisate without hard external shell, prepd. by emulsion polymerisation, having particle size distribution substantially governed by polymerisation process and particle size under 2 microns, dispersed in, and predominantly insol. in A), where sum of A) + B) = 100 pts.wt., opt. C) up to 100 pts.wt. glass fibres or other reinforcing filler, and opt. D) effective amts. of conventional auxiliary agents. Pref. A) is linear, with m.pt. above 200 deg.C and relative viscosity (1% in conc. H2SO4 at 23 deg.C) 2.5-4.0, partic. poly(hexamethylene adipamide) or polycaprolactam. B) is at least partially crosslinked and has glass transition temp. below -20 deg.C; has on surface of particle mol. gps. causing adhesion to mols. of A), partic. COOH, carboxylic ester, or carboxylic amide gps.

公开(公告)号：AT70548T

公开(公告)日：1992-01-15

申请号：AT86102198

申请日：1986-02-20

Applicant: BASF AG

Inventor： ZIEGLER WALTER DR ,  BRANDSTETTER FRANZ DR ,  WEISS FRANK DR ,  SCHLEMMER LOTHAR

IPC: C08J3/205 ,  C08J3/24 ,  C08K5/09 ,  C08K5/098 ,  C08L23/08